Read here

The treatment of paper for special purposes : a practical introduction to the preparation of paper products for a great variety of purposes such as parchment paper, transfer papers, preservative papers, grained transfer papers, fireproof and antifalsification papers, polishing papers, tracing and copying papers, chalk and litho transfer papers, leather papers, luminous papers, tortoiseshell and ivory papers, metal papers, coloured papers, etc. etc., and paper articles

Louis Edgar Andés · 1907 · Scanned text

73,043 words · about 5 h 7 min to read

Period artwork: Interior of the Bodleian Library, 1845
About this edition

Scanned text — may contain errors · view original scans

Licence: PD · PD-US by publication date

Text from Internet Archive, read from page scans by OCR and set out for reading on screen; no words of the book are rewritten or summarized. How RedLectern is built

About this book

Author
Louis Edgar Andés
Language
English
Published
1907
Length
73,043 words · about 5 h 7 min
Sections
33 reader sections
Text
Scanned text, read from page scans by OCR; may contain errors
Rights
Public domain · PD-US by publication date

 

Contents (33)
  1. Front matter about 1 min
  2. Preface about 1 min
  3. Chapter I about 1 min
  4. Chapter III. Page about 1 min
  5. CHAPTER VI. Vulcanised Papier Mach4 . . . . .62 about 1 min
  6. CHAPTER IX. Fly Papers ....... 83 under 1 min
  7. CHAPTER X. Chalk and Leather Papers . . . . .88 under 1 min
  8. CHAPTER XI. Luminous Papers — Blue-Print Papers — Blotting Papers . 93 under 1 min
  9. CHAPTER XII. Metal Papers and Medicated Papers .... 105 about 1 min
  10. CHAPTER XIV. Recipes for Oil or Varnish Tracing Paper . . . 137 under 1 min
  11. CHAPTER XV. Albuminised Paper . . . . . .147 about 1 min
  12. CHAPTER XVII. Lithographic Transfer Papers ..... 190 under 1 min
  13. CHAPTER XVIII. Satin Paper ....... 195 about 1 min
  14. CHAPTER XIX. Washable Drawing Paper . . . . .212 about 1 min
  15. CHAPTER I. Parchment Paper, Vegetable Parchment about 49 min
  16. CHAPTER II. Paper for Transfer Pictures ( Metachromotypes ) about 6 min
  17. CHAPTER III. Papers for Preserving and Packing Purposes about 7 min
  18. CHAPTER IV. Grained Transfer Papers about 8 min
  19. CHAPTER V. Fireproof and Antifalsification Papers about 7 min
  20. CHAPTER VI. Paper Articles about 15 min
  21. CHAPTER VII. Gummed Paper about 6 min
  22. CHAPTER IX. Insecticide Papers about 5 min
  23. CHAPTER X. Chalk and Leather Parers about 19 min
  24. CHAPTER XII. Metal Papers and Medicated Papers about 12 min
  25. CHAPTER XIII. Marbled Paper about 16 min
  26. CHAPTER XIV. Tracing and Copying Papers about 38 min
  27. CHAPTER XVI. Papers for Cleaning and Polishing Purposes about 24 min
  28. CHAPTER XVII. Lithographic Transfer Papers about 5 min
  29. CHAPTER XVIII. Sundry Special Papers about 19 min
  30. CHAPTER XIX. Waterproof Papers about 11 min
  31. Chapter XX about 16 min
  32. Contents about 2 min
  33. Index To Subjects about 36 min

Continue:

Front matter

LOUIS. E. ANDES

THE TREATMENT OF PAPER FOR SPECIAL PURPOSES

I

Preface

Of all the materials now in extensive use, paper is probably the one attracting the greatest attention, by reason of its manifold application to the production of useful articles. Thin sheets of paper are now made up, not merely into articles that retain the characteristics of the material, in some cases coated or coloured, but also into others in which the original material has disappeared, homogeneous solid substances being formed that are capable of competing with wood or iron in point of durability and elasticity. Instructions for working paper up into a great variety of articles are to be found in a large number of books and periodicals; and the author has under¬ taken the task of collecting and sifting them, in the hope that the result will prove beneficial to all trades in which paper is used as a raw material.

LOUIS EDGAR AND&3.

Chapter I

Parchment Paper, Vegetable Parchment Making Parchment Paper The Parchment Paper Machine .

Opaque, Supple Parchment Paper Thick Parchment ....

Kugler’s Parchment Paper and Parchment Slates Double and Triple Osmotic Parchment .

Anti-Erasion Paper and Parchment

Staining Parchment Paper

Utilising Waste Parchment Paper

Parchmenting Linen, Woollen, and Cotton Fabrics

Parchment Millboard ....

Wood’s Artificial Parchment

Imitation Horn and Ivory from Parchment Paper

Pergamyu (Grease-Proof Imitation Parchment Paper)

Impermeable Parchment Paper .

Parchmented Millboard ....

Parchment Paper Filters.

Elastic Mass from Vegetable Parchment.

Imitation Parchment Paper

Artificial Parchment ....

Testing the Sulphuric Acid

28 29

31 31

32 32 34

CHAPTER II. Pater for Transfer Pictures (Metachromotypes) . . 39

Transfer Papers for Decorating Glass . . . .42

Transfer Papers for Glass Etching . . . .43

vii viii

Chapter III. Page

Butter Paper . . . . . . .44

Needle Paper . . . . . . .45

Salicylic Paper . . . . . . .45

Paraffin Paper . . . . . . .47

Wrapping Paper for Silverware . . . . .48

Waterproof Paper . . . . . .48

Hygroscopic Paper . . . . . .48

Anticorrosive Paper . . . . . .49

CHAPTER IV. Antony’s Method . . . • . .51

Grossheim’s Method . . . . . .51

Tischler’s Method . . . . . .54

CHAPTER V. Fireproof and Antifalsification Papers . . .56

Fireproof Papers ....... 56

Antifalsification Paper . . . . . .59

Calomel Paper for Preventing Falsification of Documents . 59

Antifalsification Paper . . . . . .60

CHAPTER VI. Vulcanised Papier Mach4 . . . . .62

Paper Bottles . . . . . . .64

Unbreakable Writing Tablets . . . . .65

Plastic Articles of Paper . . . . . .66

Waterproof Coverings for Walls and Ceilings . . .67

Parchment Slates . . . . ... 68

Flanges and Manhole Rings . . . . .68

Paper Wheels, Roofing, and Boats . . . .69

Paper Barrels . . . . . . .70

Paper Gaspipes . . . . . . .72

Paper Boxes . . . . . . .72

Paper Horseshoes . . . . . .72

IX

Chapter VII. Page

Machine for Gumming Paper . . . . .78

CHAPTER VIII. Hectograph Papers . . . . . .80

Hectograph Sheets . . . . . .80

Endless Hectograph Paper . . . . .81

CHAPTER IX. Fly Papers ....... 83

(a) Saccharin Paper . . . . . .83

( b ) Non-poisonous Colocynth Paper. . . .83

(c) Non-poisonous Quassia Paper . . . .84

(d) Non-poisonous Vegetable Fly Paper . . .84

(e) Poisonous Fly Paper . . . . .84

Non-poisonous Papers for destroying Rats and Mice . . 85

Moth Papers . . . . . . .85

CHAPTER X. Chalk and Leather Papers . . . . .88

Glac6 Chalk Paper . . . . . .88

Warren de la Rue’s Paper . . . . .88

Chalk Paper : Papier M6tallique, Ivory Paper . . .89

Leather Paper . . . . . . .89

Kellog’s Leather Paper . . . . .89

Leather Paper . . . . . .90

Klein’s Imitation Leather . . . .91

CHAPTER XI. Luminous Papers — Blue-Print Papers — Blotting Papers . 93

Luminous Paper . . . . . . .95

Blue-Print and Similar Papers . . . . .96

Albumin Blue-Print Papers. . . . .96

Haupt’s Sensitive Paper . . . . .96

Ferro-Prussiate Blue-Print Paper . . .97

(a) For Blue Lines on a White Ground. . . 97

( b ) For White Lines on a Blue Ground. . . 97

X

PAGE

Indigo Blue-Print Paper . . . . .98

Heliographic Paper (Black Lines on a White Ground) . 99

Photographic Transfer Paper . . . .99

Blotting Papers ....... 100

Ink Eradicator Paper . . . .100

Blotting Paper . . . . . .100

Paper Stencil Plates . . . . . .100

CHAPTER XII. Metal Papers and Medicated Papers .... 105

Brandt and Nawrocki’s Method ..... 106

Molten Metallic Paper ...... 107

Medicated Papers . . . . . .108

Aseptic and Antiseptic Papers . . . .108

Varnished Paper . . . . . .109

Gout Papers. ...... 109

Yellow Gout Paper ..... 109

Brown Gout Paper . . . .109

Christy’s Chrome-Gelatine Bandaging . . . 110

Ricou’s Anti- Asthma Paper. .... 110

Papier China ique ...... 110

Blister Paper (Papier Epispastique) .... 110

Winsly Paper (Papier Winsly) . . . .111

East Indian Paper Plaster for Slight Flesh Wounds . Ill

Mustard Paper . . . . . .111

Hygienic Paper Handkerchiefs .... 112

Millboard Splints ...... 112

Iodine Paper . . . . • .113

Gautier’s Nascent Iodine Paper .... 113

CHAPTER XIII. Marbled Parer ....... 117

Apparatus for Marbling Paper ..... 119

Paper Sprinkling Machines . . . . .132

CHAPTER XIV. Recipes for Oil or Varnish Tracing Paper . . . 137

Waxed Tracing Paper ...... 139

XI

PAGE

Temporarily Transparent Tracing Paper. . . .139

Victoria Tracing Paper . . . . . .140

Coloured Copying Papers (Carbon Papers) . . .140

Graphite Paper (Black Carbon Paper) .... 141

Double-coated Carbon Papers for Copying from the Negative Inscription ....... 141

Backing for Sheets of Copying Paper .... 143

Ferruginous Copying Paper ..... 143

Iridescent or Mother-of-Pearl Papers .... 144

Beinisch’s Iridescent Paper ..... 144

Puscher’s Iridescent Paper for Visiting Cards, etc. . . 144

Imitation Mother-of-Pearl ..... 145

Mother-of-Pearl Paper ..... 145

CHAPTER XV. Albuminised Paper . . . . . .147

Bromide Albumin Paper for Enlargements . . . 149

Bromide Paper . . . . . . .149

Zitterow’s Collodion Photographic Paper . . .149

Ferro-Gum Paper ...... 150

Gelatine Paper for Photo-Zinco Work .... 150

Matt Albuminised Paper . . . . .151

Stable Sensitised Paper . . . . . .152

Heliochrome Paper . . . . . . 153

Sensitised Paper for Photo-Zincography .... 154

Instantaneous Positive Paper . . . . .156

Halleur’s Photographic Paper . . . . .156

Photo-Lithographic Paper . . . . .156

Pigmented Photographic Paper ..... 157

Platinum Paper . . . . . . .160

Shellac Paper . . . . . . .162

Fumigating Papers . ...... 162

Combustible . . . . . . .163

Incombustible ....... 163

Other Recipes ....... 163

Armenian Paper ....... 164

Litmus Paper . . . . . . .164

Blue Litmus Paper . . . . . .165

Red Litmus Paper ...... 165 xii

PAGE

Turmeric Paper ....... 166

Tetramethyl-Paraphenyl-Diamine Papier . . . 166

Different Test Papers . . . . . .166

Oenocrine Paper . . . . . . .167

CHAPTER XYI.

Papers for Cleaning and Polishing Purposes . . 168

Glass Paper . . . . . . .169

Pumice Paper . . . . . . .174

Emery Papier . . . . . . .176

Paper Substitute for Cotton Waste .... 188

CHAPTER XVII. Lithographic Transfer Papers ..... 190

Scotch Transfer Paper . . . . . .191

Un stretchable Transfer Paper ..... 191

Unstretchable Sensitive Transfer Paper .... 192

Transfer Paper . . . . . . .192

Tracing and Transfer Papier . . . . .193

Autographic Paper . . . . . .193

CHAPTER XVIII. Satin Paper ....... 195

Ivory Paper for Miniatures . . . . .195

Enamel Paper ....... 196

Metallic Paper (Papiier M6tallique) .... 197

Telegraphic Paper . . . . . .197

Paper for Gun Cartridges . . . . .197

Tortoiseshell Paper . . . . . .198

Artificial Snow Paper . . . . . 198

Weather-Gauge Papers ...... 200

Toughened Filter Paper ...... 200

Paper for Magic Lantern Pictures .... 201

Split Paper . . . . . . .201

Contents xiii

page

Charred-Outline Pictures ..... 203

Flexible Mirrors ....... 203

Sulphur Paper ....... 203

Artificial Flower Paper ...... 204

Indelible Pictures ...... 204

Barometer Pictures (Weather-Gauge Pictures) . . . 205

Albumin Clarifying Paper ..... 205

Insulating Paper ....... 206

Electric Paper ....... 206

Paper Floor Covering ...... 206

Paper Matches . . . . . . .207

Crocodile Tears — Physical Toy ..... 207

Magic Pictures ....... 208

Laundry Blue Papers ...... 209

Blue Paper for Bleachers’ Use ..... 211

CHAPTER XIX. Washable Drawing Paper . . . . .212

Waterproof Satin Paper ...... 212

Impervious Paper ...... 213

Impervious Packing Paper for Hygroscopic Substances . . 213

Waterproofing Composition for Cellulose Casks . . .213

Waterproofing Composition for Cartridges . . .214

Washable Card for Photographic and Lithographic Purposes . 214

Anti- Perspiration Socks ...... 215

Washable Coloured Paper ..... 215

Waterproof Paper ...... 218

Blackburn’s Recipe . . . . . .218

Mitschele’s Recipe . . . . .218

Carmichael’s Recipe . . . . . .219

Dorian’s Recipe . . . . . .219

Bird’s Recipe . . . . . .219

Waterproof Millboard . . . • . 220

Sugar Paper ....... 220

CHAPTER XX. The Characteristics of Paper — Paper Testing . . 222

THE TREATMENT OF PAPER FOR SPECIAL PURPOSES

CHAPTER I. Parchment Paper, Vegetable Parchment

ARCHMENT paper is the name given to paper that has undergone such modification by treatment with sulphuric acid that it no longer softens or separates into its constituent fibres on being immersed, or even boiled, in water, but retains its coherence, is impervious to water and air, and preserves its newly acquired properties when re-dried. The parchmenting process by which this change is effected is based on the power of sulphuric acid to convert the superficial strata of pure cellulose into a gelatinous mass, which forms a pro¬ tective coating for the rest. This gelatinous mass is a substance, amyloid, similar to starch, and when subjected to the continued action of sulphuric acid undergoes further conversion into a gummy substance, wood dextrin. Amyloid therefore appears to be that conversion-product which unites the fibres so firmly and intimately as to conveit them into a coherent mass which has entirely lost the property of solubility in water, and at the same time has considerably modified the longitudinal and transverse extensibility of the fibres, whereby i

2 Treatment oe Paper for Special Purposes their strength is greatly increased. If a strip of unsized paper be dipped in sulphuric acid the fibres swell up and become coated with the aforesaid gelatinous envelope, which extends throughout the entire mass if the exposure to the acid be sufficiently prolonged. According to Hoffmann, amyloid is still imperfectly known, being regarded by some chemists as a kind of cellulose, and by others as an intermediate stage between starch and cellulose. Any one desiring to prepare amyloid as a matter of scientific interest can do so by treating 1 part of pure cotton with 30 parts of dilute sulphuric acid (4 parts of acid to 1 of water). The cotton speedily dissolves, and at the end of about half a minute forms a stiff gelatinous mass, which gradually becomes more fluid, so that in 15 minutes it attains the consistency of syrup. On treating this with water, amyloid separates out as a white, flocculent, gelatinous substance in which no fibrous structure can be detected. If the acid mass be left alone for some time longer, it gradually changes into dextrin and sugar ; and if the addition of water be delayed until 7-8 hours have elapsed, only a very small quantity of flocculent matter will be pre¬ cipitated. In presence of acids and alkalis, amyloid behaves just the same as vegetable fibres, differing from these merely in its lack of structure, and from starch inasmuch as the blue coloration imparted by iodine can be removed by washing with water.

When mixed with a sufficiency of water, amyloid has a glutinous appearance, and if spread out on a sheet of glass will dry to a thin, tough, transparent film. If dried on paper it does not adhere to the latter, but can be readily detached, though when deposited direct on paper from its solutions, as is done in the preparation of vegetable parchment, it remains unalterably combined with the fibres. Under the microscope the fibres of vegetable parchment can be plainly seen to be enveloped in a thin, transparent skin, and it is perfectly certain that, through the action of the acid, the fibres have received a coating of amyloid, from the fact that the superficial layer is stained blue by iodine, whilst the interior retains its shape unaltered, even in the case of the finest flax fibres. Unsized paper dipped in dilute sulphuric acid at ordinary temperature immediately becomes coated with a gelatinous film, and in the same way the surface of the individual fibres will suffer alteration if time be given for the acid to penetrate. On removing the paper from the acid bath and dipping it in water containing ammonia or caustic soda, the influence of the acid is stopped, and the acid mass separates into amyloid, which unites the fibres to a dense mass, and sulphuric acid which is eliminated by washing. The gelatinous film covering the surface of the paper facilitates the setting of the fibres together in drying, by permitting the escape of the water vapour expelled from the interior, but retarding the penetration of the air by which the water would otherwise be replaced. This behaviour explains the dried, transparent appearance of many kinds of such parchment.

Filter paper that has been washed with hydrochloric acid and hydrofluoric acid may be regarded as almost perfectly pure cellulose. If this, when dried, be impregnated with 50 per cent, sulphuric acid it furnishes a transparent, gelatinous mass, which will retain its appearance unchanged for any length of time. At 100° C., or even below that temperature conversion into dextrin occurs very rapidly. When thoroughly washed this colloidal cellulose, for so the mass may be termed will dissolve in pure water. The removal of the final traces of acid is facilitated by washing with ordinary alcohol, and drying at a gentle heat. When the mass is taken up’ with water it forms a rather milky fluid, which filters readily, and thereafter will not deposit any sediment, even during several days, but readily undergoes alteration on boiling. By the aid of a new Laurent compensator, it was ascertained that a 4-inch stratum of the solution of colloidal cellulose deviates the plane of polarisation f° to the right. In contrast to the achroo-dextrins this colloidal cellulose is thrown down from solution by very small quantities of extraneous sub¬ stances : sulphuric acid, nitric acid, common salt, sodium sulphate, etc., as well as by a sufficiency of alcohol. When dried on marble coated with vaseline, the colloidal cellulose gives a lustrous, semi-transparent film, which dissolves com¬ pletely in cold water. A very short immersion in sulphuric acid of G93 B. density (or a little longer if the density be 55°), renders the colloidal cellulose insoluble in that acid, a small quantity of dextrin being formed at the same time. The substance may also be nitrated under the same conditions as ordinary cellulose. The properties of colloidal cellulose afford an explanation of many circumstances noticed in making parchment. Certain very thin vegetable parchments will cede colloidal cellulose to boiling water, which is not the case with the thicker kinds, owing undoubtedly to the fact that a stronger acid is used in making the latter, the colloidal cellulose, which is also formed in this case, becoming insoluble. To some extent vegetable parchment forms a tissue of ordinary cellulose, the pores of which are filled with colloidal cellulose. That this is so can be demonstrated by applying colloidal cellulose to ordinary filter paper on both sides, allowing it to dry slowly, and then passing it through a calendering machine between two sheets of polished zinc. The resulting product exactly resembles vegetable parchment that has been satinised in the same way. Colloidal cellulose differs from any natural product that has hitherto been examined.

The alterations sustained by vegetable parchment, in com¬ parison with the paper from which it is made are somewhat extensive. For instance, the strength is increased three- or four-fold, whilst at the same time the sp. gr. increases by 32-42 per cent., and the thickness shrinks 34-37 per cent., a certain proof that the individual particles of the paper move closer together during the process. This increases the homo¬ geneity and transparency, and consequently the resemblance to animal membrane and true parchment, a circumstance to which the product owes its distinctive name.

It is an essential preliminary to the production of parchment paper that the paper forming the raw material should be perfectly free from any substances capable of retarding the process or jeopardising the formation of a uniform product. For this reason the paper used must neither be sized nor contain any mineral substances whatsoever. Long staple paper, made from rags, is the best material, though wood pulp and straw pulp are not precluded. Sulphuric acid is generally used as the parchmenting reagent, though solutions of ammoniacal copper oxide or zinc chloride are employed as being capable of effecting the same transformation.

To ensure success it is necessary that the parchmenting solution should be of a certain concentration, and used at a certain temperature ; and it may be conveniently mentioned here that these conditions are fulfilled by the use of 9-9.', parts of English concentrated sulphuric acid, or the undiluted chamber acid (60 J B.), at a temperature not exceeding 10’ C. The acid-free zinc chloride solution, obtained by dis¬ solving zinc in hydrochloric acid, should he concentrated to the consistency of syrup, and employed at a temperature which may range from 50-100° C. according to the actual con¬ centration.

The time allowed for the action of the parchmenting reagent is an important factor, and depends — apart from the nature of the liquid — on the thickness and composition (material) of the paper; pure, thin paper for instance requiring only 3-5 seconds, whilst thicker paper will take longer (up to 12 seconds). The action of the acid must be stopped immediately the proper exposure lias been given, by a thorough washing, supplemented by neutralisation with alkaline lyes, or the like, the paper being dried after a final washing with pure water. The necessary precautions to adopt in order to prevent the paper from wrinkling will be referred to later on.

To obtain a dense, strong parchment, care must be taken to see that the alteration is confined to the surface of the fibres, and that the paper employed is not porous, as this would furnish a weak, though dense product. A thin, firmly twisted cotton thread, for example, will receive a greater accession of strength by treatment with sulphuric acid, than a loosely twisted one of twice the thickness. Thin, dense cotton material, the fibres of which have been forced closely together by pressing before putting them through the acid treatment, will yield an article of such strength that in many cases it can be used as a substitute for leather, and when made supple by greasing is capable of numerous applications.

At the present time paper in sheets is rarely used for making parchment paper on a manufacturing scale ; and the operation of dipping the paper in the acid bath is almost invariably performed by machinery. A sufficient length of unsized paper, mounted on rollers, is introduced into a lead or glass tank, and is passed round a lead or glass roller, through the acid bath. Before leaving the tank the dipped paper traverses a pair of squeezing rollers, to express the surplus liquid, and is afterwards led through a series of washing tanks supplied with a constant flow of fresh water. To eliminate the last traces of acid, the paper is finally passed through a washing tank, the water in which receives an addition of alkali at intervals, and the operation is completed by rinsing in pure water. The more effective the washing before the paper reaches the neutralising tank, the smaller the con¬ sumption of ammonia ; and it is therefore to the interest of the manufacturer to wash the paper so completely as to render the use of ammonia a supplementary, rather than a necessary, precaution. After the final rinsing the paper is passed through a pair of felt rollers, to remove as much of the water as possible, ancl is then stretched between layers of dry felt on a drying cylinder, from which it is removed before it becomes quite dry, and is smoothed between rollers heated by steam. During the drying process it is essential that the parchment paper should be kept well stretched transversely, since it shrinks much more than ordinary paper, and would otherwise become uneven. Very thick parchment paper is made by passing two separate layers of paper through the acid bath, then uniting them in front of the first pair of rollers before entering the washing tanks, and passing them together through the pressure rollers. In this way the two layers will adhere so firmly together that they cannot afterwards be separated.

The peculiar properties of parchment paper render it suitable for numerous applications, such as legal and other documents, insurance certificates, banknotes, drafts, important records, and in fact all documents whose preservation is a matter of importance. One method sometimes adopted for preserving these documents against fire is to pack them in strong boxes, which are then allowed to become encrusted with crystals of alum or some other salt. In the event of fire, the water of crystallisation is converted into steam, which protects the parchment paper documents more effectually from destruction than if ordinary paper had been used. Parchment paper is also far better able to withstand insect ravages than ordinary paper; and this power may be still further increased by incorporating certain compounds (mercury salts, for example) with the paper before it is treated with acid. It can also be recommended for making banknotes, since the lettering on paper that has been parchmented after printing can no longer be scratched out without entirely destroying the substance of the paper itself. Another advantage of parchment paper is, that writing on such paper is very difficult to remove and replace by fresh text, so that a considerable degree of security

8 Treatment of Parer for Special Purposes is afforded against falsification. Owing to its strength and durability, parchment paper is adapted for plans, especially those made for building purposes and exposed to wet weather and careless handling. The thin, transparent sheets make very good tracing paper. Parchment paper can also be largely used for binding books, being durable and of excellent appearance. This latter quality also characterises books, cards, etc., made of the same material, the paper being printed after being parchmented, since it shrinks under the acid treatment. Parchment paper readily absorbs printer’s ink, as well as ordinary writing ink, and it will fix dyestuffs in general more readily than calico does, for instance. There is no need to expatiate on its usefulness for covering glasses and other vessels containing substances liable to deterioration, such as preserves, extracts, etc., for wrapping fatty products or the like, for capsuling corked bottles, and so forth. Furthermore, it serves for wrapping tobacco and other substances, to prevent the escape of contained moisture or the absorption of moisture from the air. Still further applications are for luting the joints of stills and other apparatus, making small bags, the edges of which are cemented with gelatine, for cooking and steaming food, etc.

The properties of parchment paper are detailed by Kletzinsky as follows :

“Vegetable parchment is unaffected by caustic potash, and will also resist the action of cold acid better than animal membrane. Experiments have shown that parchment paper forms just as good a covering for receptacles as the best animal bladder. Hot, concentrated hydrochloric acid will dissolve phyto parchment to glucose, apart from a small fibrous residue."

When vegetable parchment is soaked in water, which is then heated to boiling and treated with sulphuric acid, a somewhat violent reaction ensues, and if the resulting dark brown acid pulp be at once diluted with water, a slightly coloured solution of sugar is obtained that can be freed from sulphuric acid by adding milk of lime. The precipitated gypsum carries down with it the undecomposed particles of paper, and clarifies the liquid, which can then be treated for tbe production of alcohol. If the manufacture of parchment paper should ever attain the degree of importance it deserves, the waste products will easily find a more suitable application than conversion into spirit.

Given careful preparation and sufficient washing, no increase occurs in the weight of the paper, the amount of sulphuric acid retained being imponderable ; and consequently the remark¬ able and technically valuable alteration sustained by the paper in the acid treatment is purely molecular. Equally surprising are the shrinkage and contraction set up in the process. The paper becomes slightly thicker, but its super¬ ficial area diminishes by 10-30 per cent, according as the exposure to the acid bath ranges between 10 and 15 seconds ; this shrinkage being in no way compensated by the slight increase in thickness, the augmented strength is at once explained on a physical basis.

With regard to the use of parchment paper for closing glasses containing alcoholic liquids, the following statement is made: A wide sugar-glass was filled half full of strong spirit, and then tied up with moistened parchment paper. When dried, it set as firm and hard as pig’s bladder. After the vessel had stood in a warm place for three weeks, only a very small quantity of the alcohol had evaporated : in fact, the strength of the spirit had increased to a small extent (about \ a degree). This is not difficult to understand when it is remembered that both paper and bladder are more permeable to water vapour than to that of spirit.

The behaviour of parchment toward white or fuming nitric acid, of sp. gr. 1 *4—1 '6, is important. If a sulphuric parchment be dipped in such acid for 10 minutes at least, and then washed thoroughly with water, it will be found to have increased 10-20 per cent, in thickness, and to a considerable degree in strength, the shrinkage of superficial area being much smaller. When washed and dried under moderate pressure it exhibits a perfect resemblance to parchment, with greatly increased powers of resistance to mechanical abrasion and atmospheric influences. When dried and re-dipped in dilute sulphuric acid this nitro-parchment becomes glass-clear and transparent, besides being more resistant to acids. On the other hand, it dissolves to a golden yellow solution in boiling caustic potash, and like all other nitro-compounds it burns readily like touch-paper.

Experiments have been made to determine the comparative strength of parchment paper, ordinary paper, and animal parchment. With this object, test strips of parchment paper and parchment were cut to a length of 22‘2 mm., the ends being then clamped to horizontal cylinders, so as to form a loop of the material in each case. Through each loop was passed a small wooden cylinder, fitted at the ends with small cords supporting a pan for the reception of weights, and the pans were weighted until the test strips broke. A series of these trials showed that parchment paper has about five times the strength of the paper from which it is made, and that parchment paper is about three-fourths as strong as ordinary parchment of equal thickness. It was also found that the strips of parchment paper are very unequal in thickness, con¬ siderable differences in this respect being observable even in strips cut from one and the same piece.

Although parchment paper may be inferior to the real article in point of strength, it is far superior in its power of resisting the influence of chemical reagents, water in particular, for whilst it absorbs an equal quantity of that liquid and becomes perfectly soft and flexible, it can be left in contact therewith for several days, and even boiled, without suffering in the least.

Parchment Paper, Vegetable Parchment i i

When dried again it regains its original appearance and' strength. Ordinary animal parchment on the other hand is soon attacked by boiling water, and is gradually changed into gelatine. Even at the ordinary temperature it is very prone to putrefy in presence of moisture, whereas the n on-nitrogenous vegetable parchment can be exposed to moisture without suffer¬ ing the slightest alteration.

From experiments made by A. Sudicke with parchment paper from the Helfenberg Works, near Dresden, it appears that paper in the course of transformation into vegetable parchment increases in thickness by about 34-44 per cent., and by 32-42 per cent, in specific gravity. The strength of the crude paper Avas 2f-3 lb. per sq. yd., and that of the finished parchment paper 10|-12| lb.

For many purposes it is necessary that parchment paper should be sized ; and tubes of this paper intended to replace sausage skins, require to be fastened with some adhesive, the provision of which was found somewhat difficult at first, until Jacobsen succeeded in devising a suitable preparation. The reliability of this preparation was tested in a large sausage factory in Berlin, some two million tubes being tried.

When several sheets of parchment paper are gummed to¬ gether, they form an extremely strong material, greatly resembling real parchment, and valuable to the bookbinder. Again, parchment paper gummed on to packing cloth makes a waterproof wrapping that should find extensive application.

The opening of the book is shown; the full text loads in the reader.

Loading the full text…