Part III
Scientific Pursuits:
INCLUDING
ACOUSTICS. AERONAUTICS. CHEMISTRY. ELECTRICITY. GALVANISM. HEAT. HYDRAULICS. MAGNETISM. MECHANICS. MICROSCOPE. OPTICS AND OPTICAL ILLUSIONS. PHOTOGRAPHY. PNEUMATICS. SPECTRUM.
ACOUSTICS.
Acoustics is the science relating to sound and hearing. Sound is heard when any shock or impulse is given to the air, or to any other body which is in contact directly or indirectly with the ear.
DIFFERENCE BETWEEN SOUND AND NOISE.
Noises are made by the cracks of whips, the beating of hammers, the creak of a file or saw, or the hubbub of a multitude. But when a bell is struck, the bow of a violin drawn across the strings, or the wetted finger turned round a musical glass, we have what are properly called sounds.
SOUNDS, HOW PROPAGATED.
Sounds are propagated on all bodies much after the manner that waves are in water, with a velocity of 1,142 feet in a second. Sounds in liquids and in solids are more rapid than in air. Two stones rubbed together may be heard in water at half a mile; solid bodies convey sounds to great distances, and pipes may be made to convey the voice over every part of the house.
TO SHOW HOW SOUND TRAVELS THROUGH A SOLID.
Take a long piece of wood, such as the handle of a hair broom, and placing a watch at one end, apply your ear to the other, and the tickings will be distinctly heard.
TO SHOW THAT SOUND DEPENDS ON VIBRATION.
Touch a bell when it is sounding, and the noise ceases; the same may be done to a musical string with the same results. Hold a musical pitch-fork to the lips, when it is made to sound, and a quivering motion will be felt from its vibrations. These experiments show that sound is produced by the quick motions and vibrations of different bodies.
MUSICAL FIGURES RESULTING FROM SOUND.
Cover the mouth of a wine glass, having a foot-stalk, with a thin sheet of membrane, over which scatter a layer of fine sand. The vibrations excited in the air by the sound of a musical instrument, held within a few inches of the membrane, will cause the sand on its surface to form regular lines and figures with astonishing celerity, which vary with the sound produced.
TO MAKE AN ÆOLIAN HARP.
This instrument consists of a long narrow box of very thin deal, about six inches deep, with a circle in the middle of the upper side of an inch and a half in diameter, in which are to be drilled small holes. On this side seven, ten, or more strings of very fine catgut are stretched over bridges at each end like the bridges of a fiddle, and screwed up or relaxed with screw pins. The strings must all be tuned to one and the same note,[5] and the instrument should be placed in a window partly open, in which the width is exactly equal to the length of the harp, with the sash just raised to give the air admission. When the air blows upon these strings with different degrees of force, it will excite different tones of sound. Sometimes the blast brings out all the tones in full concert, and sometimes it sinks them to the softest murmurs.
[5] D is a good note for it. The upper string may be tuned to the upper D, and the two lower to the lower D and D D. The “harmonics” are the sounds produced.
A colossal imitation of the instrument just described was invented at Milan in 1786, by the Abbate Gattoni. He stretched seven strong iron wires, tuned to the notes of the gamut, from the top of a tower sixty feet high, to the house of a Signor Moscate, who was interested in the success of the experiment; and this apparatus, called the “giant’s harp,” in blowing weather yielded lengthened peals of harmonious music. In a storm this music was heard at a greater distance.
THE INVISIBLE GIRL.
The facility with which the voice circulates through tubes was known to the ancients, and no doubt has afforded the priests of all religions means of deception to the ignorant and credulous. But of late days the light of science dispels all such wicked deceptions. A very clever machine was produced at Paris several years ago, and afterwards exhibited in London under the name of the “Invisible Girl,” since the apparatus was so constructed that the voice of a female at a distance was heard as if it originated from a hollow globe, not more than a foot in diameter. It consisted of a wooden frame something like a tent bedstead, formed by four pillars a a a a, connected by upper cross rails b b, and similar rails below, while it terminated above in four bent wires c c, proceeding at right angles of the frame, and meeting in a central point. The hollow copper ball d, with four trumpets t t, crossing from it at right angles, hung in the centre of the frame, being connected with the wires alone by four narrow ribbons r r. The questions were proposed close to the open mouth of one of these trumpets, and the reply was returned from the same orifice. The means used in the deception were as follow: a pipe or tube was attached to one of the hollow pillars, and carried into another apartment, in which a female was placed; and this tube having been carried up the leg or pillar of the instrument to the cross-rails, had an aperture exactly opposite two of the trumpet mouths; so that what was spoken was immediately answered through a very simple mode of communication.
VENTRILOQUISM.
This is an art by no means very difficult of acquirement, if the young reader will take the pains. It is produced by a reflection of sound within the mouth, the voice being brought to the lowest possible place in the larynx. When the art is acquired by practice, the voice may be made to appear as if coming from any part of a room, from up a chimney, or from the depths of a cellar. The celebrated Dr. Wolcott, better known as Peter Pindar, used to amuse his friends in a remarkable manner with this art. He would represent his landlady as demanding payment of her rent, and hold a colloquy with her, which would at last rise to terms of reproach and fury, and end by a noise as if the landlady had been kicked down stairs. The marvellous powers of Matthews, Le Lagg, Alexander, and, lastly, Mr. Love, are familiar to most persons. To learn the art, the young practitioner must have the power of enunciating well, and that without motion of the lips,--of disguising the voice, so as to imitate other sounds,--and of adapting the degree to the apparent source of the sound. By practice this art is attainable by any person whose organs of speech are completely and fully developed.
AERONAUTICS.
BALLOONS.
The art of sailing or navigating a body through the air is called aëronautics. In remote ages, Icarus is said to have risen so high in the air that the sun melted his wings, and he fell into the Ægean sea, and was drowned; and there is reason to believe, from some figures that have recently been discovered on Egyptian and Assyrian monuments, that the ancients possessed means of rising in the air with which we are not now acquainted.
The air-balloon, as now constructed, is a bag of silk of large dimensions, usually cut in gores, and is, when expanded by gas, of a pear-shape. It ascends in the atmosphere because its whole bulk is much lighter than the air would be in the space it occupies. It is, in fact, a vessel filled with a fluid which will float on another fluid lighter than itself.
HOW TO MAKE AN AIR-BALLOON.
The best shape for an air-balloon, or rather a gas-balloon, is that of a pegtop. And in preparing the gores proceed as follows: Get some close texture silk, and cut it into a form resembling a narrow pear with a very thin stalk. Fourteen of these pieces will be found to be the best number; and, of course, the breadths of each piece must be measured accordingly. When sewing them together, it will be of advantage to coat the parts that overlap with a layer of varnish, as this will save much trouble afterwards, and hold the silk firmer in its place during the stitching. The threads must be placed very regularly, or the balloon will be drawn out of shape, and it will be found useful if the gores are covered with an interior coating of varnish before they are finally sewn together. Take care not to have the varnish too thick. To the upper part of the balloon there should be a valve opening inwards, to which a string should be fastened, passing through a hole made in a small piece of wood fixed in the lower part of the balloon, so that the aeronaut may open the valve when he wishes to descend; and this should be imitated on a small scale, so that the young aëronaut may be perfectly familiar with the construction of a balloon. The gores are to be covered with a varnish of India-rubber dissolved in a mixture of turpentine and naphtha. Over the whole of the upper part should be a net-work, which should come down to the middle with various cords, proceeding from it to the circumference of a circle about two feet below the balloon. The circle may be made of wood, or of several pieces of slender cane bound together. The meshes should be small at top, against which part of the balloon the inflammable air exerts the greatest force, and increase in size as they recede from the top.
The car is made of wicker-work; it is usually covered with leather, and is well varnished or painted. It is suspended by ropes proceeding from the net which goes over the balloon. Balloons of this kind cannot be made smaller than six feet in diameter, of oiled silk, as the weight of the material is too great for the air to buoy it up. They may be made smaller of thin slips of bladder, or other membrane glued together, or of thin gutta-percha cloth, which is now extensively used for this purpose; with this they may be made a foot in diameter, and will rise beautifully.
HOW TO FILL A BALLOON.
Procure a large stone bottle which will hold a gallon of water, into this put a pound of iron filings, or granulated zinc, with two quarts of water, and add to this by degrees one pint of sulphuric acid. Then take a tube, either of glass or metal, and introduce one end of it through a cork, which place in the bottle, then put the other end into the neck of the balloon, and the gas will rise into the body of it. When quite full withdraw the tube, and tie the neck of the balloon with strong cord very tightly. If freed it will now rise in the air.
TO MAKE FIRE-BALLOONS.
Cut the gores, according to the forms already given, from well-woven tissue paper, paste the gores nicely together, and look well over the surface of the paper for any small hole or slit, over which paste a piece of paper, and let it dry. Pass a wire round the neck of the balloon, and have two cross pieces at its diameter a little bent, so that a piece of soft cotton dipped in spirits of wine may be laid on them. When all is prepared let some one hold the balloon from its top by means of a stick, while you dip the cotton in spirits of wine till it is thoroughly saturated, place it under the balloon and set fire to it, but be very careful you do not set fire to the balloon. When the air is sufficiently heated within, the balloon will indicate a desire to rise, and when it pulls very hard, let it go, and it will ascend to a great height in the air, and at night present a very beautiful appearance.
PARACHUTES.
These are easily made by cutting a piece of paper in a circular form, and placing threads round the edges, which may be made to converge to a point, at which a cork may be placed as a balance. They ascend by the air getting under them, and are frequently blown to a great distance.
CHEMISTRY.
In the eleventh century, and during the reign of King Henry the First, surnamed Beauclerk, or the fine scholar, there appeared for the first time in certain books, professing to teach the art making of gold, the words chemistry, chemist, derived from the Greek χημεία. Seven hundred years and more have passed away, and that which was only the pursuit of a shadow called alchemy, has resulted in the acquisition of a great and noble science, now and again called chemistry. When we go to the French Exposition, we shall doubtless pass by much that is worthy of notice, and bring away with us only a general impression of the wonders it contains. So it is with the great edifice Chemistry; we may, in these brief pages, peep in at the open door, but should we desire to go beyond the threshold, there are numerous guides, such as Roscoe, Wilson, and Fownes, who will conduct us through the mazes of the interior, and explain in elementary language the beautiful processes which have become so useful to mankind.
Chemistry is one of the most comprehensive of all the sciences, and at the same time one which comes home to us in the most ordinary of our daily avocations. Most of the arts of life are indebted to it for their very existence, and nearly all have been, from time to time, improved by the application of its principles.
Chemistry is, in fact, the science which treats of the composition of all material bodies, and of the means of forming them into new combinations, and reducing them to their ultimate elements, as they are termed, that is, bodies which we are unable to split up, as it were, or separate into other bodies. To take a common substance as an illustration; water, by a great number of processes, can be separated into two other substances, called oxygen and hydrogen, in the proportion by weight of 8 parts of the first to 1 of the second; but no power that we at present possess can separate the oxygen and hydrogen into any other bodies; they are therefore called ultimate elements, or undecomposable bodies.
Again, sulphate of magnesia (common Epsom salts) can be very easily separated into two other substances,--sulphuric acid and magnesia; and in this instance, both these substances can again be sub-divided--the acid into sulphur and oxygen, and the magnesia into a metallic body called magnesium and oxygen; but sulphur, oxygen, and magnesium are incapable of further division, and are therefore called ultimate elements.
These ultimate elements amount to 64 in number, according to the present state of our knowledge, and may be arranged in various ways; the simplest plan, perhaps, is dividing them into Non-metallic and Metallic elements.
The Non-metallic elements are:--1. Oxygen. 2. Hydrogen. 3. Nitrogen. 4. Chlorine. 5. Iodine. 6. Bromine. 7. Fluorine. 8. Carbon. 9. Sulphur. 10. Selenium. 11. Tellurium. 12. Silicon. 13. Boron. 14. Phosphorus. The last-named element is the connecting link with the metals through arsenic, which phosphorus closely resembles in its chemical properties.
The Metallic elements may be sub-divided into the metals of the alkalies, the metals of the alkaline earths, the metals of the earths, and the other metals sometimes called metals proper.
1st. The metallic bases of the alkalies:--potassium, sodium, lithium, ammonium, cæsium, rubidium.
2d. The metallic bases of the alkaline earths:--calcium, strontium, barium.
3d. The metallic bases of the earths:--aluminium, glucinum, zirconium, thorium, yttrium, erbium, cerium, lanthanum, didymium.
4th. The metals proper, the most important of which are:--platinum, gold, silver, mercury, copper, iron, tin, lead, nickel, zinc, bismuth, antimony, manganese, cobalt, arsenic.
Now, from these elementary bodies, united together in various proportions, is formed the infinite variety of substances around us, whether animal, vegetable, or mineral; in fact, a few only are generally employed;--in the case of animals and vegetables, oxygen, hydrogen, carbon, nitrogen, with occasionally some sulphur, calcium, phosphorus, and silicon, suffice for building up the beautiful forms of animated nature; while the fabric of our globe itself consists for the most part of the earths; silex, i. e. flint or crystal; lime, in the shape of chalk, marble, or limestone, such as our flagstones are composed of; slate and granite, which are compounds of aluminium, silica, and small quantities of oxide of iron, and sometimes a little potash, &c.; and through their masses are projected irregular streams--veins as they are termed--of the metals, either in a pure state, as is the case sometimes with gold, silver, platinum, mercury, and perhaps one or two others; or combined with one of the non-metallic elements, or with one another.
Late calculations have determined the composition of the earth’s solid crust in 100 parts by weight to be
Oxygen 44·0 to 48·7 Silicon 22·8 „ 36·2 Aluminium 9·9 „ 6·1 Iron 9·9 „ 2·4 Calcium 6·6 „ 0·9 Magnesium 2·7 „ 0·1 Sodium 2·4 „ 2·5 Potassium 1·7 „ 3·1 ----- ----- 100· 100· ===== =====
All these combinations are effected by certain powers, termed forces; those which cause the union of the elements are called the forces of attraction; those causing their separation, the forces of repulsion.
The force of attraction when exerted between masses of matter, is termed gravitation; when it unites particles of matter of a similar kind and produces masses, it is called the attraction of cohesion; when the particles united are of a dissimilar character, it is then termed chemical or elective affinity. For example, the crystals of Epsom salts are formed from minute particles of the salt, united into a larger or smaller mass by the attraction of cohesion, while the elements of which each particle consists, namely, the sulphur, oxygen, and magnesium, are united by the attraction of chemical affinity.
Cohesion thus unites particles of a similar kind; chemical affinity, of a dissimilar nature. It is to cohesion that the existence of masses of matter is owing, and its power increases as the squares of the distances diminish, in an inverse ratio to the squares of the distances of the particles on which it acts.
The power exerted by cohesion may be exhibited in various ways. This is one: Procure two discs of glass about three inches in diameter, their surfaces being ground extremely smooth; fix each into a square piece of wood, taking care that they are placed accurately in the centre; then put them together, by sliding their edges very carefully over each other, so as to avoid any air getting between them, and you will find a great force necessary to separate them. A hook should be fixed into the centre of each piece of wood, so that they may be suspended, and a weight hung to the lower one. It is almost impossible for any one to separate them by merely pulling them with both hands; a weight of many pounds is required for that purpose. In like manner two freshly-cut surfaces of caoutchouc will, on being squeezed together, cohere so perfectly, that it is difficult to tear them asunder, and it is in this way that tubes of caoutchouc may be rapidly prepared for experiments, where little or no pressure is exerted.
Chemical affinity is sometimes called elective, or the effect of choice, as if one substance exerted a kind of preference for another, and chose to be united to it rather than to that with which it was previously combined; thus, if you pour some vinegar, which is a weak acetic acid, upon some pearlash (a combination of potash and carbonic acid), or some carbonate of soda (a combination of the same acid with soda), a violent effervescence will take place, occasioned by the escape of the carbonic acid, displaced in consequence of the potash or soda preferring the acetic acid, and forming a compound called an acetate. Then, if some sulphuric acid be poured on this new compound, the acetic acid will in its turn be displaced by the greater attachment of either of the bases, as they are termed, for the sulphuric acid. Again, if into a solution of blue vitriol (a combination of sulphuric acid with oxide of copper) the bright blade of a knife be introduced, the knife will speedily be covered with a coat of copper, deposited in consequence of the acid preferring the iron, of which the knife is made, a quantity of it being dissolved in exact proportion to the quantity of copper deposited.
It is on the same principle that a very beautiful preparation, called a silver-tree, or a lead-tree, may be formed thus:--Fill a wide bottle, capable of holding from half a pint to a pint, with a tolerably strong solution of nitrate of silver (lunar caustic), or acetate of lead, in pure distilled water; then attach a small piece of zinc by a string to the cork or stopper of the bottle, so that the zinc shall hang about the middle of the bottle, and set it by where it may be quite undisturbed; in a short time, brilliant plates of silver or lead, as the case may be, will be seen to collect around the piece of zinc, assuming more or less of the crystalline form. This at first is a case of elective affinity; the acid with which the silver or lead was united prefers the zinc to either of those metals and in consequence discards them in order to attach the zinc to itself, subsequently a voltaic current is set up between the two metals, and the process will continue until almost the whole of the zinc is taken up, or nearly the whole of the silver or lead deposited.
Again, many animal and vegetable substances consist for the most part of carbon or charcoal, united with oxygen and hydrogen in the proportion which forms water. Now oil of vitriol (strong sulphuric acid) has so powerful an affinity, or so great a thirst for water, that it will abstract it from almost any body in which it exists; if you then pour some of this acid on a lump of sugar, or place a chip of wood in it, the sugar or wood will speedily become quite black, or be charred, as it is called, in consequence of the oxygen and hydrogen being removed by the sulphuric acid, and only the carbon, or charcoal, left.
When Cleopatra dissolved pearls of wondrous value in vinegar, she was exhibiting unwittingly an instance of chemical elective affinity; the pearl being simply carbonate of lime, which was decomposed by the greater affinity or fondness of lime for its new acquaintance (the acetic acid of the vinegar) than for the carbonic acid, with which it had been united all its life,--an example of inconstancy in strong contrast with the conduct of its owner, who chose death rather than become the mistress of her lover’s conqueror.
GASES.
The three permanent gaseous elements are oxygen, hydrogen, and nitrogen.
The compound gases are very numerous, some being combustible, and others supporters of combustion.
Gases are for the most part transparent and colourless, with a few exceptions, and of course, like the air of the atmosphere, invisible. They are little affected by the attraction of cohesion, but rather, on the contrary, the particles composing them have a constant tendency to separate from each other, so that their force of expansion is only limited by the pressure under which they may be kept, and the temperature they may be exposed to. They have a tendency to penetrate each other, as it were; for instance, if you take a jar of heavy gas, such as carbonic gas, set it with its mouth upwards, then invert over it another jar containing hydrogen, a gas nearly twenty-two times lighter; in a very short time the two gases will have become thoroughly mixed, the heavy carbonic acid having risen, and the light hydrogen fallen, until the gases are thoroughly mixed, each jar containing an equal quantity of each gas.
OXYGEN GAS.
This gas, so named from two Greek words signifying the maker of acid, was discovered by Dr. Priestly in 1774. He obtained it by heating the red oxide of mercury in a glass retort, when the gas escaped in considerable quantities. In the ensuing year Scheele obtained it by a variety of methods, and a few years afterwards Lavoisier discovered that it was contained in atmospheric air, where it exists in the proportion of about one-fifth, the remaining four-fifths being almost entirely nitrogen.
Oxygen gas may be obtained for the purpose of experiment, by heating to redness the black oxide of manganese in an iron bottle, to the mouth of which a flexible tube is attached to convey away the gas as fast as it is liberated from the manganese. The first portions should be allowed to escape, being mixed with the air in the tubes and bottle, and the remainder may be collected in a gasometer, or in glass jars inverted over water.
Another method to obtain the gas, and one to be used only in the absence of other ingredients, is to mix in a retort some of this same oxide of manganese with about half its weight of strong sulphuric acid, and apply heat to the retort, when the gas will come over in considerable quantities; the first portions must be allowed to escape as before.[6] If the gas is required very pure, a small quantity of the salt called chlorate of potassa may be heated in a retort, and oxygen gas will be evolved, and may be collected as before. If you have an iron bottle, the first mode is by far the cheapest, as the heat of a bright fire is sufficient for the operation, and a large quantity of gas is obtained in a short time from a very inexpensive material. The most rapid and convenient process of all is to heat a mixture of two parts chlorate of potash, and one of powdered black oxide of manganese, in a common clean oil flask, to which a cork and bent tube has been adapted. Care must be taken not to mistake sulphide of antimony for black oxide of manganese, as very serious accidents have arisen from this cause.
[6] Some boiling water should be added to the mass left in the retort directly the gas has ceased to come away, or it will adhere to the glass so firmly, that the retort will certainly be spoilt.
Oxygen is largely distributed over our globe, both in its uncombined state, and in union with other substances. Besides forming one-fifth of the atmosphere, it forms eight-ninths by weight of all the water in the ocean, rivers, and springs on the face of the whole earth. It also, in combination with various metals, forms the various earths and minerals of which the crust of the earth consists, so that it is the most abundant and widely distributed substance in nature, and in combination with other elements, forms nearly half the weight of the solid earth.
In its uncombined state it is a colourless gas, somewhat heavier than atmospheric air, without taste or smell. It is a powerful supporter of combustion, and is absolutely necessary for the support of animal life, which cannot exist for any time without a free supply of this gas, which is constantly consumed in the act of breathing, and is replaced by an equivalent portion of carbonic acid gas. The want of oxygen is partly the cause of the oppression felt in crowded rooms, where the air cannot be renewed so fast as is required for the number of persons who are constantly consuming the oxygen; and if an animal be confined under a glass jar inverted over water, it will presently die, just for the same reason that burning tapers are extinguished under similar circumstances.
If a jet of this gas be thrown upon a piece of charcoal, sulphur, or almost any combustible body in a state of ignition, it will make it burn with great vividness and rapidity. For a complete series of experiments with oxygen see “The Boy’s Play-book of Science.”
EXPERIMENT.
But by far the most intense heat, and most brilliant light, may be produced by introducing a piece of phosphorus into a jar of oxygen. The phosphorus may be placed in a small copper cup, with a long handle of thick wire passing through a hole in a cork that fits the jar. The phosphorus must first be ignited; and, as soon as it is introduced into the oxygen, it gives out a light so brilliant that no eye can bear it, and the whole jar appears filled with an intensely luminous atmosphere. It is well to dilute the oxygen with about one-fourth part of common air to moderate the intense heat which is nearly certain to break the jar if pure oxygen is used.
EXPERIMENT.
If a piece of charcoal, which is pure carbon or nearly so, be ignited, and introduced into a jar containing oxygen or common atmospheric air, the product will be carbonic gas only, of which we shall speak presently. As most combustible bodies contain both carbon and hydrogen, the result of their combination is carbonic acid and water. This is the case with the gas used for illumination; and in order to prevent the water so produced from spoiling goods in shops, various plans have been devised for carrying off the water when in the state of steam. This is generally accomplished by suspending over the burners glass bells, communicating with tubes opening into the chimney, or passing outside the house.
To show that oxygen, or some equivalent, is necessary for the support of combustion, fix two or three pieces of wax-taper on flat pieces of cork, and set them floating on water in a soup-plate, light them, and invert over them a glass jar; as they burn, the heat produced may perhaps at first expand the air so as to force a small quantity out of the jar, but the water will soon rise in the jar, and continue to do so until the tapers expire, when you will find that a considerable portion of the air has disappeared, and what remains will no longer support flame; that is, the oxygen has been converted partly into water, and partly into carbonic acid gas, by uniting with the carbon and hydrogen, of which the taper consists, and the remaining air is principally nitrogen, with some carbonic acid; the presence of the latter may be proved by decanting some of the remaining air into a bottle, and then shaking some lime-water with it, which will absorb the carbonic acid and form chalk, rendering the water quite turbid.
NITROGEN.
This gas is, as its name implies, the producer of nitre, or at least forms a portion of the nitric acid contained in nitre. It is rather lighter than atmospheric air, colourless, transparent, incapable of supporting animal life, on which account it is sometimes called azote--an objectionable name, as it is not a poison like many other gases, but destroys life only in the absence of oxygen. This gas extinguishes all burning bodies plunged into it, and does not itself burn. It exists largely in nature, for four-fifths of the atmosphere consists of nitrogen gas. It is also an important constituent of animal bodies, and is found in the vegetable world.
Nitrogen may be most easily obtained for experiment by setting fire to some phosphorus contained in a porcelain or metallic cup, placed under a gas jar full of air, and resting on the shelf of the pneumatic trough, or in a soup-plate filled with water.
Nitrogen combines in five different proportions with oxygen, producing five distinct chemical compounds, named respectively nitrous oxide, nitric oxide, nitric tri-oxide, nitric tetr-oxide, nitric pent-oxide, which last, united with water, forms nitric acid, now called hydric nitrate, as nitrous acid is termed hydric nitrite.
Nitrous oxide gas is generally known by the name of “laughing gas,” from the jolly sensations experienced on inhaling it. It may be procured by distilling in a glass retort a salt called nitrate of ammonia, which yields the gas in considerable quantities, and it should be kept standing in jars over water for some hours before it is used. It should be transferred into a silk air-tight bag, furnished with a stopcock and mouthpiece, from which the gas may be breathed; a little practice is required to do this easily, and more resolution to desist when the gas begins to produce its effects, as it appears to fascinate the experimenter, and actual force is often necessary to remove the bag from the mouth. The effects produced vary according to the temperament of the person inhaling it; they are, however, always of a highly pleasurable nature, muscular action being generally greatly exalted, compelling the individual to race round the apartment and execute leaps and pirouettes perfectly astounding. Some persons shout and sing, and I have seen one expend his superfluous animation in twisting his features into such ludicrous grimaces as would be the envy of the candidates at a grinning match, and beat them all out of the field. Sir H. Davy was the discoverer of this gas, and of its peculiar effects on the nervous system, and a full account of it may be found in his “Researches on Nitrous Oxide Gas.”
This gas is heavier than air, and supports combustion nearly as energetically as oxygen, as may be shown by introducing a piece of ignited phosphorus into a jar of this gas. It will not, however, support the life of small animals, such as mice, which introduced into it die very quickly.
The next compound of nitrogen with oxygen, when one proportion of nitrogen unites with two of oxygen, is termed nit_ric_ oxide gas. It may be easily procured by heating in a retort some copper turnings in dilute nitric acid. It is colourless and transparent, and has the property of combining with oxygen to form other compounds.
EXPERIMENT.
Into a jar of this gas standing over water pass some oxygen gas. The jar will be filled with red fumes, which will be rapidly absorbed by the water. If atmospheric air be used instead of oxygen, there will remain in the jar the nitrogen of the air, amounting to four-fifths of the air employed.
This gas is destructive to animal life, in consequence of its property of uniting with the oxygen in the lungs, and producing the highly corrosive nitrous acid gas. It will, however, support the combustion of a few substances, phosphorus for instance, provided it is sufficiently heated before being plunged into the gas.
We pass over the third and fourth compounds of nitrogen with oxygen, as they are not calculated for amusing experiments. Nitric acid is easily prepared on the small scale, by gradually heating equal parts by weight of nitric and sulphuric acid in a retort to which a receiver has been adapted. The receiver, which may be a clean oil flask, should be kept cool with wetted blotting paper.
Nitrogen combines with chlorine and iodine, forming detonating compounds, the former being so extremely dangerous that it will be better to pass it by.
The compound with iodine, called iodide of nitrogen, may very easily be made by pouring strong solution of ammonia (a compound of nitrogen and hydrogen) upon some iodine in a phial, shaking them well together, and after letting them stand for a few hours, pouring off the fluid; the black powder remaining in the phial is the explosive compound, the iodide of nitrogen. When dry, it is very apt to detonate spontaneously; it should therefore be shaken out of the phial while wet, and spread in very small quantities on separate pieces of blotting paper, which should be kept apart from each other. When thoroughly dry, the slightest touch with the point of a feather, shaking the paper on which it rests, or even opening too rapidly the door of a closet where it has been put to dry, will cause it to explode, producing a quantity of violet-coloured fumes. The explosion is somewhat violent, producing a sharp cracking noise; and the greatest care should be taken in experimenting with it.
ATMOSPHERIC AIR.
As has been already mentioned, nitrogen is the principal constituent of the air of the atmosphere which surrounds our globe, extending to a height of about forty-five miles above it, and playing a most important part in the economy of nature, inorganic as well as organic.
This atmospheric air consists by volume of nearly four-fifths of nitrogen, and rather more than one-fifth of oxygen, viz. seventy-nine of the former to twenty-one of the latter, or twenty-three parts by weight of oxygen and seventy-seven of nitrogen; it generally contains also a variable proportion of the vapour of water, and a very small quantity of carbonic acid gas, being only about four volumes to 10,000 of air. Its constituent parts are easily separated, as it is a mechanical mixture and not a chemical compound, though the mixture by diffusion is so complete that chemists have not been able to ascertain any difference in the composition of air taken from all parts of the world, and from different heights, up to the highest point which has to this time been attained.
The atmosphere presses on the surface of the globe, and every being on it, with a force of about fifteen pounds to every square inch of surface, but as it presses equally in all directions, upwards as well as downwards, its weight cannot be perceived unless the pressure be removed from one surface by some artificial means.
Atmospheric air contains, besides the oxygen and nitrogen, its principal constituents, a small proportion of carbonic acid gas, as has been mentioned, and this may be shown by filling a tube about half full of lime-water, and shaking it with the air contained in the other half, when it will become slightly turbid from the insoluble carbonate of lime formed.
When we consider that every living animal is constantly consuming oxygen, and replacing it by carbonic acid gas, and that all burning bodies, fires in our dwellings, furnaces, artificial lights of all kinds, act in the same way in abstracting the oxygen from the air, and replacing it by immense quantities of carbonic acid gas, which is a poison to all animals who breathe, or attempt to breathe it, we must wonder what becomes of this irrespirable gas, as it is found to exist in the air in quantities so minute, and by what means the oxygen is restored, and the air again made fit for respiration. This is effected by one of those laws which the wisdom of the Creator has impressed upon matter, by which one part of creation as it were balances another, and all proceeds in an endless circle of change. This carbonic acid, which is so poisonous to animal life, is the food of the vegetable world, plants having the power of taking up the carbonic acid into their pores; converting the carbon into their own substance, and rejecting the oxygen, which is again respired by animals, &c. In the same way, all animal refuse is the food of vegetables, and is used under the name of manures.
The atmosphere contains also a variable quantity of vapour of water, invisible as long as it is in the state of vapour, but it may be rendered obvious by bringing any very cold body into warm air, when the vapour will condense on the cold body in the form of small drops of water. A tumbler of fresh-pumped water brought into a crowded room, is almost immediately covered with moisture, and it may also be seen on bottles of wine which have been put into ice before coming to table. Fogs are occasioned by the condensation of vapour produced by mixing a current of warm air with a colder air. The banks of Newfoundland are notorious for dense fogs, occasioned by the warm air brought from the south by the great Gulf stream, mixing with the cold air from the Arctic regions, and thus precipitating the vapour in a visible form, rendering everything but itself invisible. The famous London fogs depend upon the same precipitation of the vapour of water, with the addition of the smoke from the numerous sea-coal fires, which give it that interesting yellow tinge for which it is so remarkable.
Aqueous vapour appears to impart a transparency to air, and permits objects to be seen more distinctly in proportion to its quantity; hence, when distant hills appear nearer, and objects upon them more distinct than usual, rain may be expected, the air being fully charged with vapour ready to be deposited on the slightest cause.
HYDROGEN.
Hydrogen gas is the lightest substance known, being fifteen times lighter than atmospheric air. It is colourless and transparent, incapable of supporting combustion or respiration, but is itself combustible. Hydrogen, as its name implies (being derived from two Greek words, signifying the generator of water), is a constituent of water in the proportion of one-ninth by weight, and is always obtained by decomposing that fluid, by presenting to it some body to take up its other ingredient, oxygen, and so set the hydrogen at liberty. If the steam of water be passed through a red-hot gun barrel, containing iron filings, the water is decomposed, the iron taking the oxygen, and the hydrogen comes over in torrents; but as every one has not a gun barrel and furnace to heat it, the usual mode is to employ dilute sulphuric acid, and iron filings, or zinc, in small pieces, and it may be collected over water by means of a bent tube issuing from the bottle in which it is formed. It is so light that it was used to fill balloons before coal gas was to be had, and if you procure a light air-tight bag of silk, or thin membrane such as a turkey’s crop, and fill it with the gas, it will ascend rapidly, and dance about the ceiling of a room.
EXPERIMENTS.
1. Attach a tobacco-pipe to a bladder filled with this gas, and blow some soap-bubbles with it; they will rise very rapidly, and if a lighted taper be applied to them they burn.
If you mix in a soda water bottle one-third of oxygen with two-thirds of hydrogen, and apply flame, the mixture will explode with a sharp report. Great care must be taken in all experiments with the mixed gases. To avoid danger the gases are placed in separate india-rubber bags, and are only brought together at the jet. This is an expensive apparatus, and should only be used by experienced persons.
2. If a jar of this gas be held with its mouth downwards, and a lighted taper passed up well into the jar, the taper will be extinguished, and the gas take fire, and burn quietly at the mouth of the jar; if mixed with oxygen or atmospheric air, it will explode.
Hold over the jet of hydrogen issuing from a small tube, hollow cylinders of glass or earthenware, Florence flasks, or hollow glass balls, and musical sounds will be produced, which were supposed to depend on some peculiar property of hydrogen gas, until Mr. Faraday tried flame from coal gas, olefiant gas, and even the vapour of ether, when the sounds were still produced, and he attributed them to a continuous explosion, or series of explosions, produced by the union of oxygen with the hydrogen of the flames.
WATER.
With oxygen, hydrogen unites to form the important compound water, which exists not only in the obvious form of oceans, rivers, lakes, rains, dews, &c. &c. but is found intimately combined with many substances, giving them some of their peculiar properties. Many crystals have a definite proportion of water combined with them, and on losing this water they lose their crystalline form. Many acids also cannot exist as acids without water. The slaking of lime depends upon the union of water with the lime, the dry powder resulting from the process being a hydrate of lime, the water having become solidified, and in passing from the fluid to the solid state gives out its latent caloric, producing the heat observed during the process. When a large quantity of lime, a barge-load for instance, has got wetted by accident, the heat evolved has been sufficient to set fire to the barge.
At the temperature of 32° of Fahrenheit’s thermometer, water loses its fluid form, and becomes ice. As it solidifies, it starts into beautiful crystals, which unite and cross each other at determinate angles. Ice is lighter than the water on which it floats, forming a protection to the water beneath, and preventing it from being frozen so rapidly; else, if the ice were heavier than water, and consequently sank as soon as formed, each portion of water would be frozen in its turn, until rivers became solid throughout, and every living creature in them must be destroyed. Now, the temperature of the water under the ice is seldom much below 40°, and if care be taken to break holes at intervals to allow access to the air, the fish and other aquatic animals seldom suffer even in our coldest winters.
Although it is impossible to raise ice even one degree above 32° without thawing, it is not difficult to reduce water many degrees below that point without freezing it.
In order to obtain both the constituents of water in a separate state, it must be decomposed by galvanism, each pole of a battery terminating in a separate tube containing water, when the result will be that at the positive pole oxygen gas will be evolved, and hydrogen at the negative, the latter being double the quantity of the former. Now, if you mix the gases thus obtained, introduce them into a vessel called a “Eudiometer,” and pass an electric spark through them from a Leyden phial, a sudden flash will be seen, and the gases will entirely disappear, being again converted into water. If you have a mercurial trough, and perform this experiment over mercury, the inside of the eudiometer will exhibit minute drops of water. Thus you have proved both by analysis and synthesis, that water consists of oxygen and hydrogen, in the proportion of one volume of the former to two of the latter.
EXPERIMENT.
Take some perfectly pure distilled water, filter it, surround it with a mixture of light snow, or powdered ice, and salt, taking care to keep it perfectly still, a thermometer having been previously placed in it. The mercury will gradually sink many degrees below the freezing point 32° (it has been reduced as low as 4°), the water still remaining fluid; when all at once, either from shaking the table, or simply because the reduction can be carried no further, it suddenly starts into ice, and the thermometer jumps up at once to 32°, where it remains until the whole is frozen, when the temperature gradually sinks to that of the surrounding medium.
Now if you remove the glass of ice from the freezing mixture into the apartment, and watch the thermometer, you will find it gradually rise to 32°, and there remain until all the ice is melted, when it will gradually acquire the temperature of the room. The reason of this is, that the water in passing from the solid to the fluid form absorbs, and in passing from the fluid to the solid form gives out caloric, so maintaining the temperature at 32°, the point at which the change of form takes place, until it is completed.
Between the temperature of 32° and 212°, water exists in a fluid form, under ordinary circumstances; but at the latter point it assumes the form of vapour or steam, and acquires many of the properties of gases, being indefinitely expansible by heat, the force increasing as the temperature is raised, provided the steam be confined, until it becomes irresistible,--witness the frequent explosions of steam-engines even in this country; and in America, where the engines are worked at a high pressure, accidents are of daily occurrence.
The temperature at which water boils is modified by the pressure applied to it. Thus, as you ascend a mountain, and so pass through a portion of the atmosphere, water boils at a lower temperature, until at great heights it boils at so low a heat, that good tea cannot be made because it is impossible to heat the water sufficiently. Under the exhausted receiver of an air-pump, water boils at about 140°.
CHLORINE.
Another gaseous element, sometimes called a supporter of combustion, is named chlorine, from a Greek word signifying yellowish green.
This gas was formerly called “oxymuriatic acid,” being supposed to be a compound of oxygen and muriatic acid gases, until Sir H. Davy, in a series of masterly experiments carried on during the years 1808-9-10 and 11, proved that it contained no oxygen or muriatic acid, and that it was in fact a simple or undecompounded substance, and changed its name to chlorine, which name was, after some discussion, accepted by the scientific world, and is still in use.
This gas may be obtained for experiment, by gently heating in a retort a mixture of muriatic or hydrochloric acid, hydrochloride, as it is now called, with some black oxide of manganese: the muriatic acid, a compound of chlorine and hydrogen, is decomposed, and so is the oxide of manganese, giving out some of its oxygen, which takes the hydrogen from the muriatic acid to form water, while the chlorine gas, with which the hydrogen had been united, is set at liberty, and may be collected in jars over water.
Chlorine gas is transparent, of a greenish yellow colour, has a peculiar disagreeable taste and smell, and if breathed even in small quantities, occasions a sensation of suffocation, of tightness in the chest, and violent coughing, attended with great prostration. I have been compelled to retire to bed from having upset a bottle containing some of this gas. It destroys most vegetable colours when moist, and is in fact the agent now universally employed for bleaching purposes.
It has also the power of combining with and destroying all noxious smells, and is invaluable as a purifier of foul rooms, and destroyer of infection. For these latter purposes it is used in combination with lime, either in substance or solution, under the name of “Chloride of Lime.”
Sir W. Burnett has lately discovered that the chloride of zinc answers the same purposes as the chloride of lime, and has the advantage of being itself destitute of smell, and his fluid is frequently substituted for the other.
Chlorine gas is a powerful supporter of combustion, many of the metals taking fire spontaneously when introduced in a fine state of division into the gas.
EXPERIMENTS.
1. Into a jar of chlorine gas introduce a few sheets of copper leaf, sold under the name of Dutch foil, when it will burn with a dull red light.
2. If some metallic antimony in a state of powder be poured into a jar of this gas, it will take fire as it falls, and burn with a bright white light.
3. A small piece of the metal potassium may be introduced, and will also take fire.
4. A piece of phosphorus will also generally take fire spontaneously when introduced into this gas. In all these cases direct compounds of the substances with chlorine are produced, called chlorides.
5. If a lighted taper be plunged quickly into the gas, it will continue to burn with a dull light, giving off a very large quantity of smoke, being in fact the carbon of the wax taper, with which the chlorine does not unite; while the other constituent of the taper, the hydrogen, forms muriatic acid by union with the chlorine.
6. This substance has the property of destroying most vegetable colours, and is used in large quantities for bleaching calico, linen, and the rags of which paper is made. It is a curious fact that it shows this property only when water is present, for if a piece of coloured cloth is introduced dry into a jar of the gas, also dry, no effect will be produced--wet the cloth, and reintroduce it, and in a very short time its colour will be discharged.
7. Introduce a quantity of the infusion of the common red cabbage, which is of a beautiful blue colour, into a jar of this gas, and it will instantly become nearly as pale as water, retaining a slight tinge of yellow. A solution of sulphate of indigo can always be obtained, and answers well for this experiment.
MURIATIC ACID GAS, OR HYDRIC CHLORIDE.
With chlorine, hydrogen forms a compound called muriatic, or hydrochloric acid gas. It cannot easily be formed by the direct union of its elements, but is procured from some compound in which it exists ready formed. Common salt (chloride of sodium) is generally employed; and when acted on by strong sulphuric acid (or oil of vitriol), the gas is disengaged in abundance. It must be collected over mercury, for water absorbs it, forming the liquid muriatic, or hydrochloric acid.
A lighted taper plunged into this gas is instantly extinguished. It is very dangerous to animal life if respired. It has the property of destroying animal effluvia, and was once employed to purify the cathedral of Dijon, which was so filled with putrid emanations from the bodies buried in it, that it had been closed for some time. It perfectly succeeded, but it is so destructive to all metallic substances that it is not used now, for the chlorides of lime and zinc have since been discovered to act more effectually than the muriatic acid gas, without its inconvenience.
The compounds of hydrogen with iodine are passed over.
With nitrogen, hydrogen unites and forms one of the most extraordinary compounds in the whole range of chemistry,--the gas called ammonia. This is the only gas possessing what are called alkaline properties; i. e. it changes the blue colour of certain vegetables to green, yellow to deep brown, and unites with the acids to form neutral compounds, just as the other alkalies, potash and soda, which are oxides of metals. It may be procured in abundance by heating the hydrochlorate of ammonia, or sal ammoniac, as it is usually called, with quick-lime, which takes the hydrochloric acid, and sets free this remarkable gas. It must be received over mercury, as it is absorbed to almost any extent by water, forming the fluid sold as “spirits of hartshorn” in the shops.
This gas is colourless and transparent, lighter than atmospheric air, and will not support combustion; it has a very pungent but not disagreeable smell. Under certain circumstances it is combustible.
EXPERIMENTS.
1. Take a bottle containing chlorine gas, and invert over its mouth another filled with ammoniacal gas; then if the bottles be held in the hand (guarded by a pair of gloves), and suddenly turned, so that the chlorine be uppermost, the two gases will unite so rapidly that a white flame fills the bottles for an instant.
2. Substitute for the chlorine of the last experiment a bottle of carbonic or hydrochloric acid gas; in either case the gases disappear, and a light white powder settles on the sides of the bottles, being the carbonate or hydrochlorate of ammonia, according to the acid used.
Carbonate of ammonia is the substance sold for “smelling salts;” and the hydrochlorate, or muriate of ammonia, is the salt called “sal ammoniac,” whence the alkaline gas was first obtained, and from which it got its name of ammonia. The salt itself was so called, because it was formerly brought from the deserts near the ruins of the temple of Jupiter Ammon.
This salt is, as has been shown, a compound of muriatic acid gas and ammoniacal gas, containing therefore only three simple elements--hydrogen, chlorine, and nitrogen, all gases, and known only in the gaseous state, its symbol being NH₄Cl; yet they by union form a solid body, resembling in all essential qualities the salts of potash and soda, which are oxides of known metals. Moreover, if some mercury be placed in a solution of this salt, and subjected to the action of galvanism, the negative pole being applied to the mercury, and the positive to the sal ammoniac, the mercury presently loses its fluidity, increases greatly in size, and in fact presents the same appearance as when it is mixed with some metal, forming what is called an “amalgam.” When the battery ceases to act, a succession of white films forms on the surface of the amalgam, and the mercury soon returns to its original state. How is this to be explained? Some chemists have supposed that there must be a base united to the mercury, and have named this hypothetical substance “ammonium,” to correspond to potassium and sodium, the bases of potash and soda, which resemble ammonia in so many properties. But what is this ammonium? and how is it formed? for hydrogen and nitrogen are simple elementary bodies. Are all metals compounds of gases? and are there but a few elements instead of the 64 now enumerated? This, however, is a difficult question, not fitted for discussion here.
Carbonate of ammonia may be obtained by mixing together powdered chalk (which is a carbonate of lime) and muriate of ammonia, and heating the mixture in close vessels, when the salt in question will rise in fumes, and be condensed in a mass in the upper part of the vessel. It is, however, so largely produced in other manufactures, particularly in gas-works, that there is no necessity to resort to the more expensive and direct method. It is the well-known “smelling salts.”
The only other salt of ammonia worth our notice here is the nitrate, from the destructive distillation of which is obtained the nitrous oxide, or laughing gas, already mentioned.
IODINE.
On the coasts of certain islands belonging to the Duke of Argyll, vast quantities of sea-weed are occasionally torn up from their ocean beds and deposited on the shores. This weed, after being partially dried by exposure to the sun and air, is burnt in a shallow pit; the ashes are then collected, and form the commercial raw material called kelp, from which iodine is procured by a gradual series of processes.
EXPERIMENTS.
Iodine has a beautiful metallic lustre, with a bluish black colour, and should be kept in a well-stoppered bottle. A small quantity placed in a clear flask and heated, affords a magnificent violet vapour, which may be poured from the flask into another glass vessel, when it condenses again into crystalline plates. The colour of the vapour originates the name of this element, so called from the Greek Ἰώδης, violet-coloured. If a little iodine be placed in contact with a thin slice of phosphorus, the latter takes fire almost immediately.
BROMINE.
So called from the Greek βρόμος, a bad odour, is most intimately allied with chlorine and iodine; like these elements it belongs to the sea, and is a constituent of sea-water. Bromine is a very heavy fluid, and should be preserved by keeping it covered with water in a stoppered-bottle.
Experiments with liquid bromine are not recommended, as all the most interesting ones can be performed with the vapour, which is easily procured by letting fall a few drops of bromine into a warm dry bottle.
EXPERIMENTS.
Pounded antimony sprinkled into the vapour takes fire immediately.
A thin slice of phosphorus placed in a deflagrating ladle and placed into the vapour of bromine ignites very quickly.
A solution of sulphate of indigo, or an infusion of red cabbage, are easily bleached by being shaken violently with the vapour of bromine.
FLUORINE.
In many parts of England, especially in Devonshire, Cornwall, and above all in Derbyshire, is found a very beautiful mineral, known by the name of Fluor Spar, Derbyshire Spar, and called by the miners Blue John, to distinguish it from another mineral found, in the same locality, called Black Jack. It occurs in very regular and frequently large crystals in the form of cubes, and occasionally in octoëdra. It is a compound of calcium with fluorine, and is very abundant in certain fossil bones. This element, in combination with hydrogen and called hydrofluoric acid, acts so energetically upon all substances containing silica, that it cannot be preserved in vessels of glass or porcelain--very few of the metals are capable of resisting its action, lead being nearly the only common metal possessed of this power. Gutta percha may also be employed for vessels to hold it.
This property of dissolving silica, has caused this acid to be used for engraving on glass.
EXPERIMENT.
Mix one part of powdered fluor-spar, quite pure, with two parts of oil of vitriol, in a saucer, and apply a gentle heat, when the acid will be disengaged in the form of vapour. Prepare a piece of glass after the manner of engraving on copper, by coating it with a thin covering of wax, placing a paper over the wax, and then drawing any design with a sharp-pointed instrument, when, on removing the paper, the wax-coating will be found to be removed wherever the instrument has passed over it. Now invert, this glass over the fumes of the acid for half an hour or so, and then heat the glass so as to soften the coating, and wipe it off; the design will then appear “bitten in” as the term is, that is, the acid will have dissolved the glass wherever it was not protected by the wax, and will exhibit the design indelibly fixed on the glass.
This acid requires the greatest care in handling, for it is extremely corrosive, producing very troublesome ulcers if it comes in contact with the skin; even the fumes will produce smarting if the skin is long exposed to them.
CARBON.
The next substance in our list of elementary bodies is named carbon.
The purest form of carbon is the precious stone called diamond, which consists entirely of carbon in a crystallized form. The French chemist Lavoisier was the first who proved the combustibility of the diamond; and Sir H. Davy found that when once set on fire it would continue to burn in oxygen gas air, and that the product of the combustion was carbonic acid gas, exactly equal in quantity to the gas produced by burning an equal weight of pure charcoal, the most common form of carbon.
Plumbago, or “black-lead,” as it is very improperly called, is also nearly pure carbon, a very small quantity of iron being united with it.
By far the greater part of all vegetable, and a very large portion of animal bodies consists of carbon; and in the state of carbonic acid in combination with lime and some other earths, it forms nearly the half of all the chalk, marble, and limestone of our hills; so that it is, in one shape or other, one of the most widely diffused bodies in nature.
Carbon forms two gaseous compounds with oxygen; the first, called carbonic oxide, is easily obtained by boiling oxalic acid with its own bulk of sulphuric acid, in a flask to which a cork and bent tube is attached. The gas comes over in large quantities, and must be collected in a gas jar, or the pneumatic trough. It is inflammable, and burns with a lambent blue flame.
The other compound, carbonic acid, is transparent, colourless, much heavier than atmospheric air, has an agreeable taste, has the power of irritating the mucous membrane of the nose, (as any one can tell who has drunk soda-water), without possessing any particular odour, is absorbed by water, does not support respiration, and extinguishes flame.
Carbonic acid gas may be obtained with the greatest facility by pouring some muriatic or sulphuric acid, diluted with about six parts of water, upon some pieces of marble or limestone in a bottle with a tube attached, when the gas comes over in torrents. It may be collected over water.
EXPERIMENTS.
1. To show the great comparative weight of this gas, place a lighted taper at the bottom of a tall glass jar, then take a jar full of carbonic acid gas, and pour it as you would pour water into the jar containing the lighted taper; you will soon find the taper will be extinguished as effectually as if you had poured water on it, and the smoke of the taper will float on the surface of the gas in very beautiful wavy forms.
2. Heat a piece of the metal potassium in a metal spoon (platinum is best), and if introduced in a state of ignition into the gas, it will continue burning brilliantly, producing a quantity of dense smoke, which is the carbon from the carbonic acid, the potassium having seized the oxygen and being converted by it into potash.
3. If a mouse, bird, or other small animal, be placed in a jar of this gas, it becomes insensible almost immediately, but if speedily removed it will occasionally recover.
4. Shake up some water with some of this gas in a bottle; the greater part of the gas will be absorbed by the water, which acquires a sparkling appearance and a pleasant sharp taste; with the addition of a little soda this becomes the well-known beverage called soda-water, so famous for removing the morning headaches caused by “that salmon” having disagreed at yesterday’s dinner.
It is the presence of this gas which renders it so dangerous to descend into deep wells, for by its great weight it collects at the bottom, and instantly suffocates any unfortunate person who incautiously subjects himself to it. Hence it is prudent always to let down a lighted candle before any one descends into a well, or other deep excavation, and if the candle is extinguished, it is necessary to throw down several pails of water, lime-water if possible, and again to try the candle, which must burn freely before it is safe for any one to descend.
It is this same gas under the name of “choke-damp,” which proves so dangerous to miners, particularly after an explosion of “fire-damp,” for it is the principal product of the explosion, and it is by no means an easy matter to dislodge it.
Carbonic acid gas has been condensed into the fluid form by causing it to be disengaged under great pressure; the fluid acid has the appearance of water. When the pressure is removed, as by allowing some of the fluid acid to escape from the vessel in which it has been condensed, it instantly reassumes the gaseous form, and in so doing absorbs so much latent caloric that a portion of the acid is actually solidified, and appears in the shape of snow, which may be collected and preserved for a short time. After a lecture by Mr. Addams before the Ashmolean Society of Oxford, I carried a kind of snowball of carbonic acid for a distance of 500 or 600 yards, and placed it in a saucer in a room. It evaporated very rapidly, and left no residue, not even a mark where it had lain. It was too cold to be touched by the naked hand without pain.
Carbonic acid and lime are mutually tests for each other. If a jar containing a little lime-water be put into a jar of this gas, it speedily becomes turbid, the gas uniting with the lime, and producing chalk (the carbonate of lime), which is insoluble in water.
This gas is produced in large quantities by the respiration of animals, as may be proved by respiring through a tube immersed in lime-water, when the water will be instantly rendered turbid from the formation of chalk.
CARBON AND HYDROGEN.
To the combination of these elements in various proportions, and with the occasional addition of other substances, we are indebted for all, or nearly all, our means of obtaining light and heat. Coal, wood, spirit, oil, and all the varieties of fats, are composed principally of carbon and hydrogen, and may easily be converted into the gas with which our houses and streets are lighted, which is nearly pure carburetted hydrogen.
The two chief definite gaseous compounds of these two elements are the light carburetted hydrogen, and the heavy carburetted hydrogen, or olefiant gas. The first is easily procured by stirring the bottom of stagnant water on a hot summer’s day, and collecting the bubbles in a bottle filled with water and inverted over the place where the bubbles rise. This gas burns with a yellowish flame, and when mixed with a certain proportion of air, or oxygen gas, explodes with great violence on the application of a flame. It is the much dreaded fire-damp generated so profusely in some coal-mines, and causing such fearful destruction to life and property when accidentally inflamed.
The other compound, the heavy carburetted hydrogen, forms part of the gas used for illumination; and, in fact, whatever substance is employed for artificial light, whether oil, tallow, wax, &c. &c. it is converted into this gas by heat, and then furnishes the light by its own combustion.
This gas has some very curious properties, and may be obtained nearly pure by mixing in a retort, very carefully, one part of spirits of wine and four of sulphuric acid. A lamp must be placed under the retort, when the gas will be speedily disengaged, and come over in great abundance; it may be collected over water.
This gas is transparent, colourless, will not support combustion, but is itself inflammable, burning with a brilliant white light, and being converted into carbonic acid and water. If mixed with three or four times its bulk of oxygen, or with common atmospheric air in much larger proportions, it explodes with great violence.
This gas is sometimes called “olefiant gas,” from the property it has of forming an oily substance when mixed with chlorine.
EXPERIMENT.
Into a jar standing over water half full of this gas, pass an equal quantity of chlorine gas. The gases will speedily unite and form an oily-looking liquid, which may be collected from the sides of the jar as it trickles down. By continually supplying the jar with the two gases as they combine, a considerable quantity of this substance may be collected. Care should be taken that the olefiant gas is rather in excess.
The substance produced is insoluble in water, with which it should be washed by shaking them together in a tube, and has a pleasant sweetish taste and aromatic smell, somewhat resembling ether.
COAL GAS.
The gas so universally employed for the purposes of illumination is a mixture of the carburetted and the bi-carburetted hydrogen, with minute portions of other gases scarcely worth mentioning. It is procured by submitting coals to a red heat in iron retorts, having a tube passing from one end, along which passes all the fluid and gaseous matter separated from the coal, namely, gas tar, ammoniacal liquor, and various gases, carburetted hydrogen, carbonic acid, sulphuretted hydrogen, &c. &c. The tar and ammoniacal liquor remain in the vessel in which the tubes from the retorts terminate, and the gaseous productions are conveyed through water and lime to separate the impurities; the remaining gas, now fit for use, passes into large iron vessels, called gasometers, inverted over water (like the jars in a pneumatic trough), whence it is sent through pipes and distributed where required. What remains in the retorts is called coke. It consists principally of charcoal, mixed with the earthy and metallic particles contained in the coal.
EXPERIMENT.
If you possess an iron bottle, fill it with powdered coal, and attach a flexible tube to it, and put it in the fire: as soon as it becomes red hot, large quantities of smoke will escape from the end of the tube, being the gas mixed with all its impurities. By passing it through water (if mixed with lime it will be better), the gas may be collected in jars standing over water, and submitted to experiment. If you do not possess a bottle, take a tobacco-pipe with a large bowl, (a “churchwarden” for example); fill the bowl with small coal, cover it with clay or putty, and when dry put it into the fire, and the gas will soon appear at the other end of the pipe, when it may be lighted, or the gas may be collected over water, as in the former experiment.
The light carburetted hydrogen contained in this gas is given off spontaneously in some coal-mines, and as it forms explosive mixtures with atmospheric air, the mines where it abounds could not be worked except at the greatest risk until about the beginning of the present century, when Sir H. Davy, while prosecuting some researches on the nature of flame, found that flame would not pass through metallic tubes, and he gradually reduced the length of the tubes, until he found fine iron wire gauze formed an effectual barrier against the passage of flame. He then thought that if the light in a lantern were surrounded with this gauze, it might safely be used in an inflammable atmosphere, where a naked light would instantly cause an explosion. Upon submitting the lamp to experiment, he found that by passing coal gas by degrees into a vessel in which one of his lamps was suspended, the flame first became much larger, and then was extinguished, the cylinder of gauze being filled with a pale flame, and though the gauze sometimes became red-hot, it did not ignite the gas outside. As the supply of coal gas was diminished, the wick of the lamp was rekindled, and all went on as at first. A coil of platinum wire was afterwards suspended in the lamps, which becomes intensely heated by the burning gas, and gives out sufficient light to enable the miner to see to work. As long as the gauze is perfect it is almost impossible for the external air to be kindled by the wick of the lamp, but the miners are so careless that they will often remove the gauze to get a better light, to look for a tool, or some cause equally trivial, and many lives have been lost in consequence of such carelessness.
The effect of fine wire gauze in preventing the passage of flame may be shown by bringing a piece of the gauze gradually over the flame of a spirit-lamp, until it nearly touches the wick, when the flame will be nearly extinguished, but the vapour of the spirit passes through, and may be lighted on the upper side of the gauze, which will thus have a flame on either side, though totally unconnected with each other. The flame from a gas-burner will answer as well as the spirit-lamp.
Nearly all the fluids, and solids also, used for procuring artificial light, such as naphtha, various oils, tallow, wax, spermaceti, spirits of wine, ether, &c. &c. are compounds of carbon and hydrogen in different proportions, with the occasional addition of some other elements, especially oxygen and hydrogen, in the proportions to form water; as a general rule, those bodies containing the greatest proportion of carbon give the most light, though not necessarily the most heat.
PHOSPHORUS.
The next body we have to notice is phosphorus, a most remarkable substance, procured from the earthy part of bones by a process not worth detailing here. It should be always kept under water, and the naked fingers should not be allowed even to touch it, for the smallest piece getting under the nail will inflame the first time the hand comes near the fire, and produce a sore very painful and difficult to heal. It should be cut under water by a knife or scissors, and removed with a pair of forceps. Its combustible properties have been frequently mentioned. It has also the property of shining in the dark, so that if you write on a wall with a solution of phosphorus in oil, the letters will appear luminous in the dark--there is no danger, excepting from the greasiness of the oil.
Of the compounds of phosphorus with oxygen we have nothing to do here, but it forms with hydrogen a very curious gaseous compound, which takes fire spontaneously on the contact of air, or almost any gas containing oxygen.
EXPERIMENTS.
It may be procured in either of two ways, according to the purpose for which it is wanted. The simplest way is to put a lump or two of phosphuret of lime into a saucer, about two inches in depth, containing some very diluted hydrochloric acid; bubbles of gas will speedily arise, and bursting on the surface of the fluid will burn with a slight explosion, and a circular wreath of smoke will rise into the atmosphere, enlarging as it rises, and wreathing itself round and round in the most elegant forms. Care must be taken that the phosphuret is fresh, and has been kept in a well-closed bottle, or the experiment will fail. The apartment must be free from draughts. If you desire to collect the gas, another method must be employed.
Fill a small retort quite full, neck and all, of a solution of caustic potash, drop five or six pieces of phosphorus into it, place the finger on the end of the retort, and immerse it in a basin also containing a hot solution of potash, remove the finger, and on applying the heat of a lamp to the retort, the gas will soon be disengaged rapidly, and drive out the fluid in the retort; it then escapes into the air, when it inflames with the same appearances as before described. Or it may be collected in gas jars filled with the potash solution, and held over the mouth of the retort. The object in using hot solution of potash in the basin is, that when the gas ceases to be given off, and the heat of the lamp is withdrawn, the hot fluid may gradually fill the vacuum which will form in the retort, and so prevent its being broken.
This gas is transparent and invisible, like most other gases. It is very poisonous if inhaled. If kept for any time, it loses its property of spontaneous inflammation, and must therefore be made at the time it is required.
SULPHUR.
Sulphur, or brimstone, as it is frequently called, is sold in the form of sticks, or roll brimstone, or in fine powder called flowers of brimstone.
It is capable of showing electric phenomena when rubbed, giving out slight sparks, and first attracting and then repelling light bodies, such as small pieces of paper, &c. It is so bad a conductor of heat, that if grasped suddenly in a hot hand, it will crack and split into pieces just as glass does when suddenly heated or cooled--of course I am speaking of the roll brimstone. Water has no effect on it, as may be seen in the pans placed for pet dogs to drink out of, where the same piece of brimstone lies for years entirely unaltered, though it is supposed to prevent the dogs from having the mange!
Sulphur is largely used in the arts, principally in the manufacture of gunpowder, and fireworks of various kinds.
It combines with hydrogen, and forms a gaseous compound called sulphuretted hydrogen, which is almost the most poisonous of all the gases. It fortunately has so abominable smell, that due notice is given of its presence. Rotten eggs, a dirty gun-barrel, cabbage water, putrid animal and vegetable matter, &c. are indebted to this gas for their inviting odour; and it is found in certain mineral springs, as at Harrogate, where the water contains a considerable quantity of this gas, and is found useful in many diseases of the skin. It is also given off in a gaseous form by some volcanoes.
This gas may be obtained by pouring dilute hydrochloric acid upon a metallic sulphuret, such as that called crude antimony, being a native sulphuret of that metal. The gas may be kept for a short time over water. It is colourless and transparent, inflammable, but quite irrespirable, a small bird dying instantly when placed in air containing only 1/1500th of this gas. Its most remarkable property perhaps is the effect it has on certain metallic oxides, and other metallic salts, blackening them instantly. White paint is easily stained by this gas, and it will darken the colour of a metal in a solution, especially of lead, even when diluted with 20,000 times its weight of water. By way of experiment, slips of riband, silk, or even paper, may be wetted with various metallic solutions, such as silver, mercury, lead, &c. or words may be written with the solutions, and on holding them over a stream of this gas they will be instantly darkened.
If this gas be collected in the pneumatic trough, which is usually painted white, you will have the pleasure of seeing the colour changed to a very dark brown, when your experiments are finished. With this very limited description of some of the non-metallic elements and their combinations, we must, for want of space, take leave of this division of chemistry; “the beginning of which is pleasure, its progress knowledge, its objects truth and utility.”--(Davy.)
METALS.
We have a few words to say about a class of bodies called metals, which are of the utmost importance to mankind, and indeed without some of them, especially iron, few of the arts of civilized life could exist.
Fifty substances are now included in the list of metals; some of them, however, are only supposed to exist, such as ammonium, the supposed base of ammonia; and very many are to be viewed rather in the light of chemical curiosities, as from their great rarity they are too expensive for use, even if possessed of valuable properties of which others might be destitute.
Several metals have been known from the earliest period of which we have any record; such were iron, gold, silver, copper, lead, tin, mercury, and probably zinc, or at least its ores; for brass, which is an alloy of copper and zinc, is frequently mentioned in the early part of the Old Testament. In the sixteenth century others were discovered, such as antimony and bismuth. In the last century, cobalt, arsenic, platinum, nickel, manganese, and chromium, together with several unimportant metals, were discovered by various philosophers; while in the present century, Dr. Wollaston discovered rhodium, the hardest and nearly the most indestructible of all the metals; and a few years later, Sir Humphry Davy found that the alkalies, potash, and soda, with many of the earths as they were called, had each a metal for its base, to which he gave the Latin name of the alkali or earth, with the termination um, as potassi_um_, the base of potassa, sodi_um_ of soda, calci_um_ of calx (lime), &c.
Until Sir H. Davy’s discovery of the metals of the alkalies, great specific gravity was regarded as one of the most striking characteristics of a metal, the lightest of them being much heavier than the heaviest earth; but potassium is very much lighter than water, and not much heavier than spirits of wine. The other metals vary from a specific gravity of nearly twenty-one--or twenty-one times heavier than an equal bulk of water--that of platinum, to somewhat less than seven, which is the specific gravity of antimony.
When pure, they all have a lustre, differing indeed among themselves, but so peculiar that it is called the metallic lustre, for instance, gold and copper are yellow and red--nearly all the others white, but of a different shade; still there is no mistaking their metallic character, no other substances at all equalling them in this respect. They are also opaque, although some, like gold, when reduced to thin films, allow light to pass through them. They are all good conductors of heat and electricity, though some possess that property to a greater extent than others.
Many of them are what is called malleable, that is, may be extended or spread out by rolling, or beating them with a hammer; and ductile, or have the property of being drawn out into wire. Gold, silver, copper, and iron, are the most remarkable in this respect.
All the metals are fusible, but some require very different degrees of heat to render them fluid,--platinum requiring the heat of the oxy-hydrogen blowpipe, while tin melts in the flame of a candle, and mercury is fluid at all temperatures in this climate, but becomes solid at 40° Fahr. below 0,--a temperature occasionally experienced in the Arctic regions, where the mercurial thermometer is useless, the mercury becoming solid.
They are all excellent conductors of heat and electricity, and have the property of reflecting light and forming mirrors; for looking-glasses owe their power of reflecting objects principally to what is called the “silvering;” that is, a mixture of mercury and tin spread over the back of the glass, which being transparent, allows the image reflected from the metal to pass through it.
The following classification is most instructive, because it suggests to the young student that there must be identical properties in the metals thus placed together:--
Class 1. Ammonium, cæsium, lithium, potassium, sodium.
Class 2. Calcium, barium, strontium.
Class 3. Aluminium, cerium, didymium, erbium, glucinium, lanthanum, thorium, yttrium, zirconium.
Class 4. Zinc class: cadmium, magnesium, zinc.
Class 5. Iron class: cobalt, chromium, indium, iron, manganese, nickel, uranium.
Class 6. Tin class: niobium, tantalum, tin, titanium.
Class 7. Tungsten class: molybdenum, tungsten, vanadium.
Class 8. Arsenic class: antimony, arsenic, bismuth.
Class 9. Lead class: lead, thallium.
Class 10. Silver class: copper, mercury, silver.
Class 11. Gold class: gold, iridium, osmium, palladium, platinum, rhodium, ruthenium.
POTASSIUM.
Potassium was discovered by Sir H. Davy in the beginning of the present century, while acting upon potash with the enormous galvanic battery of the Royal Institution, consisting of 2,000 pairs of 4-inch plates. It is a brilliant white metal, so soft as to be easily cut with a penknife, and so light as to swim upon water, on which it acts with great energy, uniting with the oxygen, and liberating the hydrogen, which takes fire as it escapes.
EXPERIMENT.
Trace some continuous lines on paper with a camel’s-hair brush dipped in water, and place a piece of potassium about the size of a pea on one of the lines, and it will follow the course of the pencil, taking fire as it runs, and burning with a purplish light. The paper will be found covered with a solution of ordinary potash. If turmeric paper be used, the course of the potassium will be marked with a deep brown colour.--Corollary. Hence, if you touch potassium with wet fingers you will burn them!
If a small piece of the metal be placed on a piece of ice, it will instantly take fire, and form a deep hole, which will be found to contain a solution of potash.
In consequence of its great affinity for oxygen, potassium must be kept in some fluid destitute of that element, such as naphtha.
Caution!--As the globules of potassium after conversion into potash, when thrown on ice or water burst, strewing small particles of caustic hot potash in every direction, the greatest care should be taken to keep at a sufficient distance whilst performing the above experiment.
Saltpetre, or nitre, is a compound of this metal (or rather its oxide) with nitric acid. It is one of the ingredients of gunpowder, and has the property of quickening the combustion of all combustible bodies.
Mix some chlorate of potash with lump sugar, both being powdered, and drop on the mixture a little strong sulphuric acid, and it will instantly burst into flame. This experiment also requires caution.
Want of space precludes us from considering the individual metals and their compounds in detail; it must suffice to describe some experiments showing some of their properties.
The different affinities of the metals for oxygen may be exhibited in various ways. The silver or zinc tree has already been described, page 357.
EXPERIMENTS.
1. Into a solution of nitrate of silver in distilled water immerse a clean plate or slip of copper. The solution, which was colourless, will soon begin to assume a greenish tint, and the piece of copper will be covered with a coating of a light grey colour, which is the silver formerly united to the nitric acid, which has been displaced by the greater affinity or liking of the oxygen and acid for the copper.
2. When the copper is no longer coated, but remains clean and bright when immersed in the fluid, all the silver has been deposited, and the glass now contains a solution of copper.
Place a piece of clean iron in the solution, and it will almost instantly be coated with a film of copper, and this will continue until the whole of that metal is removed, and its place filled by an equivalent quantity of iron, so that nitrate of iron is found in the liquid. The oxygen and nitric acid remain unaltered in quantity or quality during these changes, being merely transferred from one metal to another.
A piece of zinc will displace the iron in like manner, leaving a solution of nitrate of zinc.
Nearly all the colours used in the arts are produced by metals and their combinations; indeed, one is named chromium, from a Greek word signifying colour, on account of the beautiful tints obtained from its various combinations with oxygen and the other metals. All the various tints of green, orange, yellow, and red, are obtained from this metal.
Solutions of most of the metallic salts give precipitates with solutions of alkalies and their salts, as well as with many other substances, such as what are usually called prussiate of potash, hydro-sulphuret of ammonia, &c.; and the colours differ according to the metal employed, and so small a quantity is required to produce the colour that the solutions before mixing may be nearly colourless.
EXPERIMENTS.
1. To a solution of sulphate of iron add a drop or two of a solution of prussiate of potash, and a blue colour will be produced.
2. Substitute sulphate of copper for iron, and the colour will be a rich brown.
3. Another blue, of quite a different tint, may be produced by letting a few drops of a solution of ammonia fall into one of sulphate of copper--a precipitate of a light blue falls down, which is dissolved by an additional quantity of the ammonia, and forms a transparent solution of the most splendid rich blue colour.
4. Into a solution of sulphate of iron let fall a few drops of a strong infusion of galls, and the colour will become a bluish-black--in fact, ink. A little tea will answer as well as the infusion of galls. This is the reason why certain stuffs formerly in general use for dressing gowns for gentlemen were so objectionable; for as they were indebted to a salt of iron for their colour, buff as it was called, a drop of tea accidentally spilt produced all the effect of a drop of ink.
5. Put into a largish test tube two or three small pieces of granulated zinc, fill it about one-third full of water, put in a few grains of iodine and boil the water, which will at first acquire a dark purple colour, gradually fading as the iodine combines with the zinc. Add a little more iodine from time to time, until the zinc is nearly all dissolved. If a few drops of this solution be added to an equally colourless solution of corrosive sublimate (a salt of mercury) a precipitate will take place of a splendid scarlet colour, brighter if possible than vermilion, which is also a preparation of mercury.
CRYSTALLIZATION OF METALS.
Some of the metals assume certain definite forms in returning from the fluid to the solid state. Bismuth shows this property more readily than most others.
EXPERIMENT.
Melt a pound or two of bismuth in an iron ladle over the fire; remove it as soon as the whole is fluid; and when the surface has become solid break a hole in it, and pour out the still fluid metal from the interior; what remains will exhibit beautifully formed crystals of a cubic shape.
Sulphur may be crystallized in the same manner, but its fumes when heated are so very unpleasant that few would wish to encounter them.
One of the most remarkable facts in chemistry, a science abounding in wonders, is the circumstance, that the mere contact of hydrogen, the lightest body known, with the metal platinum, the heaviest, when in a state of minute division, called spongy platinum, produces an intense heat, sufficient to inflame the hydrogen: of course this experiment must be made in the presence of atmospheric air or oxygen.
Time and space (or rather the want of them) compel us to conclude with a few experiments of a miscellaneous character.
TO FORM A SOLID FROM TWO LIQUIDS.[7]
Prepare separately, saturated solutions of sulphate of magnesia (Epsom salts) and carbonate of potash. On mixing them the result will be nearly solid.
[7] Saturated solutions are made by adding the salt to boiling water until it will take up no more, letting it stand till cold and then pouring off the liquid.
Solutions of muriate of lime and carbonate of potash will answer as well.
TO FORM A LIQUID FROM TWO SOLIDS.
Rub together in a Wedgewood mortar a small quantity of sulphate of soda and acetate of lead, and as they mix they will become liquid.
Carbonate of ammonia and sulphate of copper, previously reduced to powder separately, will also, when mixed, become liquid, and acquire a most splendid blue colour.
The greater number of salts have a tendency to assume regular forms, or become crystallised, when passing from the fluid to the solid state; and the size and regularity of the crystals depends in a great measure on the slow or rapid escape of the fluid in which they were dissolved. Sugar is a capital example of this property; the ordinary loaf-sugar being rapidly boiled down, as it is called: while to make sugar-candy, which is nothing but sugar in a crystallized form, the solution is allowed to evaporate slowly, and as it cools it forms into those beautiful crystals termed sugar-candy. The threads found in the centre of some of the crystals are merely placed for the purpose of hastening the formation of the crystals.
EXPERIMENTS.
1. Make a strong solution of alum, or of sulphate of copper, or blue vitriol, and place in them rough and irregular pieces of clinker from stoves, or wire-baskets, and set them by in a cool place, where they will be free from dust, and in a few days crystals of the several salts will deposit themselves on the baskets, &c.; they should then be taken out of the solutions, and dried, when they form very pretty ornaments for a room.
2. Fill a Florence flask up to the neck with a strong solution of sulphate of soda, or Glauber’s salt, boil it, and tie the mouth over with a piece of moistened bladder while boiling, and set it by in a place where it cannot be disturbed. After twenty-four hours it will probably still remain fluid. Pierce the bladder covering with a penknife, and the entrance of the air will cause the whole mass instantly to crystallize, and the flask will become quite warm from the latent caloric, of which we have spoken before, given out by the salt in passing from the fluid to the solid state. It is better to prepare two or three flasks at the same time, to provide against accidents, for the least shake will often cause crystallization to take place before the proper time.
CHANGES OF COLOUR PRODUCED BY COLOURLESS LIQUIDS.
Make a strong infusion of the leaves of the red cabbage, which will be of a beautiful blue colour; drop into it a few drops of dilute sulphuric acid, and the colour will change to a bright red; add some solution of carbonate of potash, or soda, and the red colour will gradually give way to the original blue; continue adding the alkaline solution, and the fluid will assume a bright green colour. Now resume the acid, and as it is dropped in, the colour will again change from green to blue, and from blue to red. Now this simple experiment illustrates three points: first, that acids change the colour of most vegetable blues and greens to red; second, that alkalies change most blues and reds to green; and third, that when the acid and alkali are united together, they both lose their property of changing colour, and become what is called a neutral salt, i. e. a compound possessing the properties of neither of its constituents.
ELECTRICITY.
No branch of science is more capable of affording amusement, combined with instruction, than electricity, and there are few sciences in which the experiments are more easily performed. We would therefore especially recommend it to our young friends.
The term electricity is derived from the Greek word electron, signifying amber, because electrical attraction was first discovered from its being noticed that when amber was rubbed into a certain degree of warmth, it had the power of attracting small bodies to itself.
Electricity therefore primarily treats of the phenomena and effects produced by the friction or rubbing together of certain bodies called electrics. These consist of glass, amber, resinous matters, silks, hair, wool, feathers, various vegetable substances, and atmospheric air, and the electricity so obtained is usually called Frictional Electricity, to distinguish it from that produced by chemical action, and called Voltaic Electricity.
SIMPLE MEANS OF PRODUCING ELECTRICITY.
To show the nature of electrical action, rub a piece of sealing-wax or amber upon the coat-sleeve, and it will attract light bodies, such as straws or small pieces of paper. If a clean glass tube be rubbed several times through a silken or leather cloth, and presented to any small substances, it will immediately attract and then repel them; and if a poker suspended by a dry silk string be presented to its upper end, then the lower end of the poker will exhibit the same phenomena as the tube itself, which shows that the opposite electrical condition may be induced upon other bodies by the mere neighbourhood and approach of another electrified body, and the effect so produced is called induced electricity.
When an electrified conductor is supported by non-conductors, so that the electric fluid cannot pass from the conductor to the earth, it is said to be insulated: thus the human body is a conductor of electricity--but if a person standing on a glass stool (as represented in the drawing) be charged with electricity, the electric fluid cannot pass from him to the earth, and he is said to be insulated; and if he be touched by another person standing on the ground, sparks will be exhibited at the point of contact, where also the person touching will feel a pricking sensation.
ATTRACTION AND REPULSION EXHIBITED.
In order to illustrate certain remarkable facts in this science of an amusing character, attention must be directed to the figure A B, which is a metal stand; C is a small piece of cork or pith, which is suspended from the hook by a dry silken thread. Having rubbed an electric, as a dry rod of glass, and presented it to C, the ball will be instantaneously attracted to the glass and will adhere to it. After they remain in contact for a few seconds, if the glass be withdrawn without being touched by the fingers, and again presented to the ball, the latter will be repelled instead of attracted, as in the first instance. By being touched with the finger, the ball can be deprived of its electricity, and if after this has been done we present a piece of sealing-wax in the place of the glass formerly employed, the very same phenomena will take place. On the first application the ball will be attracted, and on the second repelled.[8]
[8] For a more complete account of this interesting science we would refer the young reader to “The Boy’s Playbook on Science,” or, if more advanced, to “Noad’s Manual of Electricity.”
Before the young reader can perform any very important experiments with electricity, he must become possessed of an ELECTRICAL MACHINE, which is an instrument contrived for the purpose of rubbing together the surfaces of glass and leather. They generally consist of a cylinder, or plate of glass, and a piece of silk or leather for it to rub against, covered with an amalgam, the method of preparing which we shall hereafter describe.
HOW TO MAKE AN ELECTRICAL MACHINE.
It is very easy to make a glass machine of the cylindrical form, if the maker cannot afford to buy one. First procure a common wine bottle of good dimensions, and thickish glass. Drill a hole through its bottom, with a file moistened with dilute sulphuric acid. A blacksmith, if supplied with the acid, would undertake to do this part of the work. Through this hole and the mouth pass a spindle, as represented in the cut. The end of B should be squared to fix a handle on, and the spindle should be fixed firmly in the bottle. The bottle is then to be fixed in a frame in the following manner: the end of the spindle C passes through a hole at B; and the other end at C has the handle for turning the machine.
Next make a cushion of wash-leather stuffed with wool, and fastened to the top of a frame of the following figure. This frame is to be of such a height that the cushion shall press against the sides of the bottle, and a piece of black silk is sewn on to the top of the cushion, and hangs over the bottle D. The cushion should be smeared with an amalgam, formed by melting together in the bowl of a tobacco-pipe one part of tin with two of zinc; to which, while fluid, should be added six parts of mercury. These should be stirred about till quite cold, and then reduced to a fine powder in a mortar, and mixed with a sufficient quantity of lard to form a thickish paste. When all is done, the machine is complete.
THE CONDUCTOR.
The electricity being generated by the friction produced between the rubber and the bottle from the motion imparted by the handle, it is necessary to draw it off for use. This is performed by what is called a conductor. This is made by covering a cylinder of turned wood six inches long and two and a half inches in diameter, and nicely rounded at the ends, with tinfoil, which is then mounted on a stand on a glass rod. When used, it is to be placed in the direction of the length. In it some pins are inserted, with the points outside, in a line even with, and about half an inch from, the bottle, and it should be of such a height as to come just below the silk apron. When it is wished to charge a Leyden jar, it is to be placed at the round end of the conductor. By these simple means a great variety of pleasing experiments may be performed; but to show the various phenomena connected with this interesting study, we shall now describe an electrical machine of the newest construction, and perform our experiments with it.
THE PLATE ELECTRICAL MACHINE.
Formerly the electrical machine was made in the form of a cylinder, but now it consists of a plate A, as seen in the engraving. The plate is turned by the handle F through the rubber B B, which diffuses the excitement over the glass. The points or balls at each side of the plate carry off a constant stream of positive electricity to the prime conductor C. Negative electricity is generated by insulating the conductor to which the cushion is attached, and continuing the prime conductor with the ground, so as to carry off the fluid collected from the plate.
HOW TO DRAW SPARKS FROM THE TIP OF THE NOSE.
If the person who works the machine be supported on a stool having glass legs, and connected with the conductor by means of a glass rod, the electricity will pass from the conductor to him, and as it cannot get away, owing to the glass on which he stands being a non-conductor, any person on touching him can draw the electricity from him, which will exhibit itself in small sparks as it passes to the person who touches him. If touched on the nose, sparks of fire will issue from it.
HOW TO CHARGE A LEYDEN JAR.
A most useful piece of electrical apparatus is called the Leyden jar, here represented. It is employed for the purpose of obtaining a quantity of electricity, which may be applied to any substance. It consists of a glass jar, coated both inside and without, four-fifths of the way up, with tinfoil. A knob rises through a wooden top communicating with the inside of the jar. When it is wished to charge the jar, this knob is applied to the prime conductor of the electrical machine when in action, and a quantity of electricity being given off, the jar will remain charged with it till a connexion is made, by some good conductor of electricity, between the knob and the outside tinfoil. A piece of brass chain must hang from the stem that carries the knob, and connect it with the interior of the jar.
THE ELECTRICAL BATTERY.
If several of these jars be united, a large quantity of electricity can be collected; but, in arranging them, all the interior coatings must be made to communicate by metallic rods, and a similar union must be effected among the exterior coatings. When thus arranged, the whole series may be charged as if they formed but one jar.
For the purpose of making a direct communication between the inner or outer coatings of a jar or battery, by which a discharge is effected, an instrument called a discharging rod is employed. It consists of two bent metallic rods, terminating at one end by brass balls, and connected at another by a joint which is fixed to the end of a glass handle, and which, acting like a pair of compasses, allows of the balls being separated at certain distances. When opened to the proper degree, one of the balls is made to touch the exterior coating, and the other ball is then brought into contact with the knob of the jar, when a discharge is effected; while the glass handle secures the person holding it from the effects of the shock.
DANCING BALLS AND DOLLS.
Get two round pieces of wood, A B, and coat them with tinfoil; or two pieces of metal plate; attach one of them to the prime conductor by a chain, and let it hang about two or three inches from the knob. Place some pith-balls upon the bottom piece of wood B, and bring it under the other. Immediately this is done, and the upper piece is charged with electricity from the machine, the pith-balls will jump up and down, and from one to the other with great rapidity. If some of the pith be formed into little figures, they will also dance and leap about in the most grotesque manner. The same may be made to dance by merely holding the inside of a dry glass tumbler to the prime conductor for a few minutes, while the machine is in action, and then if this be placed over them they will jump about, to the astonishment of the spectators, as the cause of their motions is not quite so apparent.
THE ELECTRICAL KISS.
This amusing experiment is performed by means of the electrical stool. Let any lady challenge a gentleman not acquainted with the experiment to favour her with a salute. The lady thereupon mounts the glass stool, and takes hold of a chain connected with the prime conductor. The machine being then put in motion the gentleman approaches the lady, and immediately he attempts to imprint the seal of soft affection upon her coral lips, a spark will fly in his face, which generally deters him from his rash and wicked intention.
RINGING BELLS.
Bells may be made to ring by electricity in the following manner. Let three small bells be suspended from a brass wire, D D, and supported by a glass pillar A, passing through bell B to the bell E. The electrical apparatus being attached to the knob F, the electricity passes down the wires D D to the bells, which are then positively electrified and attract the clappers C C, that are negatively so, in consequence of being insulated by the silken strings, which are not conductors. The bells therefore attract the clappers till they are charged, when they strike against the centre bell to discharge themselves, and thus a peal is rung on the bells until the electricity is driven off.
WORKING POWER OF ELECTRICITY.
This may be shown in a variety of ways. The subjoined machine will exhibit the principle upon which many ingenious toys may be made by the young philosopher. In the figure A is a wooden board or stand, B B B B, four pillars of glass, gutta-percha, or sealing-wax, having fine wires, C C, stretched above. On these rest the rotatory wire or wheel F, having its points turned the reverse ways. By means of a chain attached to the conductor, and to the instrument at B, the electricity passes over the pillar B, up the wire C into the wheel, and off at the points, which causes it to be turned round on an inclined plane till it reaches the top.
THE ELECTRIFIED WIG.
While a person is on the electrical stool, if he be charged with much electricity,
“Each hair will stand on end, Like quills upon the fretful porcupine.”
A wooden head--not your own, but a real wooden head--with a wig of streaming hair, and a handsome face to correspond, may be made in the following form, with a wire in the neck to support it by, and fixed in the conductor of an electrical machine. When this is put in motion the hair will rise up, as in the figure, in a manner to astonish even the “big-wigs.”
IMITATION THUNDERCLOUDS.
To show the manner in which thunderclouds perform their operations in the air, A A is a wooden stand, on which are erected two uprights, B B; C C are two small pulleys, over which a silken cord can pull easily; E is another silken line stretched across from one upright to another; on these silken cords two pieces of thin cardboard covered with tinfoil, and cut so as to represent clouds, are to be fixed horizontally, and made to communicate, by means of thin wires F and G, one with the inside, and the other with the outside, of a charged jar, D. Now, by pulling the loop of the silk line, the clouds will be brought near the cloud 2; continue this slowly, until the clouds (which are furnished with two small brass balls) are within an inch of each other, when a beautiful flash, strongly resembling lightning in miniature, will pass from one cloud to the other, restoring electrical equilibrium.
THE LIGHTNING STROKE IMITATED.
If the jar D be put behind the stand, and the cloud 2 removed, a vessel communicating by means of a wire with the outside of the jar may be swum in water under the remaining cloud; the mast being made of two pieces, and but slightly joined together, with a hollow space in one half of the mast, into which the ends of the conductor pass, but do not touch, leaving an interval of about a quarter of an inch between them. The hollow is then filled with gun-cotton, and closed with cork. When the cloud is passed over the vessel, the mast will be struck and shattered to pieces. A strip of tinfoil, arranged with pins over the hollow part of the mast, will show how a continuous conductor will convey the discharge safely away.
THE SPORTSMAN.
This apparatus is capable of affording much amusement. A is a stand of wood, B is a common Leyden jar, out of which proceed the wires H H--one terminating in ball F, the other in the ball D--to which are attached a number of pith birds by silken strings; E is a shelf for the birds to rest upon; C is the sportsman; G his gun.
To put this operation in motion the Leyden jar is to be charged with electricity by affixing a chain to the bottom part of it, and connecting it with an electrical machine in the usual manner, or by applying it to a prime conductor, when the birds will fly off the knob to which they are fixed in consequence of their being repelled. If the sportsman and gun be then turned, so that the end of his gun shall touch the knob F, an electric spark will pass from one to the other, a report will be heard, and the birds will fall down as if shot, in consequence of the electricity having been taken from the Leyden jar. There should be a communication between the sportsman and the jar formed of tinfoil, or some metal, as shown by the dotted line on the stand.
Such are a few of many numerous experiments which may be made by the young experimenter, who is fond of science and has any ingenuity; but should he like to amuse himself with an electrifying machine of little cost, he may warm a sheet of brown paper, and then rub it briskly on a teatray with india-rubber; on raising the paper in a dark room, he will see many pretty electrical sparks.
The back of a black tom cat is sometimes recommended as a cheap electrical machine; but as the wishes of the animal have to be consulted, perhaps it is wiser to leave the cat alone.
GALVANISM, OR VOLTAIC ELECTRICITY.
“To play with fire They say is dangerous; what is it then To shake hands with the lightning, and to sport With thunder?”--TYLER.
Galvanism, or electricity of quantity, in contradistinction to frictional electricity, called electricity of intensity, owes its name to the experiments on animal irritability made in 1790 by M. Galvani, a professor of anatomy at Bologna. These experiments were suggested by the following circumstances.
ORIGIN OF GALVANISM.
It happened that the wife of Galvani, who was consumptive, was advised to take as an article of food some soup made of the flesh of frogs. Several of these creatures were killed and skinned, and were lying on the table in the laboratory close to an electrical machine, with which a pupil of the professor was making experiments. While the machine was in action, he chanced to touch the bare nerve of the leg of one of the frogs with the blade of the knife that he had in his hand, when suddenly the whole limb was thrown into violent convulsions. Galvani was not present when this occurred; but being informed of it, he immediately set himself to investigate the cause. He found that it was only when a spark was drawn from the prime conductor, and when the knife or any other good conductor was in contact with the nerve, that the contracting took place; and after a time he discovered that the effect was independent of the electrical machine, and might be equally well produced by making a metallic communication between the outside muscle and the crural nerve.
SIMPLE EXPERIMENT TO EXCITE GALVANIC ACTION.
If the young experimenter will obtain a piece of zinc of the size of half a crown and place it on the top of his tongue, and place a half-crown underneath it, and bring the edges of the half-crown and zinc in contact in front of his tongue, he will notice a peculiar sensation in the nerves of this organ, and some taste will be imparted to his mouth at the moment of contact.
WITH METAL PLATES IN WATER.
If we take two plates of different kinds of metal, platinum (or copper) and zinc, for example, and immerse them in pure water, having wires attached to them above, then if the wire of each is brought into contact in another vessel of water, a galvanic circle will be formed, the water will be slowly decomposed, its oxygen will be fixed on the zinc wire, and at the same time a current of electricity will be transmitted through the liquid to the platina or copper wire, on the end of which the other element of water, namely, the hydrogen, will make its appearance in the form of minute gas bubbles. The electrical current passes back again into the zinc at the points of its contact with the platina, and thus a continued current is kept up, and hence it is called a galvanic circle. The moment the circuit is broken by separating the wires the current ceases, but is again renewed by making them touch either in or out of the water. If a small quantity of sulphuric acid be added to the water, the phenomenon will be more apparent. The end of the wire attached to the piece of platinum or copper is called the positive pole of the battery, and that of the wire attached to the zinc the negative pole.
The current of electricity here generated will be extremely feeble; but this can be easily increased by multiplying the glasses and the number of the pieces of metal. If we take six such glasses instead of one, partially fill them with dilute sulphuric acid, and put a piece of zinc and copper into each, connecting them by means of copper wire from glass to glass through the whole series, a stronger current of electricity will be the result. The experimenter must be careful not to let the wire and zinc touch each other at the bottom of the tumblers, and must also remember that the copper of glass 1 is connected with the zinc of glass 2, and so on.
TO MAKE A MAGNET BY THE VOLTAIC CURRENT.
To effect this, make a connexion between the poles of the above or any excited battery with the two ends of a wire formed into a spiral coil, by bending common bonnet-wire closely round a cylinder, or tube, of about an inch in diameter; into this coil introduce a needle or piece of steel wire, laying it lengthways down the circles of the coil. In a few minutes after the electric fluid has passed through the spiral wire, and consequently round the needle or wire, the latter will be found to be strongly magnetized, and to possess all the properties of a magnet.
EFFECTS OF GALVANISM ON A MAGNET.
If a galvanic current, or any electric current, be made to pass along a wire under which, and in a line with it, a compass is placed, it will be found that the needle will no longer point north and south, but will take a direction nearly across the current, and point almost east and west.
CHANGE OF COLOUR BY GALVANISM.
Put a teaspoonful of sulphate of soda into a cup, and dissolve it in hot water; pour a little cabbage blue into the solution, and put a portion into two glasses, connecting them by a piece of linen or cotton cloth previously moistened in the same solution. On putting one of the wires of the galvanic pole into each glass, the acid accumulates in the one, turning the blue to a red, and the alkali in the other, rendering it green. If the wires be now reversed, the acid accumulates eventually in the glass where the alkali appeared, while the alkali passes to the glass where the acid was.
THE GALVANIC SHOCK.
If the ends of the wires of a small galvanic battery are connected with a proper electro-magnetic coil, which may now be purchased at a very cheap rate, and the wires from the coil be placed in separate basins of water, then, on dipping the fingers of each hand in the basin, a smart shock will be felt, with a particular aching accompanied with trembling. With a strong battery and larger coil this effect is felt as high as the shoulders. The shock will also be felt by simply holding the wires of a powerful galvanic battery, one in each hand, provided the hands be moistened with salt and water. Several persons may receive the shock from the battery and coil together by joining hands.
THE ELECTROTYPE.
The electro-galvanic current has in no case been more interestingly employed than in the process of electrotyping. It consists of a mode of obtaining the copy of coins, medals, engraved plates, and other objects, which may be easily illustrated.
HOW TO MAKE AN ELECTROTYPE APPARATUS.
Take an earthen jar and a porous tube; fill the tube with ten parts of water and one of sulphuric acid; put it into the jar, into which pour as much of a solution of sulphate of copper (blue vitriol) as will fill three parts of it; place in the tube a piece of zinc, to which a copper wire is soldered and bent round, so that one end be immersed in the sulphate of copper; and a deposit of the copper will be immediately formed upon the wire. If there be plenty of acid and water, so as to allow of the action enduring for a long time, this process will go on till it has deposited all the copper. This is the principle upon which electrotyping proceeds,--a principle referable to electro-chemical decomposition.
The diagram represents an outer vessel of wood, glass, or earthenware, capable of holding a pint of liquid, within which there is suspended a short lamp-glass A, the one end being open, and the other, B, closed with a diaphragm of plaster of Paris; C is a small bag of crystals of sulphate of copper, to keep up the strength of the solution; Z is the zinc, and M the metal.
TO OBTAIN THE COPY OF A COIN OR MEDAL.
Never place the original medal in the apparatus, or the deposited copper may adhere so tightly to it that the removal destroys the beauty of the medal. Having taken an impression in sealing-wax, cover the latter with black-lead, and attach a wire so that it is in contact with the black-lead. To the wire and cast thus arranged a piece of sheet or cast zinc, amalgamated with mercury, must be attached, and we are at once furnished with the materials for the battery, as the object to be copied supplies the place of the copper. The medal must always be placed horizontally. Now let the apparatus be charged with the solution, by pouring into the outer vessel a portion of the coppery solution, so that it will stand about an inch above the medal; then pour in the glass the dilute acid to the same height as the former; now introduce the zinc into the acid, and the object to be copied into the solution of copper, which will immediately be deposited on the medal, and when of a sufficient thickness may be taken off.
HEAT.
HEAT, OR CALORIC.
The chief agent in causing the repulsion or separation of the particles of bodies from each other is heat, or more correctly caloric, by which is understood the unknown cause of the effect called heat. Philosophers are not agreed upon the nature of this wonderful agent. It pervades all nature, is the cause of nearly all the changes that take place both in organic and inorganic matter, and has great influence in the meteorological phenomena which we observe in the atmosphere that surrounds our planet. It appears to be intimately connected with light, electricity, and magnetism,--subjects which the genius of Faraday and others have investigated, and by their discoveries brought us nearer to the knowledge of the real nature of these most wonderful forces.
Caloric, then, exists in all bodies, and has a constant tendency to equalize itself, as far at least as its outward manifestation, called temperature, is concerned; for if a hot body be brought near colder ones, it will give up heat to them, until by its loss and their gain they all become of the same temperature; and this proceeds more or less rapidly, according as the original difference of temperature was greater or less. Some other circumstances also influence this equalization. The converse will take place on introducing a cold body among warmer ones, when heat will be abstracted from all the bodies within reach of its influence, until it has absorbed sufficient caloric to bring its own temperature to an equality with theirs. This is the true explanation of the apparent production of cold. When, for instance, an iceberg comes across a ship’s course, it appears to give out cold, whereas, it has abstracted the heat from the air and sea in its neighbourhood, and they in turn act upon the ship and everything in it, until one common temperature is produced in all the neighbouring bodies.
It does not follow that the bodies thus equalized in temperature contain equal quantities of caloric; far from it. Each body requires a particular quantity of caloric to raise its temperature through a certain number of degrees; and such quantity is called its specific caloric. A pound of water, for instance, will take just twice as much caloric as a pound of olive oil, to raise its temperature through the same number of degrees; the specific caloric of water is therefore double that of oil. Mix any quantity of oil at 60° of temperature with an equal weight of water at 90°, and you will find the temperature of the mixture to be nearly 80°, instead of only 74° or 75°, showing that while the water has lost only 10° of caloric, the mixture has risen 20°. If the oil be at 90°, and the water at 60°, the resulting temperature will be only 70°, or thereabouts, instead of 75°, the mean; thus, here the hot oil has lost 20°, while the mixture has risen only 10°; the water, then, contains at the same temperature twice as much caloric as the oil; its specific caloric is double that of the oil. This mean temperature does result when equal weights of the same body at different temperatures are mixed together.
The sensations called heat and cold are by no means accurate measures of the real temperature of any substances, for many causes influence these sensations, some belonging to the substances themselves, others to the state of our organs at the time. Every one has remarked that metals in a warm room feel warmer, and in a cold room colder than wooden articles, and these again than woollen or cotton articles of dress or furniture; this arises from metals being what is termed better conductors of heat than wood, and this better than wool, &c., that is, they give out or absorb caloric more rapidly than these last. Some philosophers, wishing to ascertain how much heat the human body could endure, had a room heated with stoves, every crevice being carefully stopped, until the temperature rose so high that a beefsteak placed on the table was sufficiently cooked to be eaten. They were dressed in flannel, and could with impunity touch the carpets, curtains, &c., in the room; but the iron handles, fire-irons, and all metallic substances, burnt their fingers; and one who wore silver spectacles was obliged to remove them to save his nose. The fallacy of our sensations may be easily shown by taking two basins, placing in one some water at 100°, in another some water at as low a temperature as can easily be procured--hold the right hand in one, the left in the other, for a few minutes, and then mix them, and place both hands in the mixture; it will feel quite cold to the hand that had been in the hotter water, and hot to the other.
In order to arrive at a correct estimate of the temperature of bodies, instruments are made use of called thermometers, or measurers of heat, which show increase or diminution of temperature by the rising or falling of a column of some fluid in a tube of glass, one end of which is expanded into a bulb, and the other hermetically sealed. This effect is produced by the expansion or swelling of the fluid as caloric is added to, and its contraction when caloric is abstracted from it. Coloured spirits of wine, or quicksilver, are the most usual thermometric fluids, and the tube containing them is fixed to a wooden or metallic frame, on which certain divisions are marked, called degrees.
That in general use in England is called Fahrenheit’s, from the name of the person who first introduced that particular scale. In this thermometer, the point at which the mercury in the tube stands when plunged into melting ice, is marked 32°, and the distance between that point, and the point to which the mercury rises in boiling water, is divided into 180 equal parts, called degrees; so that water is said to boil at 212° = 180° + 32°. There are two other scales of temperature used in different parts of the world, but it is not worth while to notice them here.
Not only do different bodies at the same degree of temperature contain very different quantities of caloric, but this also is the case with the same body in different forms. Ice, water, and steam, are three forms of the same body, but ice at 32° contains much less caloric than water at the same temperature, and water at 212° contains much less caloric than steam (or water in a state of vapour) at that temperature.
Place in a jar any given quantity of snow, or small pieces of ice, at 32°, and in another the same weight of water at 32°, pour on each an equal weight of water at 172°, and you will find that in the first case the ice will be melted, but the temperature will remain at 32° or thereabouts, while the temperature of the water in the other vessel will have risen to 100° or thereabouts, being as near as possible the half of the excess of the temperature of the hot water, 140° over that of the cold, namely 70° added to 32°, the original temperature. Now, what has become of the heat which was added to the ice, and is apparently lost?--it is absorbed by the ice in its passage to the fluid state; so that water may be said to be a compound of ice and caloric.
Again, take 10 ounces of water at about 50°, and add 1 oz. of water at 212°, and the temperature of the mixture will be about 66°; then condense some steam at 212°, into another 10 oz. of water until it has become 11 oz., and you will find the temperature will be nearly 212°. Why does the ounce of steam at 212° raise the temperature of the water so much higher than the ounce of water at the same temperature? Obviously because it contains hidden in its substance a vast quantity of caloric, not to be detected by the thermometer; in fact, that steam is a compound of water and caloric, as water is a compound of ice and caloric; and this caloric which exists, more or less, in all bodies without producing any obvious effect, is called latent caloric, from the Latin verb lateo, to lie hid. The quantity of caloric thus absorbed as it were by various bodies, differs for each body, and for the same body in different forms, as mentioned above.
EXPANSION.
As a general rule, all bodies, whether solid, liquid, or gaseous, are expanded by caloric. This may be shown by experiments in each form of matter.
Have a small iron rod made, which when cold just passes through a hole in a plate of metal; heat it, and it will no longer pass; after a time the rod will return to its former temperature, and then will go through the hole as before. The rod increases in length as well as width; if you have a gauge divided into 1/100 of an inch, and place the rod in it when cold, noting its position, on heating it will extend to a greater length in the gauge, returning to its former place when cool.
The effect of caloric in causing fluids to expand is actually employed as a measure of quantity in the thermometer, the rise of the fluid in the tube when heated depending on the increased bulk of the fluid occasioned by the addition of caloric. The same fact is to be noticed every day when the cook fills the kettle, and places it on the fire. As the water becomes warmer it expands, that is, takes up more room than it did before, and the water escapes by slow degrees, increasing as the heat increases, up to the point of boiling, when a sudden commotion takes place from the condensation of a portion of the water into steam.
But it is in the form of vapour or gas, (which by the bye is not the same thing,[9]) that the expansive force of caloric is most obvious. The gigantic powers of the steam-engine depend entirely on the tendency of vapour to expand on the addition of caloric; and this force of expansion appears to have no limit; boilers made of iron plates an inch or even more in thickness, and the buildings or ships containing them, having been torn to pieces and scattered in all directions by the expansive power of steam. Take a bladder, and fill it about half full of air, and tie the neck securely; upon holding it to the fire it will swell out, and become quite tense from the expansion of the contained air.
[9] It may be well to state here, that by vapour is generally understood the aërial form of a substance usually existing in a solid or fluid form at ordinary temperatures; as the vapour of iodine, a solid; of mercury, water, spirits, and other fluids: while the term gas is applied to those bodies usually known in the aërial state; thus oxygen, nitrogen, carbonic acid, hydrogen, &c. &c., are called gases. It is, however, but an arbitrary distinction; for many of these gases have, by the combined influence of cold and powerful pressure, been converted into fluids, and even solids--carbonic acid gas for instance!
The principal source of caloric is the sun, whose beams, diffused through all nature by the refractive property of the atmosphere, are the source of vitality both to vegetables and animals, and when concentrated by a large convex lens, produce the most intense heat, sufficient to light a piece of diamond, and melt platinum. Caloric is also produced or evolved by combustion, by friction, percussion, chemical combination, electricity, and galvanism.
The evolution of heat by friction may be witnessed daily in a thousand instances. Lucifer matches are lighted by rubbing the highly inflammable substances with which they are tipped against a piece of sand-paper. Nearly all savage people procure fire by rubbing a piece of hard wood violently against a softer piece. The axle-trees of steam-engines, and even of carriages, have been known to be so heated by friction as to endanger burning the carriage; and it is very usual to be obliged to pour a quantity of cold water on the iron axle of the carriages of an express train after an hour of constant and rapid work. If you merely rub the blade of a knife rapidly on a piece of wood, it will become hot enough to burn your hand.
Percussion is merely a more energetic kind of friction, and is often resorted to by the blacksmith to light his furnace. He places a nail or other piece of soft iron on his anvil, and beats it rapidly with the hammer, when it becomes actually red hot. The production of sparks by striking flint against steel, or two pieces of flint one against the other, are familiar instances of heat produced by percussion.
One of the most powerful means of producing heat is the process of combustion.
Combustion, as the word imports, is the burning together of two or more substances, a chemical union of oxygen generally with carbon and hydrogen in some shape or other. In our ordinary fires we burn coal, a hydro-carbon as it is called; and the gas which is now so universally used for the purpose of illumination, is a compound of the same bodies--so wax, tallow, oil of various kinds, both of animal and vegetable origin, are all hydro-carbons.
On the application of a sufficient heat, and a free access of atmospheric air, or of some other gas containing oxygen in a certain state of combination, these bodies take fire, and continue to burn either with flame, or a red or even white heat without flame, until they are consumed; that is, until they have entered into new combinations with the oxygen, and are converted into carbonic acid and water, the carbon forming the first product, the hydrogen the other.
The following experiment shows the production of heat by chemical action alone. Bruise some fresh prepared crystals of nitrate of copper, spread them over a piece of tin-foil, sprinkle them with a little water; then fold up the foil tightly as rapidly as possible, and in a minute or two it will become red-hot, the tin apparently burning away. This heat is produced by the energetic action of the tin on the nitrate of copper, taking away its oxygen in order to unite with the nitric acid, for which, as well as for the oxygen, the tin has a much greater affinity than the copper has.
Combustion without flame may be shown in a very elegant and agreeable manner, by making a coil of platinum wire by twisting it round the stem of a tobacco-pipe, or any cylindrical body, for a dozen times or so, leaving about an inch straight, which should be inserted into the wick of a spirit-lamp; light the lamp, and after it has burnt for a minute or two extinguish the flame quickly; the wire will soon become red hot, and, if kept from draughts of air, will continue to burn until all the spirit is consumed. Spongy platinum, as it is called, answers rather better than wire, and has been employed in the formation of fumigators for the drawing-room, in which, instead of pure spirit, some perfume, such as lavender water, is used; by its combustion an agreeable odour is diffused through the apartment. These little lamps were much in vogue a few years ago, but are now nearly out of fashion.
Experiments on combustion might be multiplied almost to any amount, but the above will be sufficient for the present. When we come to treat of the properties of the gases and some other substances, we shall have occasion to recur to this subject.
The production of caloric by chemical combination may be exhibited by mixing carefully one part of oil of vitriol with two of water, when sufficient heat will be produced to boil some water in a thin and narrow tube, which may be used as a rod to stir the mixture.
The production of heat by electric and galvanic agency belongs to another subject. I will content myself with saying here, that these forces afford the most powerful aid in decomposing and uniting various bodies, and that it was by the immense power of a battery of 2,000 pairs of plates, belonging to the Royal Institution in London, that Sir H. Davy discovered the metallic bases of the alkalies and earths.
HYDRAULICS.
The science of Hydraulics comprehends the laws which regulate non-elastic fluids in motion, and especially water, &c.
Water can only be set in motion by two causes--the pressure of the atmosphere, or its own gravity. The principal law concerning fluids is, that they always preserve their own level. Hence water can be distributed over a town from any reservoir that is higher than the houses to be supplied; and the same principle will enable us to form fountains in a garden, or other place. Should any of our young friends wish to form a fountain, or jet d’eau, they may, by bringing a pipe from T, a water-tank, which should be at the upper part of the house, convey the water down to the garden. Then by leading it through the earth, underneath the path or grass-plot, and turning it to a perpendicular position, the water will spring out, and rise nearly as high as the level of that in the tank. The part of the pipe at B should have a turnkey, so that the water may be let on or shut off at pleasure.
THE SYPHON.
The syphon B is a bent tube, having one leg shorter than the other. It acts by the pressure of the atmosphere. In order to make a syphon act, it is necessary first to fill both legs quite full of the fluid; and then the shorter leg must be placed in the vessel to be emptied. Immediately upon withdrawing the finger from the longer leg, the liquor will flow. Any young person may form a syphon by a small piece of leaden pipe, bent into the form above.
THE PUMP.
The action of the common pump is as follows: When the handle A is raised, the piston-rod B descends, and brings the piston-valve, called the sucker, or bucket, to another valve, C, which is fixed, and opens inwards towards the piston. When the handle is drawn down, the piston is raised, and, as it is air-tight, a vacuum is produced between the two valves; the air in the barrel of the pump, betwixt the lower valve and the water, then forces open the lower valve, and rushes through to fill up this vacuum; and the air in the pump being less dense than the external atmosphere, the water is forced a short way up the barrel. When the piston again descends to the lower valve, the air between them is again forced out by forcing open the upper valve; and when the piston is raised, a vacuum is again produced, and the air below the lower valve rushes up, and the water in consequence is again raised a little further. This operation continues until the water rises above the lower valve; at every stroke afterwards, the water passes through the valve of the descending piston, and is raised by it, on its ascent, until it issues out of the spout.
THE HYDRAULIC DANCER.
Make a little figure of cork, in the shape of a dancing mountebank, sailor, &c. In this figure place a small hollow cone, made of thin leaf brass. When this figure is placed upon any jet d’eau, such as that of the fountain recommended to be constructed, it will be suspended on the top of the water, and perform a great variety of amusing motions. If a hollow ball of very thin copper, of an inch in diameter, be placed on a similar jet, it will remain suspended, turning round and spreading the water all about it.
THE WATER SNAIL, OR ARCHIMEDEAN SCREW, may easily be constructed. Purchase a yard of small leaden pipe, and twist it round a pole, as in the following figure, A; place a handle at its upper end, B, and let its lower end rest in the water. Between the last turn of the pipe and the orifice place a paddle-wheel, C. Now, should the water be that of a running stream, the force of the stream will turn the pipe, and the water will rise in it till it empties itself into the trough at D. Should the water have no motion, the turning of the handle at B will elevate the water from the lower to the higher level.
MAGNETISM.
The attractive power of the loadstone has been known from a very remote period. The natural magnet appears native in a grey iron ore in octahedral crystals, composed of 168 parts of iron, and 64 parts of oxygen, Fe₃O₄. Its properties seem to have been studied in Europe during the dark ages, and a directive power is alluded to by Cardinal James de Vitri, who flourished about the year 1200, who observed, that it was indispensable to those who travel much by sea.
In modern times, the history as well as the nature of the magnet has engaged remarkable attention; and it has been determined beyond all dispute that the magnet was used by the Chinese under the name of the tche-chy (directing-stone) about 2604 years before Christ. It passed from them to the Arabs, and was first used in Europe after the Crusades; and Ludi Vestomanus asserts, that about the year 1500 he saw a pilot in the East Indies direct his course by a magnetic needle like those now in use.
RELATION OF MAGNETISM TO ELECTRICITY.
The most remarkable theories have been invented to account for the phenomena of magnetism. Halley imagined magnetic globes to be moving to and fro in the interior of the earth. Barlow’s theory, which refers the whole to electrical currents, is the most rational. Dr. Faraday, for whose kindness to us in early days we always feel grateful, in a series of very curious experiments, has succeeded in identifying magnetism with galvanism, by directing galvanic currents at right angles to the direction of powerful magnets. And its connexion with this and the common species of electricity has deprived it of all its conjuring powers, and reduced it to the well-defined action of electrical bodies.
It is not for us to write either a history of this interesting subject, or to treat it as a science to be acquired; but as it embodies a great number of most instructive and amusing experiments, we think it proper to introduce it here.
TO MAKE ARTIFICIAL MAGNETS.
This may be done by stroking a piece of hard steel with a natural or artificial magnet. Take a common sewing-needle and pass the north pole of a magnet from the eye to the point, pressing it gently in so doing. After reaching the end of the needle the magnet must not be passed back again towards the eye, but must be lifted up and applied again to that end, the friction being always in the same direction. After repeating this for a few times the needle will become magnetised, and attract iron filings, &c.
HOW TO MAGNETISE A POKER.
Hold it in the left hand in a position slightly inclined from the perpendicular, the lower end pointing to the north, and then strike it smartly several times with a large iron hammer, and it will be found to possess the powers of a magnet, although but slightly.
TO SHOW MAGNETIC REPULSION AND ATTRACTION.
Suspend two short pieces of iron wire, N S, N S, so that they will hang in contact in a vertical position. If the north pole of a magnet N be now brought to a moderate distance between the wires, they will recede from each other, as in figure 1.
The ends S S being made south poles by induction from the north pole N, will repel each other, and so will the north poles N N. This separation of the wires will increase as the magnet approaches them, but there will be a particular distance at which the attractive force of N overcomes the repulsive force of the poles S S, and causes the wires to converge, as in figure 2; the north poles N N still exhibiting their mutual repulsion.
NORTH AND SOUTH POLES OF THE MAGNET.
Each magnet has its poles, north and south--the north or south poles of one magnet, repel the north and south pole of another. If a magnet, as in the following figure, be dipped in some iron filings, they will be immediately attracted to one end. Supposing this to be the north pole, each of the ends of the filings, not in contact with the magnet, will become north poles, while the ends in contact will by induction become south poles. Both will have a tendency to repel each other, and the filings will stand on the magnet as in the figure.
POLARITY OF THE MAGNET.
The best method of proving this is to take a magnet or a piece of steel rendered magnetic, and to place it on a piece of cork by laying it in a groove cut to receive it. If the cork be placed in the centre of a basin of water, and allowed to swim freely on its surface, so that it is not attracted by the sides of the basin, it will be found to turn its north pole to the north, and its south pole to the south, the same as the mariner’s compass. If you fix two magnets in two pieces of cork, and place them also in a basin of water, and they are in a parallel position with the same poles together, that is, north to north, and south to south, they will mutually repel each other; but if the contrary poles point to one another, as north to south, they will be attracted.
THE MAGNETIC FISH.
Fish are to be purchased at the toy-shops, by which the young “magnétique” may perform this experiment; they are made hollow, and will float on the water. In the mouth of each should be inserted a piece of magnetic wire. The angling rod is like any other rod, and has a silken thread for a line, and an iron hook also strongly magnetised. To catch the fish it is only necessary to put the hook in contact with the noses of the fish, and they will be taken without any of the baits mentioned in the former part of this work.
THE MAGNETIC SWAN.
The figure of a swan should be cut in cork, and within its beak a small strongly magnetised piece of steel should be placed. The swan should then be covered with a coating of white wax, and fashioned further into the shape of a swan, and glass beads may be placed in its head for eyes. This should be placed in a small tub or large basin of water, and to make it swim about, you should place in a white stick about nine inches long a magnetic bar, on which the north and south poles are marked. If you wish to bring the swan towards you, present to him the north pole of the wand, if you wish it to retire, present the south pole, and thus you may direct the swan to any part you desire.
TO SUSPEND A NEEDLE IN THE AIR BY MAGNETISM.
Place a magnet on a stand to raise it a little above the table; then bring a small sewing-needle containing a thread, within a little of the magnet, keeping hold of the thread to prevent the needle from attaching itself to the magnet. The needle in endeavouring to fly to the magnet, and being prevented by the thread, will remain curiously suspended in the air, reminding us of the fable of Mahomed’s coffin.
TO MAKE ARTIFICIAL MAGNETS WITHOUT THE AID EITHER OF NATURAL LOADSTONES OR ARTIFICIAL MAGNETS.
Take an iron poker and tongs, or two bars of iron, the larger and the older the better, and fixing the poker upright, hold to it with the left hand near the top P by a silk thread, a bar of soft steel about three inches long, one fourth of an inch broad, and one twentieth thick; mark one end, and let this end be downwards. Then grasping the tongs T with the right hand a little below the middle, and keeping them nearly in a vertical line, let the bar B be rubbed with the lower end L of the tongs, from the marked end of the bar to its upper end about ten times of each side of it. By this means the bar B will receive as much magnetism as will enable it to lift a small key at the marked end; and this end of the bar being suspended by its middle, or made to rest on a joint, will turn to the north, and is called its north pole, the unmarked end being the south pole. This is the method recommended by Mr. Caxton, in his process, which he regarded superior to those in former use, and of which a more detailed account will be found in his interesting volume.
HORSE-SHOE MAGNETS.
The form of a horse-shoe is generally given to magnetised bars, when both poles are wanted to act together, which frequently happens in various experiments, such as for lifting weights by the force of magnetic attraction, and for magnetising steel bars by the process of double touch, for which they are exceedingly convenient. The following is the method of making a powerful magnetic battery of the horse-shoe form. Twelve bars or plates of steel are to be taken, and having been previously bent to the required form, that is, the horse-shoe shape, they are then bound together by means of rivets at their ends; before being finally fastened they are each separately magnetised, and afterwards finally united.
Horse-shoe magnets should have a short bar of soft iron adapted to connect the two poles, and should never be laid by without such a piece of iron adhering to them. Bar magnets should be kept in pairs with their poles turned in contrary directions, and they should be kept from rust. Both kinds of magnets have their power not only preserved but increased, by keeping them surrounded with a mass of dry filings of soft iron, each particle of which will re-act by its induced magnetism upon the point of the magnet to which it adheres, and maintain in that point its primitive magnetic state.
EXPERIMENT TO SHOW THAT SOFT IRON POSSESSES MAGNETIC PROPERTIES WHILE IT REMAINS IN THE VICINITY OF A MAGNET.
Let M be a magnet and K a key, held horizontally near one of its poles, or near its lower edge. Then if another piece of iron, such as a small nail, be applied to the other end of the key, the nail will hang from the key, and will continue to do so while the magnet is slowly withdrawn; but when it has been removed beyond a certain distance, the nail will drop from the key, because the magnetism induced in the key becomes at that distance too weak to support the weight of the nail. That this is the real cause of its falling off may be proved by taking a still lighter fragment of iron, such as a piece of very slender wire, and applying it to the key. The magnetism of the key will still be sufficiently strong to support the wire, though it cannot the nail, and it will continue to support it even when the magnet is yet further removed; at length, however, it drops off.
ELECTRO-MAGNETISM.
The identity of magnetism with electricity alluded to in a former paragraph, has led to the formation of a new science under the above name, and to some of the interesting experiments connected with it, we shall briefly allude for the amusement of the young reader.
POWER OF THE ELECTRO-MAGNET.
The same influence which affects the magnetic needle already described, will also communicate magnetism to soft iron. If a bar of that metal bent, as in the drawing, be surrounded with a common bonnet wire, or a copper wire prevented from touching the iron by a winding of cotton or thread, and then if a current of voltaic electricity be sent through the wire, the bar becomes a powerful magnet, and will continue so as long as the connexion with the battery is preserved. On breaking the contact, the magnetism disappears. This experiment may be easily made by the young reader with a horse-shoe magnet, surrounded by several coils of wire. P is the positive, and N the negative pole.
THE MARINER’S COMPASS AND EXPERIMENTS WITH A POCKET COMPASS.
The mariner’s compass is an artificial magnet fitted in a proper box, and consists of three parts--1, the box; 2, the card or fly; and 3, the needle. The box is suspended in a square wooden case, by means of two concentric brass circles called gimbals, so fixed by brazen axes to the two boxes, that the inner one, or compass-box, retains a horizontal position in all motions of the ship. The card is a circular piece of paper which is fastened upon the needle, and moves with it. The outer edge of the card is divided into thirty-two points, as shown in the engraving, called points of the compass. The needle is a slender bar of hardened steel, having a hollow agate cup in the centre, which moves upon the point of a pivot made of brass.
VARIATION OF THE NEEDLE.
The magnetic needle does not point exactly north and south, but the north pole of the needle takes a direction to the west of the true north. It is constantly changing, and varies at different parts of the earth, and at different times of the day.
DIP OF THE NEEDLE.
Another remarkable and evident manifestation of the influence of the magnetism of the earth upon the needle is the inclination or dip of the latter, which is a deviation from its horizontal place in a downward direction in northern regions of its north, and in southern regions of its south pole. In balancing the needle on the card, on account of this dipping, a small weight or moveable piece of brass is placed on one end of the needle, by the shifting of which either nearer to or further from the centre, the needle will always be balanced.
USEFUL AMUSEMENT WITH THE POCKET COMPASS.
Pocket compasses are to be bought for five or six shillings, and may be used in many ways. In travelling over mountains or a wide extended moor, they are indispensably necessary; and no one should go a tour into Wales, Scotland, or the lakes without such a companion, and it will be a very useful and amusing exercise for any young person to take the bearings of his own or some particular locality, and make out what may be called a bearing card. This he may easily do in the following manner. Supposing he wishes, for instance, to take the bearings of his own house, he has nothing to do but to set his pocket compass upon a map of the district,--a county map will do very well, unless his house stands on the verge of a county, then two county maps will be necessary. He must make the north of the map exactly coincide with the north, as indicated by his compass, and having fixed his map in this situation, he should take a ruler and piece of paper, and dot down the exact bearings of each important town, or place, or village, around him. Let him suppose himself, for instance, in the town of Cambridge, and laying down his map as indicated by the compass, north to north and south to south, he will find the following places due north, Wilberton, Wentworth; Little Wilbraham, Teversham, due east; Duxford and Chesterfield, south; Coton and St. Neots in Huntingdonshire, west. The other points of the compass may be filled up in the same manner. Should therefore our young friend be upon any elevated situation near his own dwelling, or upon any other elevated spot from which the bearings have been taken, he will be able to inform his young friends that such and such a place lies in such a direction, that this place lies due north, the other north-west, a third south-east, the fourth south-west, &c. &c.
INTERESTING PARTICULARS CONCERNING THE MAGNET.
Fire-irons which have rested in an upright position in a room during the summer months are often highly magnetic.
Iron bars standing erect, such as the gratings of a prison cell, or the iron railings before houses, are often magnetic.
The great iron-clad ships, which have now replaced the wooden walls of Old England, are powerfully magnetic, and therefore affect the compass by which the vessel is steered; ingenious arrangements are therefore made to correct the effect of the local attraction, so that the man-of-war may be steered correctly.
Magnetism may be made to pass through a deal board; to exhibit which, lay a needle on the smooth part above, and run a magnet along the under side, and the needle will be found to follow the course of the magnet. A magnet dipped into boiling water loses part of its magnetism, which however returns upon its cooling.
A sudden blow given to a magnet often destroys its magnetic power.
MECHANICS.
“These are machinations comical.”--FORD.
There is no subject of such importance as Mechanics, as its principles are founded upon the properties of matter and the laws of motion; and in knowing something of these, the tyro will lay the foundation of all substantial knowledge.
The properties of matter are the following: Solidity (or Impenetrability), Divisibility, Mobility, Elasticity, Brittleness, Malleability, Ductility, and Tenacity.
The laws of motion are as follow:--
1. Every body continues in a state of rest or of uniform rectilineal motion, unless affected by some extraneous force.
2. The change of motion is always proportionate to the impelling force.
3. Action and reaction are always equal and contrary.
EXPERIMENT OF THE LAW OF MOTION.
In shooting at “taw,” if the marble be struck “plump,” as it is called, it moves forward exactly in the same line of direction; but if struck sideways, it will move in an oblique direction, and its course will be in a line situated between the direction of its former motion and that of the force impressed. This is called the resolution of forces.
BALANCING.
The centre of gravity in a body is that part about which all the other parts equally balance each other. In balancing a stick upon the finger, or upon the chin, it is necessary only to keep the chin or finger exactly under the point which is called the centre of gravity.
THE PRANCING HORSE.
Cut out the figure of a horse, and having fixed a curved iron wire to the under part of its body, place a small ball of lead upon it. Place the hind legs of the horse on the table, and it will rock to and fro. If the ball be removed, the horse would immediately tumble, because unsupported, the centre of gravity being in the front of the prop; but upon the ball being replaced, the centre of gravity immediately changes its position, and is brought under the prop, and the horse is again in equilibrio.
TO CONSTRUCT A FIGURE, WHICH, BEING PLACED UPON A CURVED SURFACE, AND INCLINED IN ANY POSITION, SHALL, WHEN LEFT TO ITSELF, RETURN TO ITS FORMER POSITION.
The feet of the figure rest on a curved pivot, which is sustained by two loaded balls below; for the weight of these balls being much greater than that of the figure, their effect is to bring the centre of gravity of the whole beneath the point on which it rests; consequently the equilibrium will resist any slight force to disturb it.
TO MAKE A CARRIAGE RUN IN AN INVERTED POSITION WITHOUT FALLING.
It is pretty well known to most boys, that if a tumbler of water be placed within a broad wooden hoop, the whole may be whirled round without falling, owing to the centrifugal force. On the same principle, if a small carriage be placed on an iron band or rail, it will ascend the curve, become inverted, and descend again, without falling.
TO CAUSE A CYLINDER TO ROLL BY ITS OWN WEIGHT UP-HILL.
Procure a coffee-canister, and loading it at F with a piece of lead, which may be fixed in with solder, the position of the centre of gravity is thus altered. If a cylinder so constructed be placed on an inclined plane, and the loaded part above, it will roll up-hill without assistance.
THE BALANCED STICK.
Procure a piece of wood, about nine inches in length and about half an inch in thickness, and thrust into its upper end the blades of two penknives, on either side one. Place the other end upon the tip of the fore-finger, and it will keep its place without falling.
THE CHINESE MANDARIN.
Construct out of the pith of the elder a little mandarin; then provide a base for it to sit in, like a kettle-drum. Into this put some heavy substance, such as half a leaden bullet; fasten the figure to this, and in whatever position it may be placed, it will, when left to itself, immediately return to its upright position.
TO MAKE A SHILLING TURN ON ITS EDGE ON THE POINT OF A NEEDLE.
Take a bottle, with a cork in its neck, and place in it, in a perpendicular position, a middle-sized needle. Fix a shilling into another cork, by cutting a nick in it; and stick into the same cork two small table-forks, opposite each other, with the handles inclining outwards and downwards. If the rim of the shilling be now poised on the point of the needle, it may easily be made to spin round without falling, as the centre of gravity is below the centre of suspension.
THE DANCING PEA.
If you stick through a pea, or small ball of pith, two pins at right angles, and defend the points with pieces of sealingwax, it may be kept in equilibrio at a short distance from the end of a straight tube, by means of a current of breath from the mouth, which imparts a rotatory motion to the pea.[10]
[10] The pins are only used to hold the pea steady before it is blown from the pipe, as the pea alone will dance quite as well.
OBLIQUITY OF MOTION.
Cut a piece of pasteboard into the following shape, and describe on it a spiral line; cut this out with a penknife, and then suspend it on a large skewer or pin, as seen in the engraving. If the whole be now placed on a warm stove, or over the flame of a candle or lamp, it will revolve with considerable velocity. The card, after being cut into the spiral, may be made to represent a snake or dragon, and when in motion will produce a very pleasing effect.
THE BRIDGE OF KNIVES.
Place three glasses, A A A, in the form of a triangle, and arrange three knives upon them, as shown in the figure,--the blade of No. 1 over that of No. 2, and that over No. 3, which rests on No. 1. The bridge so made will be self-supported.
THE TOPER’S TRIPOD.
Place three tobacco-pipes in the position shown in the engraving, the mouth of the bowls downwards, and the lower end of the stems upon the stem just by the bowls. This tripod, if carefully put together, will support considerably more than a pot of “Lockwood’s home-brewed,” equally celebrated with the trick.
THE MICROSCOPE.
At any time of the year or hour of the day there are few pursuits more interesting, and at the same time instructive, than the study of Nature by means of the microscope.
This instrument has revolutionized science, solved many problems that had wearied the souls of older naturalists, and even in its simplest form is beyond all value to those who love Nature and the objects which they see around them. The microscope opens a new world to us. When the first telescope was directed to the heavens, and unlocked the mysteries of the skies, when it crumbled into dust all the theories of the past centuries, and told mankind that the planets were not merely instruments of fortune-telling, whose voices were intelligible to a chosen few, but orbs far vaster than our own; even then the new world of thought into which man entered was no wider than that which is displayed by the poorest lens that possesses the power of magnifying.
All of us must admire the more than awful grandeur of that universe whereof we form so infinitesimal a part, wherein the stars are scattered as the sand on the sea-shore, and every star a sun, the centre of a system of orbs too distant for the eye of man to perceive. Looking at our nearest planet, and observing on her face vast mountain-chains, ravines into which the light of the sun can never penetrate, and volcanoes whose craters are so wide that they would take in the whole of London, the whole of Birmingham, and all the country between them, we can judge by analogy of the unseen wonders which must exist in the world beyond our ken.
But to him who can read Nature rightly, the microscope is a teacher as grand as its sister instrument, and the awful magnificence of Nature is as evident in a midge’s wing as in the more patent glories of the sun, moon, and stars. In the following pages we hope to put the readers of this book in the way to read their microscope rightly--possibly to make it--and to show that much can be done with small means when “there’s a will,” and to indicate to them that objects of no small interest can be found without stirring from the room in which we sit, or even from the table on which our microscope is placed.
Some of our readers may say, when they read the heading of this paper, that they should like a microscope very much, but that they have no money to buy it, and that their parents cannot afford one.
This is just the feeling which we used to have when a boy, for in those days microscopes were microscopes indeed, and you had your choice between a little instrument, with a series of brass cups, having glasses in them, which magnified slightly but defined clearly, or a great composition of brass and iron, looking like a rocket-tube, with an eye-piece at one end and a glass shot at the other. In was very costly, very imposing, and magnified very highly; but it strained the eyes painfully, had no defining capacities, and made all the objects look as if they were seen through a thick fog. Practically, therefore, the former was the only instrument that was available.
A still more useful instrument, however, was that which can always be obtained for a few shillings, and which is now made wonderfully cheap and wonderfully good; we mean the double or treble pocket-lens. So we say, if you cannot afford a really good microscope, do not waste your money upon inferior and pretentious instruments, but get a sound pocket-lens.
It has a thousand advantages. It is portable, and is even more useful in the fields than in the house. It defines very clearly, and needs little trouble in manipulation. We need not say how difficult is the task of getting a complicated instrument to define properly, how impossible with a bad one. The object and the glass can be held in any light,--a matter of no small consideration when examining anything new, and trying to make out its structure. It is not easily put out of order, and if treated with the most ordinary care, will last for a lifetime.
You can push it under water, and it will magnify as well as in the air; and if you are wandering on the river-side, you can lie down on the bank, dip the upper part of your head into the water, together with the glass, and watch carefully the subaquatic objects without removing them. The water will not hurt the eye in the least, though a non-swimmer may perhaps find a little difficulty in his first attempt. It makes a good burning-glass, should fire be needed, and no other means of procuring a spark be at hand. It can be used so as to show the principle of a camera obscura, and to illustrate the manner in which photographic portraits are taken. It can be made into an admirable dissecting microscope, and needs scarcely any practice in the manipulation. These are some of its advantages, and there are many others which need not be mentioned.
Even if you should be able to procure a good microscope, get a pocket-lens as well, for you will want them both, and we may say that the most practised microscopists, and those who are possessors of the most elaborate instruments, are the very men who are most certain to have a pocket-lens about them, and to use it most frequently. Practise well with the pocket-lens before you meddle with the compound microscope. You will waste no time, but will rather gain by it; for you will be learning the rudiments of a new science, and laying a solid foundation on which to build. Whenever we see a lad take out his pocket-lens in a business-like way, use it skilfully, and put it back with a mechanical facility that tells of constant practice, we know that there is a lad who has learned the chief lesson of a naturalist,--namely, the art of observing. We speak highly of the pocket-lens, because we think highly of it and owe much to it.
One or two practical remarks on the proper handling of the pocket-lens may be of use. Do not always employ the same eye in looking through the lens, but use the eyes alternately. There is always a temptation to employ the same eye, which thus receives a kind of training in vision; but it is a temptation always to be resisted. With some persons the right eye is most in favour, and with others the left; and when the favourite eye gets all the work, it too frequently suffers. Whether you look with the right or the left eye, keep both eyes open.
It is a pitiful sight to see a human face all screwed up into a corner, the lids of the unused eye convulsively squeezed together, and the mouth slanting upwards, as if in sympathy with the eye. Not only does the human face become repulsively mean and portentously ugly by such action, but the sight of the eye is seriously strained, and sometimes impaired for life. At first the beginner will find a little difficulty in restricting his vision to one eye while the other remains open, just as a beginner on the pianoforte feels himself puzzled when he tries to make his right hand go one way and his left hand another; but in either case a little practice and plenty of perseverance are sure to overcome all obstacles, and in a wonderfully short time the difficulty will not only be overcome, but forgotten.
We speak here with some feeling, because, while engaged on a work on the microscope, we were necessarily obliged to work much at night, and inadvertently employed the left eye more than the right; the consequence of which imprudence was that we have been obliged ever since that time to give the left eye perfect rest, as far as artificial vision goes, and, except when looking through a binocular instrument, we have not ventured to use it either to a microscope or telescope. The vision accommodates itself to circumstances with wonderful ease, and the observer learns the curious art of cutting off all communication between the unused eye and the brain; so that, although the objects around may imprint themselves upon the retina, the mind is as totally unconscious of them as if they had no existence.
If possible, always examine an object without removing it, as thereby you see it as it is, without altering any of the conditions with which it is surrounded. Should this not be practicable, take the object to be viewed in the left hand and the lens in the right. Place the wrists of the two hands together, and then you will find that one supports the other, and that the lens can be held in the proper focus without the least difficulty. After you have used the lens for some little time, you will learn to hit upon the right focus almost to a hair’s breadth,--so as to lose no time, a matter of some importance when a living creature is to be examined, especially if it be in motion.
As to the selection of objects, none is necessary. Look at everything; and the uglier and more unpromising it is, let it be the closer examined. We do not merely use our aids to vision for the sake of seeing beautiful things, though the microscopist sees more beauty in a day than others will see in a year. We want to see how the world and its constituent parts are made; and though admiration will not be wanting, yet it does not, or ought not, to hold the first place. Always have a motive for looking at every object, and if you have none, try to make one. One of our friends, known by name at least to most of my readers, struck out, some years ago, a most curious train of thought while looking at an object which is seen daily by thousands of human beings, and will probably soon give the public the benefit of it. We have seen the object hundreds of times, but the ideas which it suggested did not happen to occur to us.
We are now about to suggest a very simple piece of mechanism, by which the pocket-lens can be converted into a microscope that will serve for dissection and many other purposes. The accompanying sketch is taken from an instrument of our own manufacture. It is of very rough make, and by an old Indian officer would be contemptuously termed “cutcha.” Measured, however, by its performance, it is quite as satisfactory as those instruments which are made by professed opticians, and which the same old Indian would class under the honoured title of “pucka.”
Melt three or four pounds of lead in an iron ladle, and make a mould, consisting of a hollow hemisphere of paper or cardboard, through the centre of which an iron rod has been passed. The hollow of the paper should resemble an ordinary saucer. Pour the lead into the saucer, and let it cool. The paper mould will be scorched by the heat and rendered useless, but an outer coating of lead will be cool and hard before the paper is quite destroyed. The rod and leaden stand will now appear as in the illustration. Next take a piece of stout brass wire and a wine-cork; twist the wire round the cork several times; cut off one end close to the cork; sharpen the other, and turn it up as seen in the engraving.
Bore a hole through the cork, just large enough to allow the upright rod to slip through it, and there is the “stand” of your microscope. Now take your pocket-lens, and get an optician to bore a hole through one end of it, just large enough to receive the upturned end of the wire; slip the lens on the wire, and the microscope is complete.
The cork, though grasping the upright stem with tolerable firmness, can be slid up and down so as to insure the correct focus, and can be pushed aside whenever the object has to be viewed with the naked eye and must not be removed from its place. This instrument is a capital one for dissecting purposes, and will answer quite as well as those expensive affairs that are to be purchased in the shops. If, however, our readers would like to possess a real and well-made instrument, he cannot do better than get one of Ross’s Dissecting Microscopes, which are very steady, and, as may be seen, can be adjusted to almost any position. A rack-and-pinion movement for elevating or lowering the sliding pillar would be useful.
If the object be transparent, and requires to be seen by transmitted light, the following plan will answer:--Take a thin piece of wood, cut or punch a round hole out of the middle, and support it on four legs. Wires or wooden pegs fixed in corks will answer the purpose well, and if the corks be glued to the corners of the board, the legs can be inserted or removed at pleasure. The wood of which cigar-boxes are made will answer the purpose very well. Its dimensions should be about three inches in length by two in width. Now buy one of the doll’s looking-glasses that are sold for a penny, and put it under the stand. Lay a flat piece of glass over the hole, place the object upon it, and direct the light through it by means of the mirror below. If such a mirror cannot be obtained, it is easy enough to make one, by mounting a piece of looking-glass in a cork frame, and making it swing on pivots, like the glasses of our dressing-rooms.
The young microscopist must remember that when he is examining any object by transmitted light, he must arrange it as flatly as possible on the glass. In many cases, a still neater manipulation is required,--as, for example, when the petals of flowers are under examination. Thin glass is to be purchased at any optician’s, and if cut in squares, instead of circles, is very much cheaper, and quite as useful for all practical purposes. Lay the petal on the glass plate, place a piece of the thin glass upon it, and press it gently while examining it. If it still remains thick and dull, put a drop of pure water on the petal, and replace the thin glass, when the structure will almost invariably be detected.
Everything depends on the proper management of the object and the arrangement of the light. Some opaque objects can be seen best by direct light, and others by transmitted light. If a leaf be examined, particularly if it be a thick and heavy one, like that of the ivy, the upper and lower membranes must be stripped apart,--a task which is easily performed by tearing a small slit, and then ripping it smartly across. A pair of forceps will be required for this and other delicate work, and may be obtained at a cheap rate. Care must be taken to keep the points exactly even, and if at any time one of them appears to be shorter than the other, they should be rubbed on a hone until they are brought perfectly level.
These should be made of steel; but the young microscopist will find that a second pair made of brass, and much rougher in finish, are invaluable aids as he takes his walks into the country. By their aid he can pick up minute objects, draw insects out of crevices without damaging them, and pluck the tiniest flowers without harming their petals. They can be carried in the waistcoat pocket, and the cost is sixpence. Any lad who knows how to handle solder can make a pair for himself in a few minutes.
A penknife with one blade kept scrupulously sharp is essential, and we have found an old lancet of the greatest service. Lancets have gone so much out of fashion, that the second-hand instrument shops abound with them. We did not allow our own lancet to be shut up, but removed the blade from the tortoise-shell handle, and fixed it upon a wooden handle, about four inches in length, so that it looked very clumsy, but was extremely useful.
Two pairs of scissors are needful,--one very fine, and the other moderately strong. Both pairs, however, must have very short blades and very long handles, and the scissors such as ladies use are of very little use, the short handles causing the fingers of the right hand to shade the object. As to the fine pair, it is hardly possible to have the handles too long or the blades too short; for if the points can be separated a quarter of an inch, nothing more is needed. If a pair of bent scissors can also be obtained, they are extremely pleasant to work with, and save much trouble.
For arranging the objects under the microscope, there are no instruments equal to those which are here engraved. They are nothing more than ordinary needles stuck into the handles of camel’s-hair brushes. The uppermost is made of the largest-sized darning-needle, and is useful for making little holes, and similar purposes. The two next instruments are the most generally useful, and several of each should be always at hand. Nos. 4 and 5 are for special purposes; the former for holding tissues aside, and the latter for lifting them up. The needles must not be longer than those in the illustration, as they would otherwise be too springy, and apt to tear the object instead of pulling or pushing it.
The bending is readily done in the flame of a spirit-lamp, or even of a common candle; but in the latter case the needle is always covered with soot, which must be wiped off before its shape can be seen. The elasticity of the needles is lost by the operation, but is easily restored by heating them red-hot, and plunging them immediately into cold water. The end of the handle should be wrapped with thread, in order to prevent it from splitting.
Pill-boxes of various sizes are of very great service to the microscopist. We always have them arranged in “nests,” i. e. six or seven inside each other, so that space is greatly economized, as long as they are not in absolute use. All delicate objects should be placed in separate boxes, and the predaceous insects must be treated in the same manner, or they will certainly destroy one another, or, at all events, inflict such injuries as will make them useless for microscopic purposes.
When the insects are to be killed on the spot, we employ another and a very simple plan.
We take one of the old-fashioned wooden lucifer-match boxes, bore a hole in the lid, and push through the hole a swan-quill or the barrel of one of the swan-quill steel pens. A glass tube is still better, but is too fragile. Beeswax is tightly worked into the junction of the tube with the wood, so as to make it as nearly air-tight as possible. A cork stopper is then cut to fit the tube. The accompanying illustration will show the box completed. When this is finished, we take the smallest-sized pill-box, bore a number of holes in it with a red-hot needle, place a little piece of solid ammonia within it, and inclose it in the lucifer-box. Its effects are almost instantaneous; for scarcely has the insect touched the bottom of the box before it is helpless, and in a very few moments it is quite dead, so powerful is ammonia towards insects. The reader will of course understand that the pill-boxes must never have been used for pills, and that the match-box must be carefully cleaned before employing it in the microscopic service. Moreover, any boxes that have been used for lepidopterous insects become useless, inasmuch as the scales always fall from the wings, and cling to the sides of the box, so as to mix with succeeding objects, and very much puzzle the observer.
Aquatic and marine objects require bottles, and, as a general rule, these bottles ought always to have wide mouths. Indeed, if there be no shoulder at all, their purpose will be better served, as a small object is very apt to be caught under the shoulder, and to give much trouble before it can be removed without injury. Wide and short test-tubes answer admirably for collecting; and it will always be advisable to have a few small test-tubes ready fitted with corks, for the purpose of isolating those specimens which might receive or cause injury by being mixed with others.
To remove minute objects from one vessel into another is a very easy process. Take a glass tube, mark off a portion about eight inches in length, cut a little notch with a file, and bend it smartly, when it will break neatly across, without leaving points or having the regularity of its ends injured by gaps. Turn each end round and round in the flame of the spirit-lamp, and you have an ordinary “pipette.” The object of placing the ends of the tube in the flame is to render the edges quite smooth and rounded.
Now mark off the same length of tube, and place the marked portion in the flame, taking care to warm it well first, lest the sudden heat should crack the glass. Keep it continually turning between the fingers, and when it is quite soft, and of a fine red heat, draw the hands smartly apart, and you will produce a couple of tubes tapering to very fine points. Break off the tapering portions at any convenient point, round the edges as before, and you will then have pipettes suitable for small objects. As there are many specimens, especially the smaller animalculæ, which have a habit of retiring into the remotest corner, it is necessary to bend another pipette, so as to follow them. For our own part, we prefer the pipette to be bent nearly to a right angle.
The mode of using these simple instruments is as follows:--Place the forefinger or thumb firmly on the large end, and push the point under water. When the opening is close to the sought-for object, lift the finger suddenly, and admit the air into the tube. The water will immediately rush in at the lower end, and if the orifice has been properly directed, will carry the object into the tube. The finger is again applied to the mouth of the tube, and the object can be then carried off.
As with the pocket-lens almost every object is to be viewed by means of direct light, the young observer will find himself much aided by a suitable background. Any small object, such as a minute insect, a seed, or a hair, becomes very indistinct if held up against the light, or even when viewed against a broken background of trees, houses, or herbage. The simplest plan of securing a proper background is to take a disc of ivory, bone, or even of white cardboard, and to blacken one side of it. The black paint which is used for this purpose must be without gloss, and have what is called a “dead” surface. Ink answers very well for the purpose, and so does ivory-black; but Indian ink is too glossy to be serviceable.
To procure specimens from the water is a matter of some difficulty if managed badly, but easy enough when the collector knows his business. It is of course needful to attach the collecting vessel to the end of a rod, and to plunge it into the spots which look most favourable. Now even so simple a matter as this requires some little care, if the young microscopist really wishes to obtain the best specimens. A common walking-stick will answer most purposes; but the most efficient rod for the purpose is one of the common walking-stick fishing-rods without the top joint, as it can be carried without attracting attention, and can be lengthened at will by adding the different joints.
Many methods have been proposed by which the vessel is to be attached to the rod; but that which I am about to describe is certainly the simplest and most effective that I have tried. Get a piece of gutta-percha tubing, just large enough to be slipped on the end of the rod or stick; mark off an inch or so, and cut the tube nearly through, as at a in Fig. 1. Now cut it away longitudinally, so that a long tongue of gutta-percha is left, as at b, and the instrument is completed.
Its application is as simple as its structure. Bend the tongue over, so as to form a loop, and push the end through the short tube. Slip the neck of the bottle into the loop, and draw the tongue until it is tolerably tight. Push the end of the stick into the tube, taking care to hold the tongue firmly in its place, and the vessel will then be fastened at right angles to the stick.
The whole arrangement can be seen in Fig. 2, where a represents the gutta-percha tube, b the tongue, c the stick, and d the vessel.
The method of collecting by means of this instrument is as follows:--Immerse the vessel in the water, with the mouth downwards, so that no water may enter. Push it gently towards the spot which is to be investigated, move it about a little, so as to cause a disturbance, and then turn the vessel with its mouth upwards. Water will instantly rush in, carrying with it the objects which are to be examined. The contents of the vessel may then be transferred to the large bottle, and another dip made. Confervoid growths, especially those which accumulate in a kind of scum on the surface, should be obtained very quietly, without previous disturbance of the water.
After the pond or stream or ditch has been well searched, the bottle should be roughly examined, by means of a pocket-lens, and the contents sorted into the smaller tubes, as has already been mentioned. This precaution is especially needful when any of the minute crustacea called Entomostraca are captured, as they are most voracious beings, and will make sad havoc among other specimens, unless they are placed in separate bottles. They are mostly large enough to be detected with the naked eye, and look something like little fleas, as they move along.
As the Entomostraca cast their shells repeatedly during their lives, some species performing this operation every two days, a beautiful series of objects can be obtained by gathering the cast shells, and preparing them for the microscope, according to the directions that will be found in the following pages. These shells are peculiarly valuable, as they retain the chief external characteristics of the creature to which they belonged, the limbs, plumes, and even the delicate bristles being preserved entire. It is in the power of the microscopist to retard or hasten the change of shell, heat and light aiding development, and cold and darkness retarding it. The remarkable “ephippium,” or saddle, which is found on the backs of the Daphnia, the Moina, and other Entomostraca, and which is used as a receptacle for eggs, should be searched for and preserved.
A very thin and very flat bottle is a most useful assistance in detecting the character of any unknown object, especially if it be living. Such a bottle may easily be made by heating one of the small test-tubes in the spirit-lamp until it is of a glowing red heat, and then pressing the sides together. Some little neatness is required in this process, as an unskilful operator is apt to press the sides unequally, and to leave a bulging projection at the end.
Should a higher power be required than is furnished by the pocket-lens, a “Coddington” lens is the very best that can be obtained. In general shape it resembles the well-known “Stanhope” lens; but the latter is so very inferior an article, that it ought never to be purchased. The two glasses can easily be distinguished by the shape of the ends; those of the Coddington being alike, while in the Stanhope one is much more convex than the other.
At first the young observer generally finds some difficulty in arranging this lens, so as to hit off the focus exactly; but if he adopts the following plan, he will soon handle a Coddington as easily as an ordinary pocket-lens. The object should be held in the left hand and the glass in the right. Let the wrists be placed firmly against each other, and the lens brought as close as possible to the object, without quite touching it. Now bring the eye to the lens, taking care not to disturb the arrangement, and then gradually draw the object away from the lens. The moment that the proper focus is obtained the object will be seen with beautiful clearness, and by drawing the object from the lens, instead of approaching the lens to the object, there is no danger of injuring the one or the other by contact.
The great advantages of the Coddington are the exceeding clearness with which it shows the object, the perfect definition of every line, its achromatic character, and its freedom from colours, and the flatness of the “field;” so that the circumference is defined as perfectly as the centre. It can now be obtained very cheaply at any of our microscopical opticians, and should always be mounted on a tolerably long handle.
THE COMPOUND MICROSCOPE.
We have already described the simpler forms of magnifying instruments, together with the best method of using them. We now purpose to describe the more complicated instrument called the compound microscope, and hints will be given as to the best method of making preparations for it.
The great distinction between the simple and compound microscope is, that whereas the former instrument magnifies the object, the latter magnifies the magnified image of the object. In the least elaborate form of this instrument there are two glasses, one at each end of a tube, the small glass magnifying the object, and being therefore called the “object glass,” while the other, which magnifies the image of the object, is placed next to the eye, and is therefore termed the “eye-glass.” In practice, however, this arrangement is found to be so extremely defective, that the instrument was quite useless, except as an experimental toy; for the two enemies of the optician, chromatic and spherical aberration, prevailed so exceedingly, that every object appeared as if surrounded with prismatic colours, and every line was blurred and indistinct.
In this uncertain state the compound microscope remained for many years, its superb capabilities being scarcely recognised. The chief fault was thought to be in the material of which the object-glass was made, and for a long series of years all experiments were conducted with a view to an improvement in this respect. When, however, the diamond had been employed as an object-glass, and had failed equally with those of less costly material, attention was directed to the right point--namely, the arrangement of the different glasses,--and at length opticians succeeded in obtaining a pitch of excellence which can be almost termed perfection. It would be impossible to describe the method which is employed for this purpose, and it must suffice to say that the principle is that of playing off one defect against another, and so making them mutually correct their errors.
The magnifying powers of the compound microscope can be very great, and it is therefore necessary that extreme care should be taken in its manipulation. It will be possible for a clumsy person to do more damage to a good instrument in three minutes than can be repaired in as many weeks.
Before proceeding to the management of the microscope and the construction of the “slides,” we will briefly describe one or two chief forms of the compound microscope.
The accompanying illustration represents the simplest form of the compound microscope as at present made. It consists of a stand and a sliding tube, in which are set the glasses which magnify the object and its image. At the top is the tube, which is capable of being slid up and down in the shoulder of the stand, so as to obtain the proper focus. Above is seen the eye-glass; and the object-glass is shown at the bottom of the tube. Below the object-glass is the “stage” on which the object to be magnified is laid; and lowest of all is a mirror, which serves to reflect the light upwards through the object, and which can be turned by means of the knobs at the sides. The object-glass is composed of two pieces, which can readily be separated. If both are used, sufficient magnifying power is gained to show the scales on a butterfly’s wing and similar minute objects; while, if one is removed, the object is not magnified to so great an extent, but a larger portion can be seen, and the definition is clearer. The cost of this instrument, together with a few accessories, is half-a-guinea.
There is another microscope constructed on the same principle, which is a very superior instrument, though it does not at first sight present any remarkable difference. It possesses, however, four times the magnifying power of that which has just been mentioned. Instead of two magnifiers, there are four, and several subsidiary articles are sent with it,--such as a condenser, a live box, an aquatic box, and half a dozen slides ready prepared. This instrument costs one sovereign.
But if the reader can by any possibility afford it, let us advise him in the strongest terms to devote three guineas to the purpose, and get a really good instrument. For this small sum a microscope may now be obtained which could not have been purchased for twenty times three guineas only a few years ago. One of these beautiful instruments is seen in the accompanying illustration; in which may be seen the tube, with its eye-piece and object-glass, and the stand, containing the stage and the mirror. The arrangement, however, is very different; for the focus is not obtained by sliding the tube up and down, but by turning the large milled heads which we see on a level with the stage, and which raise or depress the tube by means of a rack and pinion. As an extremely high power can be used with this instrument, a still finer adjustment is required, so as to obtain a very accurate focus. This is seen on the front of the tube. The reader will notice that the microscope can be inclined backwards, for it is so made that it can be set to any angle which may best suit the observer. The value of this arrangement is very great, as it permits the observer to sit at his ease in a chair, without being forced to crane his neck over the microscope, and look perpendicularly down. Another advantage attending this arrangement is that the secretions which lubricate the eye do not interrupt the vision, as is apt to be the case when looking directly downwards.
The mirror, too, can be turned in any direction, and its distance from the stage lessened or increased by means of a draw-tube. Three different powers are supplied with this microscope, together with a live-box, dissecting and stage forceps, &c.; and the whole is made so as to admit of additional apparatus. The microscope fits into a neat square box, in which is plenty of room for various articles which will presently be described. These three microscopes can be obtained from Messrs. Baker, 244, High Holborn; and we mention them, not because we wish to make any invidious distinctions between the many excellent opticians who now make microscopes, but because we happen to have used Messrs. Baker’s instruments for some years, and can bear practical testimony to their performance.
Another three-guinea microscope ought, however, to be mentioned. It is the Society of Arts microscope, which is made by Messrs. Field, opticians, of Birmingham. In form it closely resembles the instrument which has just been mentioned, but differs in some of the details, as it possesses a “diaphragm-plate” under the stage for regulating the admission of light, and, instead of three object-glasses and one eye-piece, has two object-glasses and two eye-pieces. Dr. Carpenter mentions that, up to 1861, no less than eighteen hundred of these microscopes had been sold. To this instrument the medal of the Society of Arts was awarded.
Either of these microscopes affords all that an ordinary observer is likely to need; and if he adds a few articles of supplementary apparatus, he will find himself possessed of a microscope that will serve all purposes except scientific controversy.
Presuming that the reader has supplied himself with one or other of the compound microscopes, we will proceed to show the method of using them.
The manipulation of a compound microscope is not so easy as it looks. The possessor of a really good instrument may fail hopelessly in his attempts to see a single object. Now, there are three essential points which a microscopist must attend to,--namely, the correct focus, the proper light, and the preparation of the object. Of these the focus is of course the most important, and can be best obtained as follows:--
Lay the object on the stage of the microscope, so as to get its centre exactly under the centre of the object-glass, and illuminate it as you best can. Put on the lowest power, and, without looking through the tube, lower the object-glass until it nearly touches the object. Now look through the tube, and raise the object-glass gradually from the object, until the right focus is obtained. The reason for taking these precautions is, that if you look through the tube and lower it upon the object, you will in all probability push the glass against the object, and damage either the one or the other. When you have thus learned the focus of the lowest power, add another, and repeat the process; and so on until you have made out the focus of each object-glass. If you have more than one eye-piece, try them both with each object-glass.
The proper light is our next point, and upon it rests the chief beauty of the effect. The light which will suit one object will not suit another, and even the same object should be examined under every variety of light. Some objects are best shown when the light is thrown upon them from above, and others when it is thrown through them from below. Again, the direction of the light is of vast importance; for it will easily be seen that an oblique light will exhibit minute projections by throwing a shadow on one side and brilliancy on the other, while a vertical illumination would fail to show them. On the same principle, one object will be shown better with the light in front, and another when it is on one side.
One of the most effective means of attaining this object is by using the “bull’s-eye condenser,” which is sometimes fixed to the stage, but is usually detached, as represented in the illustration. As the upright stem is telescopic, the glass can be raised to a considerable height, while the joint and sliding-rod permit the lens to be applied at any angle which promises the most brilliant light.
As for the kind of light that is employed, there is nothing which equals that of a white cloud; but as such clouds are rare, and are at the best extremely transient, and can only be seen by day, various artificial methods of illumination have been invented. Novices generally think that when the sky is bright and blue they will be very successful in their illumination, and feel grievously disappointed at finding that they obtained much more light from the clouds, whose disappearance they had anxiously been watching. Finding that the blue sky gives scarcely any light at all, they rush to the other extreme, turn the mirror towards the sun, and pour such a blaze of light upon the object, that the eye is blinded by the scintillating refulgence, and the object is often injured, because the mirror is capable of reflecting heat as well as light.
In the daytime there is nothing better than the “white-cloud illuminator,” which is made easily enough by means of plaster of Paris. A sheet of thin white paper fastened against a window-pane is also useful; and the simple plan of dabbing the glass with putty will have a beneficial effect in softening the light, when the window has a southern aspect. In default of these conveniences, it will be often sufficient to fix a piece of white letter-paper over the mirror, or even to dull its surface with wax. At all events, he who aspires to be a true microscopist must be ready with expedients, and if he finds himself in a difficulty, he must summarily invent a method of obviating it.
At night a lamp is necessary; candles are useless, because they have two faults--they flicker, and they become lower as they burn. The latter defect can be cured by using a candle-lamp, but no arrangement will cure the flame of flickering; it is peculiarly trying to the eyes, and destructive of accurate definition. An ordinary moderator lamp answers pretty well, and a small one is even better for the microscopist than one of large dimensions. The chief drawback to the moderator lamp is, that the flame cannot be elevated or lowered, so that the only way to procure a light at a higher elevation, is to stand the lamp on a block of wood or a book. Small lamps are, however, made expressly for the microscope, and, if possible, should be procured, and used for no other purpose, and intrusted to no other hands.
If you want a really brilliant, clear, white light, you must trim the lamp yourself. A small piece of pale blue or neutral-tint glass, interposed between the lamp and the microscope, has a wonderful effect in diminishing the yellow hue which belongs more or less to all artificial lights which are produced by the combustion of oil or fat. We have no doubt but that in a few years we shall be rid of the clumsy and dirty machines that we call lamps, and have substituted for them the pure brilliancy of the electric light.
Whatever lamp you use, a shade is absolutely necessary, in order to defend the eyes. Let me here warn my young readers, that they cannot be too careful of their eyes. In the exuberance of youthful strength and health we are too apt to treat our eyes as unceremoniously as our digestion, and in later years we awake to unavailing repentance.
Many shades can be purchased; but it is far better to make your own after the shape here exhibited. They are not pretty to look at, but they save the eyes better than any other form, and whether for reading, writing, or microscopic work, you should use no other. The peculiar merit of them consists in the fact that the light is thrown on the spot where it is wanted, and is cut off from everything except that spot.
Another point which calls for extreme attention is the perfect cleanliness of the glasses. It is astonishing how a tiny dust-mote, or the least condensation of damp, will diminish the powers of the microscope, and how often the instrument is blamed for indistinctness, when the real fault lies in the carelessness of the operator. Even when the greatest care is taken, dust is sure to settle on the glasses, especially on the eye-piece, and before using the microscope the glasses ought to be carefully examined. Never wipe them with an ordinary handkerchief, but get a piece of new wash-leather; beat it well until no dust issues from it, and then put it into a box, with a tightly-fitting cover. Use this, and nothing else, for cleaning the glasses, and you will avoid those horrid scratches with which the eye-glass and object-glass of careless operators are always disfigured.
Moisture is very apt to condense on the glasses and to ruin their clearness. If the microscope be brought from a cold into a warm room, the glasses will be instantly covered with moisture, just as the outside of a tumbler of cold water is always covered with fine dew when brought into a warm room. The microscope should therefore be kept at least an hour in the room wherein it is to be used, so that the instrument and the atmosphere may be of the same temperature. You should make the microscope a trifle warmer than the surrounding atmosphere, and so avoid all danger of condensation. When changing the object-glass or eye-piece, always keep the hand as far away from the glass as possible, and manipulate with the tip of the forefinger and thumb. The human skin always gives out so much exhalation, that even when the hand is cold the glasses will be dimmed; and it is a peculiarity of such moisture, that it adheres to the glasses with great pertinacity, and does not evaporate like the dew which is condensed from the atmosphere.
In order to insure perfect success in this important particular, the young microscopist will do well to get the optician from whom he purchased his instrument to explain its construction, and to give him a lesson or two in the art of taking it to pieces and putting it together again; for unless each glass can be separately cleaned, no one can be quite sure that the instrument will perform as it ought to do. The best method of ascertaining whether it is quite clean is to throw the light upwards by means of the mirror, and then to turn the eye-piece slowly round. If any dust or moisture has collected either upon the eye-glass or the “field-glass,” which forms the second lens of the eye-piece, it will be immediately detected. Turning the object-glass will in a similar manner detect impurities upon its surface.
We will now proceed to the manner in which objects are examined. Suppose, for example, that we take a buttercup-leaf, because it can be found at almost any time of the year. Place a piece of glass on the stage, lay the leaf on it, put on the lowest power, set the focus, and then look at the leaf. You will probably be disappointed, and see nothing but a confused mass of undulating dark green, like a green carpet thrown carelessly on the ground, and seen in the dim twilight.
Two points are now needed; the first being to get the leaf flat, so as to avoid the undulation, and the second being to throw a proper light upon it.
Take out the leaf, and, instead of laying it entire under the microscope, select the flattest part, and cut it out with scissors. A piece the size of a silver penny will be amply large enough. Lay this piece on the glass, get the focus afresh, and then look through the microscope. The leaf will now appear much more regular, and will be seen as a rough surface, mottled with white and traversed by pink and green ridges, which are the large and small nervures. By means of a mirror or the condenser throw a brighter light upon it, and it will be seen to be covered with a slight roughness, the nature of which cannot be clearly ascertained; then add the next highest power, and try if the structure of that roughness can be made out. Curiously enough, although the magnifying power has been more than doubled, the roughness has much the same appearance as before; so that we must try another plan, and look at the leaf edgeways.
Take the piece of leaf in the stage-forceps, but do not touch it with your hand; fix the forceps on the stage and turn the leaf so that it presents its edge to the object glass. Get your focus, and you will now see the cut edge of the leaf, and will at once distinguish its structure. On either side may be seen the upper and lower cuticle, and in the centre the soft green substance, or “parenchyma,” as it is called. From the cuticle project a number of short hairs, and when the focus is accurately obtained, the cause of the roughness will be seen in a vast number of minute projections, which are, in fact, identical in structure with the hairs, though not so well developed. The under-cuticle of the leaf is much more interesting than the upper.
Now change the illumination, and, instead of throwing the light upon the object from above, turn the mirror so as to direct it through the object from below. No apparent result will follow, because the leaf is so thick and opaque that the light cannot pass through it. Hold the leaf horizontally, and, by means of the stage-forceps, rip it smartly across, and if you do this rightly, you will find that the two cuticles are partly separated, so as to allow either to be examined separately. At first the leaf will most probably be torn along one of the large nervures, so that the cuticles are not perfectly separated. Never mind failure, but try again; and you are sure, after a few efforts, to hit upon the right method of tearing the leaf.
One of the most useful capabilities of the “live-box” is now shown. As may be seen by the figure and section, it consists of an inner tube with a thick glass, and an outer tube with a thin glass. The outer tube can be taken off, water or any other substance laid on the thick glass, and then the outer tube or cover is slid down upon it until the object is pressed flatly between the two glasses. When you have succeeded in getting a convenient slip of the leaf, lay it on the thick glass of the inner tube, and put a drop of water on it. Put on the cover, and push it down until the piece of leaf is pressed flat, without being squeezed. Now look through the microscope, and you will see a beautiful sight, showing how much there is in a despised leaf, which we daily tread under foot.
The cells of which the cuticle is chiefly composed are seen in many a waving outline, while at their points of junction are placed the remarkable contrivances called “stomata,” or mouths, which are the apertures through which the atmosphere is enabled to penetrate into the interior of the leaf. The two semilunar cells at the sides of the opening may be considered as lips, which open and close according as the plant needs the air or not. The numerous dots which are seen upon the leaf are of a vivid green colour, and it is to their presence that the leaf owes its hue.
We have given these details because they are applicable to the examination of all leaves and petals, and show the young observer the method which is to be adopted when looking for the first time at a strange object.
If the microscopist should follow up his work properly, and make sketches of every object which he places under the microscope, he cannot do better than use the camera-lucida, a neat little instrument, which is fitted into the eye-piece of the microscope. Dr. Beale’s neutral glass is as efficacious in careful hands, and only costs a fourth of the sum. This instrument cannot be applied to the ten and twenty shilling microscopes, as it requires that the tube should be perfectly horizontal. The method of using it is simple enough.
After fixing the object and getting the right focus, set the instrument horizontally, and arrange the light so that the object is well illuminated, and its lines quite clear and well defined. Now remove the cap of the eye-piece, and fix the camera-lucida in its stead. Lay a drawing-pad on the table under the camera-lucida, look through the square opening (or, if you use Mr. Beale’s glass, look through the neutral glass), and you will see the object apparently projected on the paper. We say apparently, because in reality the image is not thrown on the paper at all, but on the camera, and the eye refers it to the paper, as being the nearest object. In fact, the principle on which this camera-lucida is arranged is exactly that of the Polytechnic ghost, which appears to be in one place, whereas it is in another.
Now take a pencil, cut it to a very fine point, and trace the outline of the object on the paper. At first you will think this to be an impracticable task, for the point of the pencil will totally vanish. Soon, however, the eye will so adjust itself as to see the pencil and the object perfectly well, and by a little practice the observer will be able to sketch every object as rapidly and firmly as if he were copying a drawing, by means of tracing-paper. The neutral glass is perhaps to be preferred to the camera-lucida, as it is learned more easily, and gives less trouble than that instrument. Its cost is five shillings.
After you have practised yourself well in the handling of the microscope, your ambition will take another step, and lead you to the preparation of permanent objects. In order to set yourself up with the needful apparatus, you will have to disburse about five shillings. A small spirit-lamp will cost eighteenpence, and a small bottle of Canada balsam, another of asphalte varnish, and another of Dean’s gelatine, will make about eighteenpence or two shillings more. A few pence will purchase a sheet or two of ornamental paper, and a few more a flat plate of brass or copper, about five inches by three. The rest of the five shillings may be expended in “slides” and thin glass, cut square.
Slides are merely slips of glass, three inches in length by one in width, and the thin glass is used for laying upon the objects and defending them from dust. We advise the square glass, because it scarcely costs one quarter as much as the round glass, and is equally effective when properly managed. There are several methods of “putting up” preparations--namely, dry, in Canada balsam, in gelatine, and in cells. We will take them in their order.
The simplest plan is, of course, the “dry” mode. Suppose that you want to preserve a tiny piece of down, or the scales from a butterfly’s wing. First wash all the slides and glasses well, by dipping them into a strong solution of soda, and then into hot water, in order to get rid of grease, taking care never to touch them with the hand, but to take them out of the water with the forceps. This can be done at any time, and the glasses carefully wrapped up and placed in a box ready for use.
You now select one of the slides, and lay the object exactly in its centre. If very minute objects are used, they must be examined in order to see whether they are properly disposed. The next process is, to take one of the thin glasses with the microscope, and lay it very carefully over the object. Then cut a piece of ornamental paper, about two inches long and seven-eighths of an inch in width; cut or punch a circular piece out of its centre, damp it well, and cover the wrong side slightly, but completely, with paste. Lay it on the slide, so that the centre of the hole shall coincide with that of the object, work it down neatly with the fingers, and it will hold the square piece of thin glass, which is technically called the “cover,” in its place. Watch it occasionally as it dries, and be ready to press down any part of the paper that may start up. Write, with ink, the name of the object on the end of the slide.
When you have made a dozen or two of these preparations, it will be time to letter and index them. On each slide paste a slip of white paper, and on the paper write a brief notice of the object, thus--
+---------------+ | SCALES. | | | | D. HEAD MOTH. | +---------------+
Then scratch with a bit of flint, or with a writing-diamond, if you have one, a number on the end of the slide, and have a note-book with a corresponding number opposite to which you enter the description at a fuller length, thus:--
18--Scales of Death’s Head Moth (Acherontia Atropos), from centre of under-surface of right fore wing. Dry. June 4, 1864. +
The cross signifies that you prepared the object yourself, and the reason for adding the date is, that in after years you will have a valuable guide as to the durability of your preparations. If the specimen has been purchased or presented, always add the name of the seller or donor, as well as the date. These precautions may seem to be needlessly minute, but we have so often seen whole sets of valuable preparations rendered useless for want of ticketing, that we cannot too strongly impress on our readers the necessity for the note-book as well as the label, the one acting as a check upon the other. When the label has been affixed, and the details transferred to the note-book, the ink may be washed off the end of the slide.
There is another convenient method of putting up the elytra of beetles, parts of various insects, mosses, minute shells, and similar objects. Take a common pill-box of the smallest size, and cut a little cylinder of cork, that will nearly, but not quite, equal the height of the box, and fasten one end to the bottom of the box with glue. Now blacken the interior of the box and the cork cylinder. Put a little drop of Canada balsam, Arabian cement, or gum Arabic on the top of the cylinder; put the object on it, press it into its place, and, when the cement is hard, the preparation is complete. The cover of the box serves to keep the object from dust.
Now we come to the Canada balsam, a substance which produces beautiful effects when rightly handled, but is most aggravating to the learner, causing alternate irascibility and depression of spirits. Many objects, such as the antennæ and feet of insects, will not show their full beauty unless they are mounted in Canada balsam. The method of doing so is as follows:--A week or two beforehand put the objects into ether or spirits of turpentine, and allow them to remain there until wanted. Pile up some old books, or take a couple of convenient wooden blocks; lay your brass plate upon them; light the spirit-lamp, and put it under the plate so as to heat it. Lay two or three slides on the plate, and all then can be heated at the same time.
Warm the bottle of Canada balsam, and with a glass rod take out a very little drop, and put it exactly in the middle of the slide. In order to insure this point, I always put a dot of ink on the wrong side of the slide. Stir it about with one of the needles mentioned on page 428, and if any bubbles rise, break them. When the balsam is quite soft and liquid, take one of the objects out of the bottle and put it into the balsam, exactly over the black dot. Now add a little more balsam, so as to cover it, and let it lie for a few moments. Take one of the glass covers, put a very little balsam on its centre, and lay it neatly over the object, pressing it down gradually and equally. Unless this be done, the object will not remain in the centre, but will shoot out on one side, and the whole operation must be begun de novo. Remove it from the hot plate and lay it on a cool surface, still continuing the pressure until the balsam has begun to harden. Lay a little leaden weight--a pistol-bullet partly flattened is excellent for the purpose--and on the cover write the name of the object, as already mentioned, and then proceed to prepare another slide.
Twenty such slides may be prepared in the course of a morning, and when they are finished they should be laid carefully in a cold place, where they will be free from dust. In a week or so the balsam will be quite hard, and then the slide may be completed. Take an old knife, which should be kept for this special purpose; heat the blade in the spirit-lamp, and then run it along the edges of the slide, so as to take off the superfluous balsam which has escaped from beneath the cover. This must be done very quickly, or the balsam inside the cover will be heated by the knife, and the preparation spoiled. When this is done, cut the ornamental paper, as already described, number and label the slide, wash off the ink, and then the preparation is complete. Some objects are very troublesome to prepare, and require to be soaked in turpentine and boiled repeatedly in the balsam before they are completely penetrated with it.
Objects which are put up in Deane’s gelatine are managed after a similar fashion, save that the gelatine is to be heated by placing the bottle in hot water, and that the turpentine is not needed. Vegetable structures show beautifully when thus prepared. To remove the superfluous gelatine use a wet and not a hot knife.
Cells are very difficult to manage, and the novice had better not attempt to make them, but is hereby advised to purchase them ready made. Suppose that the young microscopist has dissected the digestive organs of a bee, and wishes to preserve it in spirit; his best plan will be to use a cell for the purpose. Let him buy a cell of sufficient depth, float the preparation into it, fill it up with spirit, put the cover loosely on, and leave it for a week, occasionally raising the cover and stirring the preparation with a needle, in order to get rid of any air-bubbles that may have been entangled in the tissues.
Then let him wipe the edges of the cell very dry, put on a slight layer of gold-size or asphalte varnish--the former is preferable--fill up the cell a “bumper,” and lay the cover very gently upon it, beginning at one end and gently lowering it. With blotting-paper the liquid that escapes must be removed, the edges dried afresh, a flattened bullet placed on the cover, and with a very small camel’s-hair brush the slightest possible coating of size painted round the edge of the cell. When it has hardened another may be given, and so on, until a thick hard wall of size has been built up round the edges and made the cover completely air-tight.
We presume that the reader does not intend to use his microscope merely as a toy, but that he desires to gain some insight into the works of Nature, and is therefore willing to set to work in a systematic manner.
It is now known that both animal and vegetable structures are built up by means of certain minute particles, technically called CELLS, and that in every part of a plant or of an animal can be recognised the constituents of which it is formed. We will, therefore, begin with the vegetables.
Some of the lowest plants, such as the minute algæ that inhabit the water, afford excellent examples of the simple vegetable cell; but as these plants are not readily procured by a beginner, we will select some familiar object wherein the cells may be found. If any soft and pulpy fruit be taken when it is quite ripe, and submitted to the microscope, the vegetable cell will be seen in a tolerably perfect form. The three rounded objects shown in the accompanying illustration are cells from the strawberry, specimens of which can easily be seen, if a very thin slice be cut with a razor or lancet, the latter being the preferable instrument. Be careful to dip the blade in water before cutting the fruit, and to float the slice from the blade to the glass slide by placing them both under water. Unless this precaution be taken, the section will not be flat, but will be crumpled up, and the cells will not be properly seen.
Within each of these cells may be seen a small rounded object, which is technically called the “nucleus;” and in some cases a smaller nucleus, called the “nucleolus,” may be observed within the nucleus itself. The increase of cells mostly takes place by a process of division. A line passes across the nucleus, which presently separates into two distinct parts, each of which recedes from the other, causing the cell to enlarge and alter its shape. Presently a line is seen across the cell itself, and in due time the cell is also divided into two parts, each having its own nucleus.
In the present instance the cell is totally spherical, because the fruit from which it was taken was soft, and allowed the constituent cells to expand. When, however, the vegetable substance becomes hard, the cells are pressed closely together, and their shapes are very much altered. Sometimes, when the cells are of nearly the same size, and the pressure is equal on every side, the cells form regular twelve-sided figures, called “dodecahedra,” which, when that occurs, show a six-sided outline. A very thin slice of raw potato will show the twelve-sided cells beautifully, and has the further advantage of exhibiting the starch globules with which the cells are filled. Here is a figure of a potato cell, which presents a six-sided outline, just like that of a bee’s waxen dwelling, and which is crowded with the beautiful globules of starch. If the reader likes to make a few dozen balls of clay, and to squeeze them together in a mass, he will find that the central balls will have lost their globular shape, and assumed a more or less regular twelve-sided form, very much like that of the potato cells.
Sometimes the cells run out longitudinally into cylinders, and attain the really enormous length of three inches; sometimes they become flattened, as the skin or epidermis of many plants; and oftentimes they push out their sides into arms or rays, like stars, and form the tissue which is technically called “stellate.” Here is a specimen of stellate tissue taken from the pith of the common rush, wherein the rays are seen to be very regular: generally, however, the rays are extremely irregular, and require some little practice to detect them. Stellate tissue may be seen in the white portion of orange-peel, in the thick fleshy substance of many aquatic plants, in certain leaf-stalks, and in many similar objects.
We will now see how the soft cells which form the pulpy fruit of the strawberry can be changed into the hard timber of the oak or iron-wood tree.
Wherever a cell is destined to form part of a permanent tissue, it is strengthened by receiving certain additions to its walls. These additions are technically known as “secondary deposit,” and are made in various ways. Sometimes they extend in a thin layer over the whole cell-wall, leaving a number of little holes, which are called “pits,” and earning the name of “pitted structures.” Very frequently the secondary deposit is arranged in a series of rings, an example of which is given in the accompanying illustration. This object is taken from the mistletoe. Good examples of the ringed structures may be seen in the anthers of many plants, and in the leaf-stem of the common rhubarb, an example of which is shown in the next illustration. Another very common form of secondary deposit is the spiral, which is generally used where strength and elasticity are united. Two examples of the spiral form are given in the illustration; the first taken from the lily, and the second from the “rhizome,” or subterranean stem of the water-lily.
Another beautiful form of secondary deposit is seen in the fern root. If the root be cut longitudinally, and the dark hard fibre dissolved carefully out with nitric acid, the deposit will seem to have assumed the shape of a winding staircase, and is then called “scalariform,” or ladder-shaped. Similar structures may be found in asparagus.
The reader will see that the hardness of the structure depends entirely on the amount of secondary deposit, and we accordingly find that when the wood is hard and fit to be worked with tools the cells are almost wholly filled with the secondary deposit. In this state they are called “wood-cells.” Examples of these cells may be seen in the accompanying illustration. In the first example, which is taken from the elder-tree, four cells are shown in order to display the manner in which their pointed ends are arranged. (The reader must remember that in all wood-cells the ends are pointed.) In the next example, which is taken from the chrysanthemum, the pitted structure is still retained; but in the last figure, which is drawn from the lime-tree, the entire cell is filled with secondary structure. The reader must understand that we can only give the veriest outline of the subject, and profess to do nothing more than indicate the method of observation, leaving the pupil to work out the details by himself.
Another curious development of the plant-cells is the formation of HAIRS. These objects alone afford an inexhaustible field for the microscopist, and any one who chooses to work out the subject will find himself repaid if he makes a good series of preparations. In their primary forms the hairs are seen merely as little projections on the epidermis, whether of the stem, leaf, or petal, and by degrees assume their varied and beautiful forms. In order to show the singular forms which hairs sometimes assume, an illustration is here given of the hairs of the lavender leaf. This is one of the hairs that give the leaf its silvery gloss. It consists of an upright stem, from the top of which a number of forked branches shoot out horizontally, much like an open umbrella held upright. The object of this remarkable form is, that the delicate vessels in which the perfume is held should escape injury. If the reader will refer to the second figure, which represents a much magnified view of the edge of the leaf, he will see the globular perfume-gland standing under the shelter of the branching hairs.
The following plants afford valuable examples of hair:--Arabis, marvel of Peru, sowthistle, tobacco, southernwood, hollyhock, snapdragon, pansy (in throat of flower), deutzia (under-side of leaf), verbena, alyssum, tradescantia, borage, cowhage, and many others. The beautiful effect produced by the petals of flowers is caused by the imperfect hairs with which their surfaces are studded.
The POLLEN of plants is always worth observing, and some specimens are of remarkably beautiful shapes. Take that of althæa, crocus, cactus, heath, violet, daisy, lily, snowdrop, wallflower, willow-herb (a very beautiful form), hollyhock, periwinkle, primrose, &c. Put some up in Deane’s gelatine, and dry some, besides examining them all when fresh.
The microscopist ought to examine the structures of WOOD by making sections in the directions transverse and longitudinal. A razor will answer very well for the purpose, and the wood should always be soaked inside, and the razor wetted before the section is made. It is often useful to make diagonal sections of several woods, especially those of the pine and juniper. All the forest trees should be examined, and their roots and bark should not be omitted. Cut sections of coconut-shell, vegetable ivory, sugar-cane (a most beautiful object when mounted opaque), bamboo, butcher’s broom, &c.
MOSSES are beautiful objects, and can always be found. Examine particularly the fruit or seed-vessel, and note the structure of its different parts. Put these on a slide, and breathe on them, noting at the same time any change which may take place.
The SPORE CASES of ferns are extremely beautiful, and should be carefully examined. The little brown dots or streaks that are seen on the under surface of the fronds are called “sori,” and contain a large but variable number of the sporanges. These consist of stalked sacs or cases, and differ much in shape, according to the species of fern. If the fern be fresh from which the sorus is taken, the sporanges may be seen writhing and twisting like so many serpents, and sometimes it happens that one of the sporanges bursts, and suddenly covers the field of the microscope with minute black dots. These dots are the spores or seeds of the fern, and when magnified with a very high power, they are seen to be variously shaped. One of the most remarkable spores is that of the equisetum, or mare’s tail of the water. This spore looks like a ball with something coiled round it. As soon as the spore is discharged from its case, four threads are seen to uncoil themselves from around it, and by their elasticity to cause the spore to jump about as if alive. These fibres are technically named elasters, and are prolongations of the outer coat of the spore.
FUNGI of all kinds should be examined. There is never any difficulty in finding fungi, though the autumn is the best time of year for this purpose. “Mould,” as it is popularly called, is a form assumed by many species of fungus, which, though objectionable to the careful housewife, are full of interest to the microscopist. The well-known mushroom and toadstools are the highest of the fungi. The black spots on leaves are fungi, mostly belonging to the genus puccinia, and the best specimens are generally found on the wild rose or bramble. The black “smut” of wheat is another fungus, very pretty under the microscope, but very obnoxious to the farmer; and the “bunt” also belongs to the same vast tribe of plants, four thousand species of which are now known to exist.
The young observer should also look for the beautiful crystals which exist in many vegetable cells. The RAPHIDES, as these crystals are called, are of various forms, mostly shaped like curved needles, but often assuming very pretty and regular outlines. Raphides are plentifully found in the bulb of the onion, in the rhubarb, the lily, the iris, &c. They are best mounted as opaque objects and, if the reader can procure a binocular microscope, he will see the form of the raphides better than with the single-tube instrument.
SEEDS of different plants should be carefully examined, especially those of small dimensions, which often exhibit some wonderful beauties of structure. The winged seed of various plants, such as the thistle, the dandelion, the valerian, and the willow-herb, are extremely interesting objects; while those of the yellow snapdragon, the mullein, the Robin Hood, and the bur-seed, are remarkably beautiful in form, though they have no parachute, as the feathery appendage is called.
Leaving dry land, we will devote a short time to the water. Let the reader take with him the simple collecting apparatus mentioned on page 430, and secure specimens of the water from different ponds, ditches, and streams. For collecting the larger objects a little net, which can be purchased cheap, is of very great use. It is easily made by any tinman, and if the young microscopist knows the use of solder, as all experimental philosophers ought to do, he can put it together in a few minutes. It is formed of a strip of zinc bent into the requisite form, and with a socket, to which a handle can be attached. A piece of coarse muslin, or, rather, fine “net,” is then stretched over the bottom, and the apparatus is complete.
In the water is sure to be found one of the lowest forms of vegetable life--namely, the “confervoid algæ.” Look for these in bright, clear pools, placing the collecting bottle near any greenish film collected around the stems of plants, or spread over the stones on the bed of the pool. If this film be very carefully taken up, it will produce many interesting forms of vegetable life. One of the most remarkable of these vegetables is that which is called “volvox globator,” a figure of which is here given.
This wonderful object is about as large as the head of a very small pin, so that it is visible to the naked eye, and looks like a tiny globule passing through the water. When it is placed under a lens of moderate power, say of an inch focus, it exhibits some very strange peculiarities. It continually revolves, and by its revolution is able to enjoy a moderate degree of locomotion, though without any apparent object. Small dark spots are also seen upon it.
If a half-inch lens be now used, the structure of the volvox begins to be exhibited. The whole surface is covered with a network of very fine fibres, having a spot at the intersection of each mesh. On applying a still higher power, say the four-tenths of an inch, the structure is further elucidated, and the dots on the surface are seen to consist of greenish bodies, each furnished with a pair of delicate fibres, technically named cilia, which are constantly vibrating, and cause the revolution of the general mass. The dark spots are now seen to be the young plants in different stages of progress. From six to ten of these are inclosed within the parent, and when the latter has reached its full age, the membrane bursts asunder, and the little volvoces are liberated.
Another interesting form is the closterium, a genus which is sure to produce several good examples. We may mention that the ponds in Blackheath are very rich in these curious vegetables, and a very considerable series of confervoids may be obtained from them. The closteria are easily recognised by their resemblance to the Australian “boomerang.”
As our space is rapidly waning, we must leave the vegetable, and proceed to the animal kingdom.
As is the case with vegetables, the animal structure is composed of cells, though they cannot be so easily traced as in the examples which we have already noticed. The young observer may readily perceive the animal cell, in its largest and simplest form, by placing a little of the yolk of egg under the microscope. CARTILAGE, or gristle, is easily seen to be composed of cells. The nails of the fingers afford good objects for the microscopist in search of animal cells. If a thin section be placed under the microscope, none but an experienced observer will be able to make out the presence of cells at all; but if the section be soaked in “liquor potassæ,” the cells immediately swell up, and their shape is at once made plain. Take the BONE of a young chicken or rabbit, and make a thin section that embraces both the bone and cartilage, and there will then be a beautiful object for the microscopist, showing how the cartilage is changed by degrees into bone.
Sections of bone should also be made, both transverse and longitudinal.
The BLOOD is another object which must be carefully examined. The “corpuscles” which give the colouring matter to the blood are cells of different size, according to the creature from which they are taken. The dimensions of the animal exercise no apparent influence on the corpuscles, for those of “proteus anguinus,” a little creature not larger than a lamprey, are many times larger than those of the ox. In the accompanying illustration is shown a series of specimens, in order to show the great difference in their shape and size, all being drawn to scale and magnified by the same lens. The circular corpuscles in the left-hand upper corner are those of man; immediately below is a single corpuscle from the pigeon. The great central corpuscle is taken from the proteus; the two in the lower right-hand corner are from the frog, one of these being viewed edgeways; and of the remaining two, that on the left hand belongs to the tortoise, and that on the right to a fish.
The insect tribes are an inexhaustible source of objects for the microscopist, who may find that even a single fly will give him employment for many months. The scales from the butterfly’s wing, the wonderful compound eyes with which insects are gifted, the structure of their feet, and their entire anatomy, are always at the service of any microscopist who really cares for his work. It would, of course, be impossible to give even a list of the interesting portions of the different insects; so one or two examples must suffice us.
Take the ANTENNÆ of the insect tribes, and see how beautifully they are formed, how graceful is the shape, and how elaborate the structure. A low power will be useful for exhibiting their general shape and outline, but it is not until we know how to use the higher powers that the real beauty of these curious organs is seen. In the accompanying illustration is given part of an antenna of the common blue-bottle fly, in order to show the remarkable cavities which exist within the antennæ, and which are thought by some anatomists to be organs of hearing, and by others to be organs of smell.
The WINGS of insects are also most remarkable, and possess many peculiarities of structure which cannot be detected without the aid of a microscope. Take, for example, the wings of any hymenopterous insect, say those of a humble-bee, and see how beautiful is the structure which causes the four wings to be united into two when the insect is about to fly. In the illustration may be seen a pair of these wings, together with the row of hooks which bind them together. A still more magnified representation of the hooks is placed near the wings.
It is now ascertained that the wings of insects are connected with the breathing apparatus, and that the respiration of the insect extends even to the very tips of these singular organs, which are not modifications of existing limbs, as in the birds, but additional structures. The circulation of insects may often be seen by placing a portion of a transparent wing under a moderately high power. We have often seen it in the wing of the great water-beetle. A series of very beautiful preparations may be made in order to show the distinction between the wings of different insects; and as the orders of insects are founded upon their wings, there ought to be at least one example of each order. The proboscis of insects is always worthy of careful examination.
As to the breathing apparatus itself, the best mode of examining it is to open a caterpillar, remove a part of the large breathing tube which runs along each side, and place it under the microscope. It should always be taken so as to include one of the spiracles, or breathing-holes. An example of a breathing-tube, taken from a silk-worm, is given in the illustration.
HAIRS of animals are very curious and interesting objects. They should be mounted in three modes--namely, dry transparent, dry opaque, and in Canada balsam, transparent. Be sure to procure some hair of the bat, the sheep, the mouse, the deer, the mole, and any of the weasel tribe. Many insects have very beautiful hair, but the most lovely hair in the animal kingdom is that which is obtained from the sea-mouse. Fish scales should also be procured, and specimens should be taken from the lateral line.
MOLLUSCS of all kinds afford many beautiful objects, and the observer should be very careful to examine the wonderful tongue-ribbon of the snail, the slug, the periwinkle, the whelk, and other similar molluscs. If meant to be examined by polarized light, the tongue-ribbon should be mounted in Canada balsam.
CRYSTALS should always form part of a collection. Take those of common salt, nitre, sugar, chlorate of potash, salicine, &c.; indeed, anything that will crystallize should be prepared and mounted, as such objects will often be most useful when examining unknown substances.
ZOOPHYTES must of course find a place in the cabinet, and the young microscopist ought to put up a few specimens of the “bird’s-head” processes which are found in the bugularia and other inhabitants of the sea. The pretty noctiluca, to which is mostly owing the phosphorescence of the sea, should be preserved, and the extraordinary appendages to the skin of certain star-fish and sea urchins should be examined. These are called pedicillariæ, and a sketch of them is given in the illustration.
OPTICS AND OPTICAL AMUSEMENTS.
“’Seeing is believing,’ so the sages say, To prove this false, hear me, my friends, I pray, And very soon you all will be agreeing, That nought is so deceptive as our seeing.”--MARTIN.
Optics is the science of light and vision. Concerning the nature of light, two theories are at present very ably maintained by their respective advocates. One is termed the Newtonian theory, and the other the Huygenean. The Newtonian theory considers light to consist of inconceivably small bodies emanating from the sun, or any other luminous body. The Huygenean conceives it to consist in the undulations of a highly elastic and subtle fluid, propagated round luminous centres in spherical waves, like those arising in a placid lake when a stone is dropped into the water.
LIGHT AS AN EFFECT.
Light follows the same laws as gravity, and its intensity or degree decreases as the square of the distance from the luminous body increases. Thus, at the distance of two yards from a candle we shall have four times less light than we should have, were it only one yard from it, and so on in the same proportion.
REFRACTION.
Bodies which suffer the rays of light to pass through them, such as air, water, or glass, are called refracting media. When rays of light enter these, they do not proceed in straight lines, but are said to be refracted, or bent out of their course, as seen in the drawing. The ray of light proceeding from B through the glass L G is bent from the point C, instead of passing in the direction of the dotted line. But if the ray F C falls perpendicularly on the glass, there is no refraction, and it proceeds in a direct line to K; hence refraction only takes place when rays fall obliquely or aslant on the media.
THE INVISIBLE COIN MADE VISIBLE.
If a coin be placed in a basin, so that on standing at a certain distance it be just hid from the eye of an observer by the rim or edge of the basin, and then water be poured in by a second person, the first keeping his position; as the water rises the coin will become visible, and will appear to have moved from the side to the middle of the basin.
THE MULTIPLYING GLASS.
The multiplying glass is a semicircular piece of glass cut into facets or distinct surfaces; and in looking through it we have an illustration of the laws of refraction, for if a small object, such as a fly, be placed at D, an eye at E will see as many flies as there are surfaces or facets on the glass.
TRANSPARENT BODIES.
Transparent bodies, such as glass, may be made of such form as to cause all the rays which pass through them from any given point to meet in any other given point beyond them, or which will disperse them from the given point. These are called lenses, and have different names according to their form. 1. Is called the plano-convex lens. 2. Plano-concave. 3. Double convex. 4. Double concave. 5. A meniscus, so called from its resembling the crescent moon.
THE PRISM.
The prism is a triangular solid of glass, and by it the young optician may decompose a ray of light into its primitive and supplementary colours, for a ray of light is of a compound nature. By the prism the ray A is divided into its three primitive colours, blue, red, and yellow; and their four supplementary ones, violet, indigo, green, and orange. The best way to perform this experiment is to cut a small slit in a window-shutter, on which the sun shines at some period of the day, and directly opposite the hole place a prism P; a beam of light in passing through it will then be decomposed, and if let fall upon a sheet of white paper, or against a white wall, the seven colours of the rainbow will be observed.
COMPOSITION OF LIGHT.
The beam of light passing through the prism is decomposed, and the spaces occupied by the colours are in the following proportions:--red, 6; orange, 4; yellow, 7; green, 8; blue, 8; indigo, 6; violet, 11. Now, if you paste a sheet of white paper on a circular piece of board about six inches in diameter, and divide it with a pencil into fifty parts, and paint colours in them in the proportions given above, painting them dark in the centre parts, and gradually fainter at the edges, till they blend with the one adjoining. If the board be then fixed to an axle, and made to revolve quickly, the colours will no longer appear separate and distinct, but becoming gradually less visible they will ultimately appear white, giving this appearance to the whole surface of the paper.
A NATURAL CAMERA OBSCURA.
The human eye is a camera obscura, for on the back of it on the retina every object in a landscape is beautifully depicted in miniature. This may be proved by the
BULLOCK’S EYE EXPERIMENT.
Procure a fresh bullock’s eye from the butcher, and carefully thin the outer coat of it behind: take care not to cut it, for if this should be done the vitreous humour will escape, and the experiment cannot be performed. Having so prepared the eye, if the pupil of it be directed to any bright objects, they will appear distinctly delineated on the back part precisely as objects appear in the instrument we are about to describe. The effect will be heightened if the eye is viewed in a dark room with a small hole in the shutter, but in every case the appearance will be very striking.
THE CAMERA OBSCURA.
This is a very pleasing and instructive optical apparatus, and may be purchased for four or five shillings. But it may be easily made by the young optician. Procure an oblong box, about two feet long, twelve inches wide, and eight high. In one end of this a tube must be fitted containing a lens, and be made to slide backwards and forwards so as to suit the focus. Within the box should be a plain mirror reclining backwards from the tube at an angle of forty-five degrees. At the top of the box is a square of unpolished glass, upon which from beneath the picture will be thrown, and may be seen by raising the lid A. To use the camera place the tube with the lens on it opposite to the object, and having adjusted the focus, the image will be thrown upon the ground-glass as above stated, where it may be easily copied by a pencil or in colours.
The form of a camera obscura used in a public exhibition is as follows:--D D is a large wooden box stained black in the inside, and capable of containing from one to eight persons. A B is a sliding piece, having a sloping mirror C, and a double convex lens F, which may with the mirror C be slid up or down so as to accommodate the lens to near and distant objects. When the rays proceeding from an object without fall upon the mirror, they are reflected upon the lens F, and brought to fall on the bottom of the box, or upon a table placed horizontally to receive them, which may be seen by the spectator whose eye is at E.
THE CAMERA LUCIDA.
This instrument consists of a glass prism, C, D, D, E, having four sides covered. The sides C, D, being exposed to the object to be delineated, rays pass through the glass and fall on the sloping side D, E; from this they are reflected to the top, and finally pass out of the prism to the eye;[11] now from the direction at which the rays enter the eye, it receives them as if coming from an image at A, B, and if a sheet of paper be placed below the instrument, a perfect delineation of the object may be traced with a pencil. This is a very useful instrument to young draughtsmen.
[11] The eye is to be applied to the little circular hole seen on the upper surface.
THE MAGIC LANTERN.
This is one of the most pleasing of all optical instruments, and it is used to produce enlarged pictures of objects, which being painted on a glass in various colours are thrown upon a screen or white sheet placed against the wall of a large room. It consists of a sort of tin-box, within which is a lamp, the light of which (strongly reflected by the reflector T,) passes through a great plano-convex lens E fixed in the front. This strongly illuminates the objects which are painted on the slides or slips of glass, and placed before the lens in an inverted position, and the rays passing through them and the lens F, fall on a sheet, or other white surface, placed to receive the image. The glasses on which the figures are drawn are inverted, in order that the images of them may be erect.
PAINTING THE SLIDES.
The slides containing the objects usually shown in a magic lantern, are to be bought at opticians with the lantern, and can be procured cheaper and better in this way than by any attempt at manufacturing them. Should, however, the young optician wish to make a few slides of objects of particular interest to himself, he may proceed as follows:--
Draw first on paper the figures you wish to paint, lay it on the table, and cover it over with a piece of glass of the above shape; now draw the outlines with a fine camel’s hair pencil in black paint mixed with varnish, and when this is dry, fill up the other parts with the proper colours, shading with bistre also mixed with varnish. The transparent colours are alone to be used in this kind of painting.
TO EXHIBIT THE MAGIC LANTERN.
The room for the exhibition ought to be large, and of an oblong shape. At one end of it suspend a large sheet so as to cover the whole of the wall. The company being all seated, darken the room, and placing the lantern with its tube in the direction of the sheet, introduce one of the slides into the slit, taking care to invert the figures; then adjust the focus of the glasses in the tube by drawing it in or out as required, and a perfect representation of the object will appear.
EFFECTS OF THE MAGIC LANTERN.
Most extraordinary effects may be produced by means of the magic lantern; one of the most effective of which is a
TEMPEST AT SEA.
This is effected by having two slides painted, one with the tempest as approaching on one side, and continuing in intensity till it reaches the other. Another slide has ships painted on it, and while the lantern is in use, that containing the ships is dexterously drawn before the other, and represents ships in the storm.
The effects of sunrise, moonlight, starlight, &c., may be imitated, also by means of double slides, and figures may be introduced sometimes of fearful proportions.
Heads may be made to nod, faces to laugh; eyes may be made to roll, teeth to gnash; crocodiles may be made to swallow tigers; combats may be represented; but one of the most instructive uses of the slides is to make them illustrative of astronomy, and to show the rotation of the seasons, the cause of eclipses, the mountains in the moon, spots on the sun, and the various motions of the planetary bodies, and their satellites.
THE PHANTASMAGORIA.
Between the phantasmagoria and the magic lantern there is this difference: in common magic lanterns the figures are painted on transparent glass, consequently the image on the screen is a circle of light having figures upon it; but in the phantasmagoria all the glass is made opaque, except the figures, which, being painted in transparent colours, the light shines through them, and no light can come upon the screen except that which passes through the figure, as is here represented.
There is no sheet to receive the picture, but the representation is thrown on a thin screen of silk or muslin placed between the spectators and the lantern. The images are made to appear approaching and receding by removing it further from the screen, or bringing it nearer to it. This is a great advantage over the ordinary arrangements of the magic lantern, and by it the most astonishing effects are often produced.
DISSOLVING VIEWS.
The dissolving views, by which one landscape or scene appears to pass into the other while the scene is changing, are produced by using two magic lanterns placed side by side, and that can be a little inclined towards each other when necessary, so as to mix together the rays of light proceeding from the lenses of each, which produces that confusion of images, in which one view melts as it were into the other, which gradually becomes clear and distinct; the principle being the gradual extinction of one picture, and the production of another.
HOW TO RAISE A GHOST.
The magic lantern, or phantasmagoria, may be used in a number of marvellous ways, but in none more striking than in raising an apparent spectre. Let an open box, A B, about three feet long, a foot and a half broad, and two feet high, be prepared. At one end of this place a small swing dressing-glass, and at the other let a magic lantern be fixed with its lenses in a direction towards the glass. A glass should now be made to slide up and down in the groove C D, to which a cord and pulley should be attached, the end of the cord coming to the part of the box marked A. On this glass the most hideous spectre that can be imagined may be painted, but in a squat or contracted position, and when all is done, the lid of the box must be prepared by raising a kind of gable at the end of the box B, and in its lower part at E an oval hole should be cut sufficiently large to suffer the rays of light reflected from the glass to pass through them. On the top of the box at F place a chafing-dish, upon which put some burning charcoal. Now light the lamp G in the lantern, sprinkle some powdered camphor or white incense on the charcoal, adjust the slide on which the spectre is painted, and the image will be thrown upon the smoke. In performing this feat the room must be darkened, and the box should be placed on a high table, that the hole through which the light comes may not be noticed.
THE THAUMATROPE.
This word is derived from two Greek words, one of which signifies wonder, and the other to turn. It is a very pretty philosophical toy, and is founded upon the principle in optics, that an impression made upon the retina of the eye lasts for a short interval after the object which produced it has been withdrawn. The impression which the mind receives lasts for about the eighth part of a second, as may be easily shown by whirling round a lighted stick, which if made to complete the circle within that period, will exhibit not a fiery point, but a fiery circle in the air.
THE BIRD IN THE CAGE.
Cut a piece of cardboard of the size of a penny piece, and paint on one side a bird, and on the other a cage; fasten two pieces of thread one on each side at opposite points of the card, so that the card can be made to revolve by twirling the threads with the finger and thumb: while the toy is in its revolution, the bird will be seen within the cage. A bat may in the same manner be painted on one side of the card, and a cricketer upon the other, which will exhibit the same phenomenon, arising from the same principle.
CONSTRUCTION OF THE PHANTASMASCOPE.
The above-named figure is a Thaumatrope, as much as the one we are about to describe, although the term Phantasmascope is generally applied to the latter instrument; which consists of a disc of darkened tin-plate, with a slit or narrow opening in it, about two inches in length. It is fixed upon a stand, and the slit placed upwards, so that it may easily be looked through. Another disc of pasteboard, about a foot in diameter, is now prepared and fixed on a similar stand, but with this difference, that it is made to revolve round an axis in the centre. On this pasteboard disc, paint in colours a number of frogs in relative and progressive positions of leaping; make between each figure a slit of about a quarter of an inch deep: and when this second disc is made to revolve at a foot distance behind the first, and the eye is placed near the slit, the whole of the figures, instead of appearing to revolve with the disc, will all appear in the attitudes of leaping up and down, increasing in agility as the velocity of the motion is increased. It is necessary, when trying the effect of this instrument, to stand before a looking-glass, and to present the painted face of the machine towards the glass.
A very great number of figures may be prepared to produce similar effects--horses with riders in various attitudes of leaping, toads crawling, snakes twisting and writhing, faces laughing and crying, men dancing, jugglers throwing up balls, &c.; all of which, by the peculiar arrangement above detailed, will seem to be in motion. A little ingenuity displayed in the construction and painting of the figures upon the pasteboard disc will afford a great fund of amusement.
CURIOUS OPTICAL ILLUSIONS.
One of the most curious facts relating to the science of vision is the absolute insensibility of a certain portion of the retina to the impression of light, so that the image of any object falling on that point would be invisible. When we look with the right eye, this point will be about fifteen degrees to the right of the object observed, or to the right of the axis of the eye, or the point of most distinct vision. When looking with the left eye, the point will be as far to the left. The point in question is the basis of the optic nerve, and its insensibility to light was first observed by the French philosopher, Mariotte. This remarkable phenomenon may be experimentally proved in the following manner:--
Place on a sheet of writing-paper, at the distance of about three inches apart, two coloured wafers; then, on looking at the left-hand wafer with the right eye, at the distance of about a foot, keeping the eye straight above the wafer, and both eyes parallel with the line which forms the wafers, the left eye being closed, the right-hand wafer will become invisible; and a similar effect will take place if we close the right eye, and look with the left.
ANOTHER.
Cut a circular piece of white paper, about two inches in diameter, and affix it to a dark wall. At the distance of two feet on each side, but a little lower, make two marks; then place yourself directly opposite the paper, and hold the end of your finger before your face, so that when the right eye is open it shall conceal the mark on your left, and when the left eye is open the mark on your right. If you then look with both eyes at the end of your finger, the paper disc will be invisible.
ANOTHER.
Fix a similar disc of paper, two inches in diameter, at the height of your eye on a dark wall; a little lower than this, at the distance of two feet on the right hand, fix another of about three inches in diameter; now place yourself opposite the first sheet of paper, and, shutting the left eye, keep the right eye still fixed on the first object, and when at the distance of about ten feet, the second piece of paper will be invisible.
THE PICTURE IN THE AIR.
One of the numerous optical illusions which have from time to time been evolved by scientific minds, is that of making an image or picture appear in the air. This is produced by means of a mirror, and an object in relief, upon which a strong light is thrown,--the mirror being set at such an angle as to throw up the reflection of the image to a certain point in the view of the spectator. This illusion is produced as follows: Let a screen be constructed in which is an arched aperture, the centre of which may be five feet from the floor: behind the screen is placed a large mirror of an elliptical form. An object is now placed behind the screen, upon which the light of a strong lamp is thrown from a point above the mirror, and is received by the mirror and reflected to the centre of the arched cavity in the screen, where it will appear to the spectator. Care should be taken to place the image in an inverted position, and the light, which must be very powerful, should be so placed that none of it may reach the opening.
BREATHING LIGHT AND DARKNESS.
The following experiment, if performed with care, is exceedingly striking. Let S be a candle, whose light falls at an angle of 56° 45′ upon two plate glasses, A B, placed close to each other; and let the reflected rays, A C, B D, fall at the same angle upon two similar plates, C D, but so placed that the plane of reflection from the latter is at right angles to the plane of reflection from the former. An eye placed at E, and looking at the same time on the two plates, C and D, will see very faint images of the candle, S; which by a slight adjustment of the plates, may be made to disappear almost wholly, allowing the plate C to remain where it is. Change the position of D, till its inclination to the ray, B D, is diminished about 3°, or made nearly 53° 11′. The distance may be easily found by a little practice. When this is done, the image that had disappeared on looking into D will be restored, so that the spectator at E, upon looking into the two mirrors, C D, will see no light in C, because the candle has nearly disappeared, while the candle is distinctly seen in D. If, while, the spectator is looking into these two mirrors, either he or another person breathes upon them gently and quickly, the breath will revive the extinguished image in C, and will extinguish the visible image in D.[12]
[12] Explanation.--The light A, C, B, D is polarized by reflection from the plates A B, because it is incident at the polarizing angle 56° 45’ for glass. When we breathe upon the plates C D, we form upon their surface a thin film of water, whose polarizing angle is 53° 11′, so that if the polarized rays A, C, B, D fall upon the plates C, D, at an angle of 53° 11′, the candle from which they proceeded would not be visible, or they would not suffer reflection from the plates C D. At all the other angles the light would be reflected, and the candle visible. Now the plate D is placed at an angle of 53° 11′, and C at an angle of 56° 45′, so that when a film of water is breathed upon them, the light will be reflected from the latter, and none from the former; that is, the act of breathing upon the glass plates will restore the invisible, and extinguish the visible image.
TO SHOW THAT RAYS OF LIGHT DO NOT OBSTRUCT EACH OTHER.
Make a small hole in a sheet of pasteboard, A, and placing it upright before three candles, B, placed closely together, it will be found that the images of all the candle flames will be formed separately on a piece of paper, C, laid on the table to receive them. This proves that the rays of light do not obstruct each other in their progress, although all cross in passing through the hole.
OPTICS OF A SOAP-BUBBLE.
If a soap-bubble be blown up, and set under a glass, so that the motion of air may not affect it, as the water glides down the sides and the top grows thinner, several colours will successively appear at the top, and spread themselves from thence down the sides of the bubble, till they vanish in the same order in which they appeared. At length, a black spot appears at the top, and spreads till the bubble bursts.[13]
[13] The thinnest substance ever observed is the aqueous film of the soap-bubble previous to bursting; yet it is capable of reflecting a faint image of a candle, or the sun. Hence its thickness must correspond with what Sir Isaac Newton calls the beginning of black, which appears in water at the thickness of the seven hundred and fifty thousandth part of an inch.
THE KALEIDOSCOPE.
If any object be placed between two plane mirrors, inclined towards each other at an angle of thirty degrees, three several images will be perceived in the circumference of a circle. On this principle is formed the kaleidoscope, invented by Sir David Brewster, and by means of which the reflected images viewed from a particular point exhibit symmetrical figures, under an infinite arrangement of beautiful forms and colours. The kaleidoscope may be bought at any toy-shop, but it is requisite that every young person should be able to construct one for himself. He must, therefore, procure a tube of tin or paper, of about ten inches in length, and two and a half or three inches in diameter. One end of this should be stopped up with tin or paper, securely fastened, in which is to be made a hole, about the size of a small pea, for the eye to look through. Two pieces of well-silvered looking-glass, B B, are now to be procured; they must be not quite so long as the tube, and they should be placed in it lengthways, at an angle of 60 degrees, meeting together in a point at A, and separating to the points C C, the polished surfaces looking inwards. A circular piece of the glass is now to be laid on the top of the edges of the reflectors, B B; which, by their not being quite so long as the tube, will allow room for its falling in, and it will be supported by the edges of the tube, which may be slightly bent over, to prevent the glass from falling out. This having been done, now proceed to make the “cap” of the instrument. A rim of tin or pasteboard must be cut, so as to fit over the glass end of the tube; and in this, on the outer side, a piece of ground glass must be fastened, so that the whole may fit on the tube like the lid of a pill-box. Then, before putting it on, obtain some small pieces of broken glass of various colours, beads, little strips of wire, or any other object, and place them in the cap; and by passing it over the end, so that the broken glass, &c. has free motion, the instrument is complete. To use it, apply the eye to the small hole, and, on turning it, the most beautiful forms will appear, in the most wonderful combinations.
The following curious calculation has been made of the number of changes this instrument will admit of. Supposing it to contain 20 small pieces of glass, and that you make 10 changes in a minute, it will take an inconceivable space of time, i. e. 462,880,899,576 years, and 360 days, to go through the immense number of changes of which it is capable.
SIMPLE SOLAR MICROSCOPE.
Having made a circular hole in a window-shutter, about three inches in diameter, place in it a glass lens of about twelve inches focal distance. To the inside of the hole adapt a tube, having at a small distance from the lens a slit, capable of receiving one or two very thin plates of glass, to which the object to be viewed must be affixed by means of a little gum-water exceedingly transparent. Into this tube fit another, furnished at its extremity with a lens half-an-inch focal distance. Place a mirror before the hole of the window-shutter on the outside, in such a manner as to throw the light of the sun into the tube, and you will have a solar magic lanthorn.
The method of employing this arrangement of lenses for microscopic purposes is as follows:--Having darkened the room, and by means of the mirror reflected the sun’s rays on the glasses in a direction parallel to the axis, place some small object between the two moveable plates of glass, or affix it to one of them with very transparent gum-water, and bring it exactly into the axis of the tube; if the moveable tube be then pushed out or drawn in, till the object be a little beyond the focus, it will be seen painted very distinctly on a card, or piece of white paper, held at a proper distance, and will appear to be greatly magnified. A small insect will appear as a large animal, a hair as big as a walking-stick, and the almost invisible eels in paste or vinegar as large as common eels.
ANAMORPHOSES.
This is a very curious optical effect, producing a distorted and grotesque figure from a regular one. The term is derived from two Greek words, signifying a distortion of figure, and by its means many optical puzzles may be produced geometrically.
Take any subject, such as the portrait of a head; divide it vertically and horizontally with parallel lines, of which the outer sides shall form the boundary, A, B, C, D, and the whole shall be equidistant. Then, on a separate piece of paper, or cardboard, prepare a drawing similar to Fig. 2 by the following means:--
1. Draw a horizontal line, a b, equal to A B, and divide it into as many equal parts as the latter is divided.
2. Let fall a perpendicular line, e v, from the middle of a b, and then draw s v parallel to a b.
3. Both e v and s v may be any length at pleasure, but the longer the first is, and the shorter the other, so will the anamorphoses be more and more deformed. The proportions in our figures are sufficiently different.
4. After having drawn from the point v right lines, v 1, v 2, v 3, v 4, to the divisions of a b, draw the line s b, and through each point where s b intersects the divergent lines draw other horizontal lines parallel to a b. We now have a trapezium, a b c d divided into as many cells as the square in Fig. 1.
The next step is to fill up all the cells of Fig. 2 with portions of the device, proportionate to their position in Fig. 1. For instance, in Fig. 1 the nose is in the second vertical division from the left, and in the third and fourth horizontal divisions from the top, and that portion of the face must accordingly be placed in a corresponding part of Fig. 2.
By these means we procure the anamorphosis seen in Fig. 2, which when viewed from a particular position, will lose all its distortion, and assume an appearance resembling that in Fig. 1. This position lies immediately over the point v, and at a height above it equal to the length of the line s v; and the means of determining it are as follows.
Place the drawing horizontally before a window; take a slip of card, and rest its lower edge on the line s v, the card being accurately vertical; pierce a small hole in the card vertically over the point v, and at a height from it equal to the length of the line s v, then with the eye placed immediately behind the card, look through the orifice at the anamorphosis, and it will be found that as soon as it has become accustomed to the novelty of the experiment, the anamorphosis will lose its distortion, and appear almost exactly like the symmetrical figure.
It would be very difficult, and would require geometrical reasoning of a lengthened kind, to show why this particular form of construction should lead to such results.
THE COSMORAMA.
The principle upon which the cosmorama is formed is so simple, that any person may easily fit up one in a small summer house, &c. Nothing more is necessary than to fix in a hole a double convex lens of about three feet focus, A, and at rather less than this distance a picture, B, is to be hung. To absorb all the rays of light but those necessary for seeing the picture, a squared frame of wood blackened on the inside is placed between the lens and the picture. The picture may be hung in a large box having a light coming in upon it from above, or in a small closet illuminated in the same manner. Should it be wished to show it by candle-light, a lamp, c, may be placed on the top of the wooden frame, and if the light of this be converged by a lens to a moderate radius, it will be more effective.
DISTORTED LANDSCAPES.
Landscapes or other matters may be drawn so as to produce curious optical illusions by the following method. Take a piece of smooth white pasteboard and sketch the design upon it. Prick the outlines in every part with a fine pin or needle, then place the pricked drawing in a perpendicular position, and put a lighted candle behind it. Place before it another piece of pasteboard, and follow with a pencil the lines given by the light, and you have produced a distorted landscape. Now take away the candle and the pricked drawing, and place your eye where the light was, and the drawing will assume the regular form. To get your eye in the proper position, it will be advisable to cut out a piece of card according to the accompanying pattern, and raising it on its base, B, look through the hole at A, when the object will appear in its proper proportions.
PHOTOGRAPHY.
“Come like shadows, but not so depart.”--SHAKSPEARE.
Associated with the use of iodine and bromine is an art which every intelligent boy may practise, if he will attend to the following precise details kindly furnished by Mr. Richard Thomas, of 10, Pall Mall, who has devoted many years to the careful study of all the processes connected with it, and from whom all the best apparatus and purest chemicals required may be obtained.
HOW TO MAKE THE NEGATIVE ON GLASS, USING COLLODION BROMO-IODIZED FOR IRON DEVELOPMENT.
1. The edges of the glass should be ground all round, also slightly on the surface of the edges. This prevents contraction of the film, enabling it to resist the action of a heavy stream of water. Mark one side in the corner with a diamond, and upon this side bestow the greatest care.
2. To clean the glass, if new.--Make a mixture of spirits of wine and solution of ammonia, equal parts; render it as thick as cream with tripoli; with a piece of cotton-wool kept for this purpose rub a small quantity over that side marked as described, wash well under a tap of water, and wipe dry with a piece of old linen, washed without soap, and kept scrupulously clean for this purpose. Plates should not, however, be cleaned in the operating room with the above mixture; the vapour of ammonia might prove injurious to the chemicals.
3. Now polish with an old white silk handkerchief. If this latter precaution be not taken, small particles of linen will be left upon the plate: these are perhaps only seen when draining off the collodion; they form nuclei and eddies, checking the collodion in its course. Some of these minute fibres are washed off, and contaminate the next picture. To all lovers of clean pictures our advice therefore is, having well dried the plate with old linen, lay it, clean side upwards, upon a few sheets of common glazed demy paper (not blotting), and rub it hard with the silk until sensibly warm: this has the double advantage of dispersing fibres and moisture, for all glass plates are slightly in a hygrometric condition. Double the silk rubber up to form a pad, and with this the glass must be firmly dusted down just before pouring on the collodion, which will then run most evenly: if the coated plate is now viewed by transmitted light, not a speck or blemish will be seen upon it. When a plate cleaned as above described is breathed upon, the moisture does not evaporate slowly, but flies off. Do not be afraid of putting the glass into an electrical condition with the silk rubber: on this account objections have been raised to the use of silk: practically, however, I find it a most valuable auxiliary in this starting-point of the process, the perfect manipulation of which makes an important difference in the value of the finished picture. What can be more inartistic and annoying to an educated eye than spots, patches, stars, and sky rockets, the forms and shapes of which rival, in numberless variety, a display of fireworks? Let us not, therefore, be contented with pictures, however good in other respects, presenting these deformities--so many blots on the photographic escutcheon.
To clean a glass after having used it, when not varnished.--Wash off the collodion film with water, then clean the marked side with plain tripoli and water, and dry as above.
To coat the plate.--First remove all the particles of dried collodion from the mouth of the bottle. Now pour upon the centre of the cleaned glass as much collodion as it will hold. Do not perform this operation hurriedly, take time, and systematically incline the plate in such a manner that the collodion may run into each corner in succession; when perfectly covered, pour off gently the excess into the bottle at one of the corners nearest to you: with observation and practice dexterity is easily acquired. There are many ways of coating the plate; each person will adopt that which practice teaches him is best. The pneumatic plate-holder is a convenient little instrument to use for holding the plate whilst pouring on the collodion: it may be used for both small and large plates.
Keep the corner of the glass plate in contact with the neck of the bottle whilst pouring off the collodion; otherwise the film will be wavy in places.
4. As soon as the collodion ceases to run, plunge the prepared glass gently, without stopping, into the nitrate of silver bath, which is prepared as follows. Into a 20-oz. stoppered bottle put nitrate of silver, 1¼ ozs.; distilled water, 4 ozs.: dissolve. To this solution add iodide of potassium, 4 grs., dissolved in 1 drachm of distilled water. Mix these two solutions: the precipitate (iodide of silver) thus formed is by shaking entirely dissolved. Add 16 ozs. of distilled water, when the excess of iodide of silver is again thrown down, but in such a finely divided state as to render the saturation of the bath with iodide of silver perfect. Now drop in sufficient of the oxide of silver to turn the turbid yellow solution a dirty brown colour; so long as this effect is produced the quantity of oxide of silver, however much in excess, is of no consequence; shake the bottle well for ten minutes or so at intervals; then add alcohol, 30 minims, and filter; to the filtered solution add dilute nitric acid of the strength stated, 5 minims. The bath is now ready for use, and should be quite neutral.
5. Allow the prepared glass to remain in this bath from five to ten minutes, according to the temperature. Move it up and down three or four times whilst in the bath, in order to get rid of the greasy appearance on the surface: drain it, but not too closely. When in the frame, place upon the back a piece of common blotting-paper, to absorb moisture, and the two lower silver wires should also be covered with slips of blotting-paper; after which the sooner it is placed in the camera the better.
6. The time of exposure can only be ascertained by practice--no rules can be laid down; and I am unacquainted with any royal road, but that of experience, leading to constant success in this most important point.
7. The plate having been taken from the camera, and placed upon a levelled stand, or held in the hand, develop immediately the latent image with the following solution:--
Iron developing solution.--Protosulphate of iron, ¼ oz.; glacial acetic acid, ¼ oz.; spirits of wine, ½ oz.; distilled water, 8 ozs.: mix. Pour on of this solution only enough to cover the plate easily, commencing at that edge of the negative which stood uppermost in the camera; move the solution to and fro until it has become intimately mixed with the silver on the plate; then pour off into the developing glass, and at once return it on to the plate. When as much intensity has been obtained as possible with the iron developer, it should be thoroughly removed by washing with water. Any intensity may be obtained afterwards by using either of the following solutions:--
8. Intensifying solution.--Pyrogallic acid, 6 grs.; glacial acetic acid, ¼ oz.; distilled water, 6 ozs.: mix. A few drops of a 30-gr. solution of nitrate of silver, the quantity to be regulated according to the intensity required, to be added, at the moment of using, to as much of the pyrogallic solution as may be necessary.
Intensifying solution (another form).--1. Pyrogallic acid, 8 grs.; citric acid, 20 grs.; distilled water, 2 ozs. 2. Nitrate of silver, 8 grs.; distilled water, 2 ozs. Mix small quantities of the solutions 1 and 2, in equal portions, the moment before using.
The pyrogallic solution, made with good acetic acid, may be kept for a month or more in a cool place. Nevertheless, if the conditions of light and situation are unfavourable, I should prefer this solution just made. The iron solutions act best when freshly prepared.
It is supposed by some that a prolonged action of the iron developer produces fogginess. This may be the case when impure or improperly prepared collodion is used, but certainly not when the preparation is pure and of the proper quality.
When the image is sufficiently intense, wash freely with common filtered water; then pour on a saturated solution of hyposulphate of soda, which should immediately remove the iodide of silver: wash again well with water; allow as much as the plate will hold to soak in for at least a quarter of an hour, changing the water occasionally, to remove all traces of hyposulphate; lastly, wash the plate with a little distilled water, stand up to dry, and, if required, varnish either with spirit or amber varnish.
The following solution is also very commonly used for fixing the negative:--Cyanide of potassium, ¼ oz.; water, 12 ozs.
Attention to the following rules and cautions will assist the operator in the production of perfect pictures:--
1. Do not disturb the deposit which will occasionally be found at the bottom of the bottle containing the collodion.
2. Remove all particles of dried film from the neck of the bottle before pouring the collodion on the plate.
3. Never use damp cloths, leathers, or buffs, for giving the final polish to the plate. Negatives with an indistinct and muddy surface are frequently produced from this cause.
4. Let the film set properly before immersion in the nitrate of silver bath: its condition can be ascertained by gently touching the lower part of the coated plate with the end of the finger.
5. Never omit to pass a broad camel-hair brush over the plate just before pouring on the collodion.
6. Bear in mind that, as light is the producing agent, so will it prove a destructive one: not less than four folds of yellow calico should be used to obstruct white light; and in that case the aperture covered should be no larger than is necessary to admit sufficient light for working by. Examine occasionally the yellow calico: when this material is used to exclude white light, it becomes bleached by constant exposure. Do not trust alone to any coloured glass; no glass yet made is anti-actinic under all aspects of light and conditions of exposure.
7. When the negative requires intensifying, carefully wash off all traces of the first developing solution before proceeding to intensify. This operation may be performed either before or after the iodide is removed by fixing.
8. Glass baths are preferable to porcelain, ebonite, or gutta-percha baths for solution of nitrate of silver.
9. In using either spirit or amber varnish, before pouring it off, keep the plate horizontal a few seconds. This gives time for soaking in, and prevents the formation of a dull surface arising from too thin a coating.
10. Rub the lenses occasionally with a soft and clean wash-leather; the rapidity of action is much influenced by the brightness of the lenses: their surfaces are constantly affected by moisture in the atmosphere, which condensing, destroys the brilliancy of the image.
11. The white blotting-paper used for some photographic purposes is not suitable for filtering solutions; that only should be employed which is made for this purpose, and is sold under the name of filtering-paper.
12. Hyposulphate of soda.--A great deal of rubbish is sold under the name of this salt. As a test of its quality, 1½ drachms should entirely dissolve in 1 drachm of water, and this solution should dissolve rather more than 4½ grains of iodide of silver.
13. Chemicals.--The purity of photographic chemicals cannot be too strongly urged; the cheapest are not always the most economical. The commercial preparations are generally not to be depended upon, as these, though perhaps unadulterated, are, strictly speaking, not chemically pure. It is best to procure them from well-known chemists, who understand the purpose for which they are intended, and make the preparation of these substances peculiarly a branch of their business.
14. Never leave chemical solutions exposed in dishes: when done with, pour them back into glass-stoppered bottles, and decant for use from any deposit, or filter if necessary.
15. In all photographic processes it is absolutely necessary to be chemically clean; and this sometimes is not easy. As a rule, never be satisfied with cleanly appearances only, but take such measures as shall insure the absence of all extraneous matter in preparing the solutions, cleaning the glasses, dishes, &c.
16. All stains on the hands, linen, &c. may be removed by means of cyanogen soap or cyanide of potassium, which should be applied without water at first, then thoroughly washed off. To assist the operation, the hands may be now gently rubbed with a fine piece of pumice-stone, when the stains quickly disappear.
For more perfect and complete directions the reader is referred to a most excellent work, “The Modern Practice of Photography,” by R. W. Thomas, F.C.S.
PNEUMATICS.
“There is a tricksy spirit in the air That plays sad gambols.”--BEN JONSON.
The branch of the physical sciences which relates to the air and its various phenomena is called Pneumatics. By it we learn many curious particulars. By it we find that the air has weight and pressure, colour, density, elasticity, compressibility, and some other properties with which we shall endeavour to make the young reader acquainted by many pleasing experiments, earnestly impressing upon him to lose no opportunity of making physical science his study.
The common leather sucker by which boys raise stones will show the pressure of the atmosphere. It consists of a piece of soft but firm leather, having a piece of string drawn through its centre. The leather is made quite wet and pliable, and then its under part is placed on the stone and stamped down by the foot. This pressing excludes the air from between the leather and the stone, and by pulling the string a vacuum is left underneath its centre; consequently the leather is firmly attached to the stone, which enables you to lift it.
WEIGHT OF THE AIR PROVED BY A PAIR OF BELLOWS.
Shut the nozzle and valve-hole of a pair of bellows, and after having squeezed the air out of them, if they are perfectly air-tight, we shall find that a very great force, even some hundreds of pounds, is necessary for separating the boards. They are kept together by the weight of the air which surrounds them in the same manner as if they were surrounded by water.
THE PRESSURE OF THE AIR SHOWN BY A WINE-GLASS.
Place a card on a wine-glass filled with water, then invert the glass: the water will not escape, the pressure of the atmosphere on the outside of the card being sufficient to support the water.
ANOTHER.
Invert a tall glass jar in a dish of water, and place a lighted taper under it; as the taper consumes the air in the jar, the water, from the pressure without, rises up to supply the place of the oxygen removed by the combustion. In the operation of cupping the operator holds the flame of a lamp under a bell-shaped glass. The air within this being rarefied and expanded, a considerable portion is given off. In this state the glass is placed upon the flesh, and as the air within it cools it contracts, and the glass adheres to the flesh by the difference of the pressure of the internal and external air.
ELASTICITY OF THE AIR.
This can be shown by a beautiful philosophical toy, which may easily be constructed. Procure a glass jar such as is here represented, and put water into it. Then mould three or four little figures in wax, and make them hollow within, and having each a minute opening at the heel, by which water may pass in and out. Place them in the jar, as seen in the figure, and adjust them by the quantity of water admitted to them, so that in specific gravity they differ a little from each other. The mouth of the jar should now be covered with a piece of skin or india-rubber, and then, if the hand be pressed upon the top or mouth of the jar, the figures will be seen to rise or descend as the pressure is gentle or heavy; rising and falling, or standing still, according to the pressure made.
REASON FOR THIS.
The reason of this is, that the pressure on the top of the jar condenses the air between the cover and the water surface; this condensation then presses on the water below, and influences it through its whole extent, compressing also the air in the figures, forcing as much more water into them as to render them heavier than water, and therefore heavy enough to sink.
THE AIR-PUMP.
The time was, and that not very long ago, when the air-pump was only obtainable by the philosophical professor or by persons of enlarged means. But now, owing to our “cheap way of doing things,” a small air-pump may be obtained for about a guinea, and we would strongly advise our young friends to procure one, as it will be a source of endless amusement to them; and, supposing that they take our advice, we suggest the following experiments.
The air-pump consists of a bell glass, called the receiver, A, and a stand, upon which is a perforated plate, B. The hole in this plate is connected with two pistons, the rods of which are moved by a wheel handle backwards and forwards, and thus pump the air out of the receiver. When the air is thus taken out, a stop-cock is turned, and then the experiments may be performed.
Under the receiver of an air-pump, when the air has been thoroughly exhausted, light and heavy bodies fall with the same swiftness. Animals quickly die for want of air, combustion ceases, a bell sounds faint, and water and other fluids change to vapour.
TO PROVE THAT AIR HAS WEIGHT.
Take a florence flask, fitted up with a screw and fine oiled silk valve. Screw the flask on the plate of the air-pump, exhaust the air, take it off the plate, and weigh it. Then let in the air, and again weigh the whole, and it will be found to have increased by several grains.
TO PROVE AIR ELASTIC.
Place a bladder out of which all the air has apparently been squeezed under the receiver, upon it lay a weight, exhaust the air, and it will be seen that the small quantity of air left within the bladder will so expand itself as to lift the weight. Put a corked bottle into the receiver, exhaust the air, and the cork will fly out.
SOVEREIGN AND FEATHER.
Place a nicely-adjusted pair of forceps at the top of the receiver, communicating with the top of the outside through a hole, so that they may be opened by the fingers. Then place on each of the little plates a sovereign and a feather. Exhaust the air from the receiver; and having done so, detach the objects, so that they may fall. In the open air the sovereign will fall long before the feather, but in vacuo, as in the receiver now exhausted of its air, they will fall both together, and reach the bottom of the glass at the same instant.
AIR IN THE EGG.
Take a fresh egg, and cut off a little of the shell and film from its smaller end; then put the egg under a receiver, and pump out the air; upon which all the contents of the egg will be forced out by the expansion of the small bubble of air contained in the great end between the shell and the film.
THE DESCENDING SMOKE.
Set a lighted candle on the plate, and cover it with a tall receiver. The candle will continue to burn while the air remains, but when exhausted will go out, and the smoke from the wick, instead of rising, will descend in dense clouds towards the bottom of the glass, because the air which would have supported it has been withdrawn.
THE SOUNDLESS BELL.
Set a bell on the pump-plate, having a contrivance so as to ring it at pleasure, and cover it with a receiver; then make the clapper sound against the bell, and it will be heard to sound very well; now exhaust the receiver of air, and then when the clapper strikes against the sides of the bell the sound can be scarcely heard.
THE FLOATING FISH.
If a glass vessel containing water, in which a couple of fish are put, be placed under the receiver, upon exhausting the air the fish will be unable to keep at the bottom of the glass, owing to the expansion of the air within their bodies, contained in the air bladder. They will consequently rise and float, belly upwards, upon the surface of the water.
THE DIVING BELL.
The diving bell is a pneumatic engine, by means of which persons can descend to great depths in the sea, and recover from it valuable portions of wrecks and other things. Its principle may be well illustrated by the following experiment. Take a glass tumbler, and plunge it into the water with the mouth downwards, and it will be found that the water will not rise much more than half way in the tumbler. This may be made very evident if a piece of cork be suffered to float inside the glass on the surface of the water. The air within the tumbler does not entirely exclude the water, because air is elastic, and consequently compressible, and hence the air in the tumbler is what is called condensed. The diving bell is formed upon the above principle; but instead of being of glass, it is a wooden or metal vessel, of very large dimensions, so as to hold three or four persons, who are supplied with air from above by means of powerful pumps, whilst the excess of air escapes at the bottom of the bell, as may be seen any day at the Royal Polytechnic Institution.
EXPERIMENTS.
1. Place a cylinder of strong glass, open at both ends, on the plate of the air-pump, and put your hand on the other end, and you will of course be able to remove it at pleasure. Now exhaust the air from the interior of the cylinder, and at each stroke of the pump you will feel your hand pressed tighter and tighter on the cylinder, until you will not be able to remove it: as soon as the air is again admitted to the interior of the cylinder, the pressure within will be restored, and the hand again be at liberty.
2. Tie a piece of moistened bladder very firmly over one end of a similar glass cylinder, and place the open end on the plate of the pump. As soon as you begin to exhaust the air from the interior, the bladder, which was previously quite horizontal, will begin to bulge inwards, the concavity increasing as the exhaustion proceeds, until the bladder, no longer able to bear the weight of the superincumbent air, breaks with a loud report.
3. The elasticity of air, or indeed of any gaseous body, may be shown by introducing under the air-pump receiver a bladder containing a very small quantity of air, its mouth being closely tied. As you exhaust the air from the receiver, that portion contained in the bladder being no longer pressed upon by the atmosphere, will gradually expand, distending the bladder until it appears nearly full: on readmitting the air into the receiver, the bladder will at once shrink to its former dimensions.
A shrivelled apple placed under the same conditions will appear plump when the air is removed from the receiver, and resume its former appearance on the readmission of the air.
4. There is a very pretty apparatus made for the purpose of showing the pressure of the atmosphere, consisting of a hollow globe of brass, about three inches in diameter, divided into two equal parts, which fit very accurately together. It is furnished with two handles; one of them screwed into a hollow stem, communicating with the interior of the globe, and fitting on to the air-pump: the other is attached to a short stem on the opposite side of the globe. In the natural state the globe may easily be separated into its two hemispheres by one person pulling the handles, but after the air has been exhausted from the interior it requires two very strong men to separate the parts, and they will often fail to do so. By turning the stopcock, and readmitting the air into the interior of the globe, it will come asunder as easily as at first.
We are indebted to the weight of the atmosphere for the power we possess of raising water by the common pump; for the piston of the pump withdrawing the air from the interior of the pipe, which terminates in water, the pressure of the atmosphere forces the water up the pipe to supply the place of the air withdrawn. It was soon found, however, that when the column of water in the pipe was more than thirty feet high, the pump became useless, for the water refused to rise higher. Why? It was found that a column of water about thirty feet high exerted a pressure equal to the weight of the atmosphere, thus establishing an equilibrium between the water in the pipe and the atmospheric pressure.
This is the principle on which the barometer, or measurer of weight, as its name imports, is constructed. The metal Mercury is about thirteen and a half times heavier than water; consequently, if a column of water thirty feet high balances the pressure of the atmosphere, a column of mercury thirty inches high ought to do so also--and this is in fact the case. If you take a glass tube nearly three feet long, and closed at one end, and fill it with mercury; then, placing your finger on the open end, invert the tube into a basin or saucer containing some of the same metal; upon removing your finger (which must be done carefully, while the mouth of the tube is completely covered by the mercury,) it will be seen that the fluid will fall a few inches, leaving the upper part of the tube empty. Such a tube with a graduated scale attached is in truth a barometer, and as the weight of the atmosphere increases or decreases, so the mercury rises or falls in the tube. This instrument is of the greatest value to the seaman, for a sudden fall of the barometer will often give notice of an impending storm when all is fine and calm, and thus enable the mariner to make the preparations necessary to meet the danger.
It was discovered by an Italian philosopher named Torricelli, and from him the vacuum formed in the upper end of the tube above the surface of the mercury has been called the Torricellian vacuum. It is by far the most perfect vacuum that can be obtained, containing necessarily nothing but a minute quantity of the vapour of mercury.
EXPERIMENT.
Pass a little ether through the mercury in the tube, and as soon as it reaches the empty space it will boil violently, depressing the mercury, until the pressure of its own vapour is sufficient to prevent its ebullition. If you now cool the upper part of the tube, so as to condense the vapour, the pressure being thus removed, the ether will again begin to boil, and so alternately, as often as you please, in order to show this fact with effect, the bore of the tube should not be less than half an inch in diameter.
EXPERIMENT.
To show that the heat abstracted by the boiling of one liquid will freeze another, fill a tall narrow glass about half full of cold water (the colder the better), and place in it a thin glass tube containing some ether. Put them under the receiver of an air-pump. As you exhaust the air, the ether will begin to boil, until at length, by continuing the exhaustion, the water immediately surrounding the tube of ether will freeze, and a tolerably large piece of ice may thus be obtained.
Ether evaporates so rapidly even under the pressure of the atmosphere, that a small animal, such as a mouse, may be actually frozen to death by constantly dropping ether upon it. If poured on the hand, it produces a degree of cold that soon becomes, to say the least, unpleasant.
EXPERIMENT.
Place a flat saucer containing about a pound of oil of vitriol under the receiver of the air-pump, and set in it a watch glass containing a little water, supported on a stand with glass legs. Exhaust the receiver, when the water will evaporate, but without boiling; and the vapour being absorbed as it forms by the oil of vitriol, the vacuum is preserved, and the evaporation continues, until the vapour has abstracted so much caloric from the remainder of the water that it is all at once converted into ice.
In most elementary works on chemistry may be found a long table of freezing mixtures, as they are called, some with and others without ice or snow. We have selected a few from each division.
WITH ICE OR SNOW.
{ Snow or powdered ice 2 parts. { Powdered common salt 1 „
{ Snow 5 „ { Powdered common salt 2 „ { Powdered sal ammoniac 1 „
{ Snow 3 „ { Dilute sulphuric acid 2 „
{ Snow 2 „ { Crystallized muriate of lime 3 „
WITHOUT SNOW OR ICE.
{ Sulphate of soda 3 parts. { Dilute nitric acid 2 „
{ Nitrate of ammonia 1 „ { Water 1 „
{ Phosphate of soda 2 „ { Dilute nitric acid 1 „
{ Sulphate of soda 2 „ { Muriatic acid 1 „
The effects of most of these mixtures may be considerably increased by previously cooling the ingredients separately in other freezing mixtures.
In connexion with this branch of science, and especially with chemistry, the youthful philosopher should practise the art of decanting air from one jar to another standing over water, beginning by passing it from a small to a larger jar, then with two of equal size; and when he can accomplish the transfer without permitting even one bubble to escape, he may essay the much more difficult task of transferring the air from a large to a smaller jar.
He should also practise using the blowpipe until he can keep up a steady and uninterrupted flame for ten minutes or a quarter of an hour, without stopping for breath. It is quite possible to replenish wind in the mouth, which alone ought to be used, without interrupting the breathing for an instant, but it requires some practice.
SPECTRUM ANALYSIS.
If the youthful student wishes to occupy his leisure in a most amusing and instructive manner, and at the same time to acquire a ready method of testing for the presence of the various metals, he cannot do better than purchase from Mr. John Browning, of 111, Minories, the Amateur’s Spectroscope, price two guineas; or, if sufficiently ingenious, a prism and lenses may be purchased for sixteen shillings, and fitted up in paper tubes. Indeed, it is always better to buy some complete set or portion of a set of apparatus, instead of the trashy so-called “Boys’ Cabinets,” which contain very much that is useless and very little for instructive experiments. The instrument enables the observer to examine the properties of metallic salts when in the state of a glowing or incandescent gas. Common light affords a continuous spectrum or band of colours, red at one end and violet at the other, the intermediate colours being orange, yellow, green, blue, and indigo. The spectra of the metals in the state of luminous vapour are not continuous, but are represented by distinct bands or lines of light.
Every element, metallic or otherwise, when converted into a luminous gas, produces lines which are always found in the same part of the spectrum, and are therefore unalterable in position. The instrument (Fig. 1) is called the Spectroscope.
The instrument (Fig. 2) will exhibit the dark fixed lines in the solar spectrum, and also the bright lines in the spectra of incandescent metals.
HOW TO USE THE SPECTROSCOPE.
Screw the tube carrying the knife edges at the small end into the prism bore, and the telescope into its proper ring. Now place any common bright light exactly in front of the knife edges, and while looking through the telescope arrange the knife edges until a bright and continuous spectrum is visible.
TO OBTAIN THE BRIGHT LINES IN THE SPECTRUM GIVEN BY ANY SUBSTANCE.
Remove the bright flame from the front of the knife edges, and substitute in its place the flame of a common spirit lamp or, still better, a gas-jet known as a Bunsen’s Burner. Take a piece of platinum wire about the substance of a fine sewing needle; bend the end into a small loop about the eighth of an inch in diameter; fuse a small bead of the substance, or salt, to be experimented on into the loop of the platinum wire, and attaching it to any sort of light stand or support, bring the bead into the front edge of the flame, a little below the level of the knife edges. If the flame be opposite the knife edges, on looking through the eye-piece of the telescope the fixed lines due to the substance will be plainly visible. When minute quantities have to be examined, the substance should be dissolved, and a drop of the solution, instead of a solid bead, be used on the platinum wire.
The delicacy of this method of analysis is very great. Swan found, in 1857 (Ed. Phil. Trans., vol. xxi. p. 411), that the lines of sodium are visible when a quantity of solution is employed which does not contain more than 1/2,500,000 of a grain of sodium.
To view Fraunhofer’s lines on the solar spectrum it is only necessary to turn the knife edges towards a white cloud, and make the slit formed by the knife edges very narrow by turning the screw at the side of them. In every instance the focus of the telescope must be adjusted in the ordinary way, by sliding the draw tube until it suits the observer’s sight, and distinct vision is obtained.
It should be noted that lines at various parts of the spectrum require a different adjustment in focussing the telescope.
The small prism turning on a joint in front of the knife edges is for the purpose of showing two spectra in the field of view at the same time. To do this it must be brought close to the front of the knife edges. Then one flame must be placed in the position in which the flame of the candle is shown in the small figure, and the other directly in front of the slit. On looking through the telescope, as before described, the spectra due to the two substances will be seen one above the other.
When the slit is turned towards a bright cloud, and a light is used in the position of the candle flame, the spectrum of any substance may be seen compared with the solar spectrum. In this manner Kirchhoff determined in the solar spectrum the presence of the lines of the greater number of the elements which are believed to exist in the sun.
PROFESSOR STOKES’ ABSORPTION BANDS.
This instrument is expressly adapted to the prismatic analysis of organic bodies, according to the method recommended by Professor Stokes in his lecture at the Chemical Society, printed in the Chemical News.
To observe these bands it is only necessary to place a very dilute solution of the substance in a test-tube, then fix the test-tube in the small clip attached to a ring which slips on in front of the knife edges. Upon bringing any bright light in front of the tube, on looking through the telescope, if the instrument has been properly adjusted, a bright spectrum will be seen, interrupted by the dark bands due to the substance in solution.
One of the simplest and most interesting experiments of this kind can be made by preparing dilute solutions of madder, port wine, and blood.
In these very dilute solutions no difference can be detected by the unassisted eye, but on submitting them in the manner already described to the test of spectrum analysis, very different appearances will be presented.
The absorption bands may, however, be most conveniently examined and accurately investigated by means of Sorby and Browning’s new Micro-Spectroscope.
TO MAP OUT ANY SPECTRUM.
Place the eye-piece with cross wires in the telescope, with the cross in the shape of an [X]. Then move the telescope so that the point where the wires cross comes successively in contact with the various lines, noting the readings of the nonius on the arc. From these readings, by the help of any mechanical scale of equal parts, a map may be easily constructed.
By the assistance of spectrum analysis four new metals have been discovered, viz. Cæsium, Rubidium, Thallium, Norium. It is often a cause of grumbling with young beginners in chemistry that there is so much washing of glasses and slopping required to obtain proper results from tests; but here is a most refined mode of testing, which may be carried on in the drawing-room, and so delicate that a portion of sodium salt even less than 1/180,000,000th part of a grain can be easily detected.
Formerly the metal Lithium was considered to be a very rare one, but since the use of the spectroscope, quantities less than the 1/6,000,000th of a grain have been detected; it now appears that lithium is a very common metal, and exists in the human body, the sea, and may be obtained from many other common sources. Lithium has been found in the ashes of marine plants, the ashes of tobacco--in milk, coffee, tea, human blood, and in muscular tissue; it has also been found in meteoric stones.
The coloured plate is a faithful copy of Kirchhoff’s Diagram, and shows the solar spectrum, also the spectra of potassium, sodium, lithium, strontium, calcium, barium, rubidium.